Indian Association for the Cultivation of Science

About: Indian Association for the Cultivation of Science is a education organization based out in Kolkata, India. It is known for research contribution in the topics: Excited state & Catalysis. The organization has 3867 authors who have published 10457 publications receiving 220098 citations.

Fate of strong cosmic censorship conjecture in presence of higher spacetime dimensions

Abstract: Strong cosmic censorship conjecture has been one of the most important leap of faith in the context of general relativity, providing assurance in the deterministic nature of the associated field equations. Though it holds well for asymptotically flat spacetimes, a potential failure of the strong cosmic censorship conjecture might arise for spacetimes inheriting Cauchy horizon along with a positive cosmological constant. We have explicitly demonstrated that violation of the censorship conjecture holds true in the presence of a Maxwell field even when higher spacetime dimensions are invoked. In particular, for a higher dimensional Reissner-Nordstrom-de Sitter black hole the violation of cosmic censorship conjecture is at a larger scale compared to the four dimensional one, for certain choices of the cosmological constant. On the other hand, for a brane world black hole, the effect of extra dimension is to make the violation of cosmic censorship conjecture weaker. For rotating black holes, intriguingly, the cosmic censorship conjecture is always respected even in presence of higher dimensions. A similar scenario is also observed for a rotating black hole on the brane.

Influence of Size and Shape on the Photocatalytic Properties of SnO2 Nanocrystals

Abstract: Tuning the functional properties of nanocrystals is an important issue in nanoscience. Here, we are able to tune the photocatalytic properties of SnO2 nanocrystals by controlling their size and shape. A structural analysis was carried out by using X-ray diffraction (XRD)/Rietveld and transmission electron microscopy (TEM). The results reveal that the number of oxygen-related defects varies upon changing the size and shape of the nanocrystals, which eventually influences their photocatalytic properties. Time-resolved spectroscopic studies of the carrier relaxation dynamics of the SnO2 nanocrystals further confirm that the electron-hole recombination process is controlled by oxygen/defect states, which can be tuned by changing the shape and size of the materials. The degradation of dyes (90%) in the presence of SnO2 nanoparticles under UV light is comparable to that (88%) in the presence of standard TiO2 Degussa P-25 (P25) powders. The photocatalytic activity of the nanoparticles is significantly higher than those of nanorods and nanospheres because the effective charge separation in the SnO2 nanoparticles is controlled by defect states leading to enhanced photocatalytic properties. The size- and shape-dependent photocatalytic properties of SnO2 nanocrystals make these materials interesting candidates for photocatalytic applications.

Hydrogen-bonding induced alternate stacking of donor (D) and acceptor (A) chromophores and their supramolecular switching to segregated states.

Abstract: This paper reports comprehensive studies on the mixed assembly of bis-(trialkoxybenzamide)-functionalized dialkoxynaphthalene (DAN) donors and naphthalene-diimide (NDI) acceptors due the cooperative effects of hydrogen bonding, charge-transfer (CT) interactions, and solvophobic effects. A series of DAN as well as NDI building blocks have been examined (wherein the relative distance between the two amide groups in a particular chromophore is the variable structural parameter) to understand the structure-dependent variation in mode of supramolecular assembly and morphology (organogel, reverse vesicle, etc.) of the self-assembled material. Interestingly, it was observed that when the amide functionalities are introduced to enhance the self-assembly propensity, the mode of co-assembly among the DAN and NDI chromophores no longer remained trivial and was dictated by a relatively stronger hydrogen-bonding interaction instead of a weak CT interaction. Consequently, in a highly non-polar solvent like methylcyclohexane (MCH), although kinetically controlled CT-gelation was initially noticed, within a few hours the system sacrificed the CT-interaction and switched over to the more stable self-sorted gel to maximize the gain in enthalpy from the hydrogen-bonding interaction. In contrast, in a relatively less non-polar solvent such as tetrachloroethylene (TCE), in which the strength of hydrogen bonding is inherently weak, the contribution of the CT interaction also had to be accounted for along with hydrogen bonding leading to a stable CT-state in the gel or solution phase. The stability and morphology of the CT complex and rate of supramolecular switching (from CT to segregated state) were found to be greatly influenced by subtle structural variation of the building blocks, solvent polarity, and the DAN/NDI ratio. For example, in a given D-A pair, by introducing just one methylene unit in the spacer segment of either of the building blocks a complete change in the mode of co-assembly (CT state or segregated state) and the morphology (1D fiber to 2D reverse vesicle) was observed. The role of solvent polarity, structural variation, and D/A ratio on the nature of co-assembly, morphology, and the unprecedented supramolecular-switching phenomenon have been studied by detail spectroscopic and microscopic experiments in a gel as well as in the solution state and are well supported by DFT calculations.

Electrical transport properties of molybdenum tellurite glassy semiconductors

Abstract: The first measurements are reported of the electrical conductivity of semiconducting molybdenum tellurite glasses of various compositions over the temperature range 100-500 K. The electrical data have been analysed in the light of polaronic conduction models. The analysis shows that the adiabatic hopping theory is most appropriate for describing the polaronic conduction in the high-temperature region. However, in the intermediate temperature range, variable-range hopping dominates. It is shown that the glass-forming oxide, rather than the transition-metal oxide, greatly affects the conduction mechanism.