Indian Institute of Technology Bombay

About: Indian Institute of Technology Bombay is a education organization based out in Mumbai, India. It is known for research contribution in the topics: Catalysis & Computer science. The organization has 16756 authors who have published 33588 publications receiving 570559 citations.

The structure of broad topics on the web

Abstract: The Web graph is a giant social network whose properties have been measured and modeled extensively in recent years. Most such studies concentrate on the graph structure alone, and do not consider textual properties of the nodes. Consequently, Web communities have been characterized purely in terms of graph structure and not on page content. We propose that a topic taxonomy such as Yahoo! or the Open Directory provides a useful framework for understanding the structure of content-based clusters and communities. In particular, using a topic taxonomy and an automatic classifier, we can measure the background distribution of broad topics on the Web, and analyze the capability of recent random walk algorithms to draw samples which follow such distributions. In addition, we can measure the probability that a page about one broad topic will link to another broad topic. Extending this experiment, we can measure how quickly topic context is lost while walking randomly on the Web graph. Estimates of this topic mixing distance may explain why a global PageRank is still meaningful in the context of broad queries. In general, our measurements may prove valuable in the design of community-specific crawlers and link-based ranking systems.

Automatic Sarcasm Detection: A Survey

Abstract: Automatic sarcasm detection is the task of predicting sarcasm in text. This is a crucial step to sentiment analysis, considering prevalence and challenges of sarcasm in sentiment-bearing text. Beginning with an approach that used speech-based features, sarcasm detection has witnessed great interest from the sentiment analysis community. This paper is the first known compilation of past work in automatic sarcasm detection. We observe three milestones in the research so far: semi-supervised pattern extraction to identify implicit sentiment, use of hashtag-based supervision, and use of context beyond target text. In this paper, we describe datasets, approaches, trends and issues in sarcasm detection. We also discuss representative performance values, shared tasks and pointers to future work, as given in prior works. In terms of resources that could be useful for understanding state-of-the-art, the survey presents several useful illustrations - most prominently, a table that summarizes past papers along different dimensions such as features, annotation techniques, data forms, etc.

Highly convenient amine-free sonogashira coupling in air in a polar mixed aqueous medium by trans- and cis-[(NHC)2PdX2] (X=Cl, Br) complexes of N/O-functionalized N-heterocyclic carbenes.

Abstract: Two new trans- and cis-[(NHC)(2)PdX(2)] (X=Cl, Br) complexes of N/O-functionalized N-heterocyclic carbenes employed in a highly convenient amine-free Sonogashira cross-coupling reaction in air in a polar mixed aqueous medium are reported. Specifically, the trans-[{1-benzyl-3-(3,3-dimethyl-2-oxobutyl)imidazol-2-ylidene}(2)PdBr(2)] (3) and cis-[{1-benzyl-3-(N-tert-butylacetamido)imidazol-2-ylidene}(2)PdCl(2)] (4) complexes effectively catalyzed the Sonogashira cross-coupling reaction of aryl iodides with substituted acetylenes in air in a mixed solvent (DMF/H(2)O, 3:1 v/v) under amine-free conditions. Interestingly, these trans- and cis-[(NHC)(2)PdX(2)] (X=Cl, Br) complexes, with two N-heterocyclic carbene ligands, exhibited superior activity compared with the now popular PEPPSI (pyridine enhanced precatalyst preparation, stabilization and initiation)-themed analogues, trans-[(NHC)Pd(pyridine)X(2)] (X=Cl, Br), 3 a and 4 a, with one N-heterocyclic carbene ligand and a "throw away" pyridine ligand in a trans disposition to each other. The higher activities of 3 and 4 compared with PEPPSI analogues 3 a and 4 a are attributed to more-electron-rich metal centers, as revealed by DFT studies, in the former complexes and is in concurrence with a more electron-rich metal center being effective in facilitating the oxidative addition of aryl halide, often a rate-determining step in palladium-mediated cross-coupling reactions. Complexes 3 and 4 were prepared from the corresponding silver analogues by transmetalation with [(cod)PdCl(2)], whereas the corresponding PEPPSI analogues 3 a and 4 a were obtained directly from the imidazolium halide salts by reaction with PdCl(2) in pyridine in the presence of K(2)CO(3) as base.