Indian Institute of Technology Kharagpur

About: Indian Institute of Technology Kharagpur is a education organization based out in Kharagpur, India. It is known for research contribution in the topics: Computer science & Dielectric. The organization has 16887 authors who have published 38658 publications receiving 714526 citations.

Biodegradable drag reducing agents and flocculants based on polysaccharides: Materials and applications

Abstract: Organic and inorganic flocculants are used in treatment of water and industrial effluents. Polymeric flocculants, synthetic as well as natural, because of their natural inertness to PH changes, low dosage, and easy handling, have become very popular in industrial effluent treatment. It has been established in the authors' laboratory that by grafting polyacrylamide branches on rigid backbone of polysaccharides, the dangling grafted chains have easy approachability to contaminants in effluents. Thus grafted polysaccharides are very efficient, shear stable and biodegradable flocculants. They also exhibit turbulent drag reducing characteristics. Among grafted guar gum, xanthan gum, carboxymethyl cellulose, and starch, grafted starch performs the best. Starch consists of amylose (a low molecular weight linear polymer) and amylopectin (a high molecular weight, branched polymer). The grafted amylopectin is found to be the best flocculant for various kinds of industrial effluents, providing credibility to the above-cited model. In the present paper, the details about grafted polysaccharides as turbulent drag reducers and flocculants are given, along with their applications.

Stability Analysis of the Continuous-Conduction-Mode Buck Converter Via Filippov's Method

Abstract: To study the stability of a nominal cyclic steady state in power electronic converters, it is necessary to obtain a linearization around the periodic orbit. In many past studies, this was achieved by explicitly deriving the Poincare map that describes the evolution of the state from one clock instant to the next and then locally linearizing the map at the fixed point. However, in many converters, the map cannot be derived in closed form, and therefore this approach cannot directly be applied. Alternatively, the orbital stability can be worked out by studying the evolution of perturbations about a nominal periodic orbit, and some studies along this line have also been reported. In this paper, we show that Filippov's method - which has commonly been applied to mechanical switching systems - can be used fruitfully in power electronic circuits to achieve the same end by describing the behavior of the system during the switchings. By combining this and the Floquet theory, it is possible to describe the stability of power electronic converters. We demonstrate the method using the example of a voltage-mode-controlled buck converter operating in continuous conduction mode. We find that the stability of a converter is strongly dependent upon the so-called saltation matrix - the state transition matrix relating the state just after the switching to that just before. We show that the Filippov approach, especially the structure of the saltation matrix, offers some additional insights on issues related to the stability of the orbit, like the recent observation that coupling with spurious signals coming from the environment causes intermittent subharmonic windows. Based on this approach, we also propose a new controller that can significantly extend the parameter range for nominal period-1 operation.

Hydrothermal Growth of Hierarchical Ni3S2 and Co3S4 on a Reduced Graphene Oxide Hydrogel@Ni Foam: A High-Energy-Density Aqueous Asymmetric Supercapacitor

Abstract: Ni foam@reduced graphene oxide (rGO) hydrogel–Ni3S2 and Ni foam@rGO hydrogel–Co3S4 composites have been successfully synthesized with the aid of a two-step hydrothermal protocol, where the rGO hydrogel is sandwiched between the metal sulfide and Ni foam substrate. Sonochemical deposition of exfoliated rGO on Ni foam with subsequent hydrothermal treatment results in the formation of a rGO-hydrogel-coated Ni foam. Then second-time hydrothermal treatment of the dried Ni@rGO substrate with corresponding metal nitrate and sodium sulfide results in individual uniform growth of porous Ni3S2 nanorods and a Co3S4 self-assembled nanosheet on a Ni@rGO substrate. Both Ni@rGO–Ni3S2 and Ni@rGO–Co3S4 have been electrochemically characterized in a 6 M KOH electrolyte, exhibiting high specific capacitance values of 987.8 and 1369 F/g, respectively, at 1.5 A/g accompanied by the respective outstanding cycle stability of 97.9% and 96.6% at 12 A/g over 3000 charge–discharge cycles. An advanced aqueous asymmetric (AAS) superc...