Indian Institute of Technology Kharagpur

About: Indian Institute of Technology Kharagpur is a education organization based out in Kharagpur, India. It is known for research contribution in the topics: Natural rubber & Dielectric. The organization has 16887 authors who have published 38658 publications receiving 714526 citations.

Epoxidation of karanja (Pongamia glabra) oil by H2O2

Abstract: Epoxidation of karanja oil (KO), a nondrying vegetable oil, was carried out with peroxyacetic acid that was generated in situ from aqueous hydrogen peroxide and glacial acetic acid. KO contained 61.65% oleic acid and 18.52% linoleic acid, respectively, and had an iodine value of 89 g/100 g. Unsaturated bonds in the oil were converted to oxirane by epoxidation. Almost complete epoxidation of ethylenic unsaturation was achieved. For example, the iodine value of the oil could be reduced from 89 to 19 by epoxidation at 30°C. The effects of temperature, hydrogen peroxide-to-ethylenic unsaturation ratio, acetic acid-to-ethylenic unsaturation ratio, and stirring speed on the epoxidation rate and on oxirane ring stability were studied. The rate constant and activation energy for epoxidation of KO were 10−6 L·mol−1·s−1 and 14.9 kcal·mol−1, respectively. Enthalpy, entropy, and free energy of activation were 14.2 kcal·mol−1, −51.2 cal·mol−1·K−1, and 31.1 kcal·mol−1, respectively. The present study revealed that epoxides can be developed from locally available natural renewable resources such as KO.

Pool boiling heat transfer characteristics of ZrO 2 -water nanofluids from a flat surface in a pool

Abstract: Nucleate pool boiling of ZrO2 based aqueous nanofluid has been studied. Though enhancement in nucleate boiling heat transfer has been observed at low volume fraction of solid dispersion, the rate of heat transfer falls with the increase in solid concentration and eventually becomes inferior even to pure water. While surfactants increase the rate of heat transfer, addition of surfactant to the nanofluid shows a drastic deterioration in nucleate boiling heat transfer. Further, the boiling of nanofluid renders the heating surface smoother. Repeated runs of experiments with the same surface give a continuous decrease in the rate of boiling heat transfer.