Showing papers by "IPG Photonics published in 2008"

Advanced flat top laser heating system for high pressure research at GSECARS: application to the melting behavior of germanium

Abstract: Laser heating plays an essential role for in-situ high pressure high temperature studies into the physical and chemical properties of materials in the diamond anvil cell (DAC) and minerals at conditions relevant to the Earth's deep interior. High temperature experiments in the multi-Mbar (over 100 GPa) pressure range require the use of very small samples and consequently the utmost stability and controllability of the laser heating is crucial. To accomplish this, we have modified the laser heating system at GSECARS employing newly developed beam shaping optics combined with two diode-pumped, single mode fiber lasers. Varying the settings of the laser heating system, we were able to shape the beam to almost any desired intensity profile and size on the surface of the sample in the DAC, including tight focus, flat top, trident and doughnut types. The advantages and excellent performance of the flat top laser heating (FTLH) technique were demonstrated in melting experiments on germanium in the DAC at pressur...

Broadband ambient noise surface wave tomography across the United States

Abstract: [1] This study presents surface wave dispersion maps across the contiguous United States determined using seismic ambient noise. Two years of ambient noise data are used from March 2003 through February 2005 observed at 203 broadband seismic stations in the US, southern Canada, and northern Mexico. Cross-correlations are computed between all station-pairs to produce empirical Green functions. At most azimuths across the US, coherent Rayleigh wave signals exist in the empirical Green functions implying that ambient noise in the frequency band of this study (5–100 s period) is sufficiently isotropically distributed in azimuth to yield largely unbiased dispersion measurements. Rayleigh and Love wave group and phase velocity curves are measured together with associated uncertainties determined from the temporal variability of the measurements. A sufficient number of measurements (>2000) is obtained between 8 and 25 s period for Love waves and 8 and 70 s period for Rayleigh waves to produce tomographic dispersion maps. Both phase and group velocity maps are presented in these period bands. Resolution is estimated to be better than 100 km across much of the US from 8–40 s period for Rayleigh waves and 8–20 s period for Love waves, which is unprecedented in a study at this spatial scale. At longer and shorter periods, resolution degrades as the number of coherent signals diminishes. The dispersion maps agree well with each other and with known geological and tectonic features and, in addition, provide new information about structures in the crust and uppermost mantle beneath much of the US.

Determination of rapid Deccan eruptions across the Cretaceous‐Tertiary boundary using paleomagnetic secular variation: Results from a 1200‐m‐thick section in the Mahabaleshwar escarpment

Abstract: [1] Flow-by-flow reanalysis of paleomagnetic directions in two sections of the Mahabaleshwar escarpment, coupled with analysis of intertrappean alteration levels shows that volcanism spanned a much shorter time than previously realized. The sections comprise the upper part of magnetic chron C29r, transitional directions and the lowermost part of C29n. Lack of paleosecular variation allows identification of four directional groups, implying very large (40 to 180 m thick) single eruptive events (SEEs) having occurred in a few decades. Paleomagnetism allows temporal constraints upon the formation of 9 out of 23 thin red bole levels found in the sections to no more than a few decades; the two thickest altered layers could have formed in 1 to 50 ka. The typical volumes of SEEs (corresponding to magnetic directional groups) are estimated at 3000 to 20,000 km3, with flux rates ∼100 km3 a−1, having lasted for decades. Flood basalt emission can be translated into SO2 injection rates of several Gt a−1, which could have been the main agent of environmental change. The total volume of SO2 emitted by the larger SEEs could be on the order of that released by the Chicxulub impact. Moreover, each SEE may have injected 10 to 100 times more SO2 in the atmosphere than the deleterious 1783 Laki eruption. The detailed time sequence of SEEs appears to be the key feature having controlled the extent of climate change. If several SEEs erupted in a short sequence (compared to the equilibration time of the ocean), they could have generated a runaway effect leading to mass extinction.

Impact of the electron-electron correlation on phonon dispersion: Failure of LDA and GGA DFT functionals in graphene and graphite

Abstract: We compute the electron-phonon coupling (EPC) of selected phonon modes in graphene and graphite using various ab initio methods. The inclusion of nonlocal exchange-correlation effects within the $GW$ approach strongly renormalizes the square EPC of the ${\text{A}}_{1}^{\ensuremath{'}}$ $\mathbf{K}$ mode by almost 80% with respect to density-functional theory in the LDA and GGA approximations. Within GW, the phonon slope of the ${\text{A}}_{1}^{\ensuremath{'}}$ $\mathbf{K}$ mode is almost two times larger than in GGA and LDA, in agreement with phonon dispersions from inelastic x-ray scattering and Raman spectroscopy. The hybrid B3LYP functional overestimates the EPC at $\mathbf{K}$ by about 30%. Within the Hartree-Fock approximation, the graphene structure displays an instability under a distortion following the ${\text{A}}_{1}^{\ensuremath{'}}$ phonon at $\mathbf{K}$.

Fault rotation and core complex formation : significant processes in seafloor formation at slow-spreading mid-ocean ridges (Mid-Atlantic Ridge, 13°–15°N)

Abstract: [1] The region of the Mid-Atlantic Ridge (MAR) between the Fifteen-Twenty and Marathon fracture zones displays the topographic characteristics of prevalent and vigorous tectonic extension. Normal faults show large amounts of rotation, dome-shaped corrugated detachment surfaces (core complexes) intersect the seafloor at the edge of the inner valley floor, and extinct core complexes cover the seafloor off-axis. We have identified 45 potential core complexes in this region whose locations are scattered everywhere along two segments (13° and 15°N segments). Steep outward-facing slopes suggest that the footwalls of many of the normal faults in these two segments have rotated by more than 30°. The rotation occurs very close to the ridge axis (as much as 20° within 5 km of the volcanic axis) and is complete by ∼1 My, producing distinctive linear ridges with roughly symmetrical slopes. This morphology is very different from linear abyssal hill faults formed at the 14°N magmatic segment, which display a smaller amount of rotation (typically <15°). We suggest that the severe rotation of faults is diagnostic of a region undergoing large amounts of tectonic extension on single faults. If faults are long-lived, a dome-shaped corrugated surface develops in front of the ridges and lower crustal and upper mantle rocks are exposed to form a core complex. A single ridge segment can have several active core complexes, some less than 25 km apart that are separated by swales. We present two models for multiple core complex formation: a continuous model in which a single detachment surface extends along axis to include all of the core complexes and swales, and a discontinuous model in which local detachment faults form the core complexes and magmatic spreading forms the intervening swales. Either model can explain the observed morphology.

Amorphous materials: Properties, structure, and durability: Structure of Mg- and Mg/Ca aluminosilicate glasses: 27Al NMR and Raman spectroscopy investigations

Abstract: The structure and properties of glasses and melts in the MgO-Al2O3-SiO2 (MAS) and CaO-MgO-Al2O3-SiO2 (CMAS) systems play an important role in Earth and material sciences. Aluminum has a crucial influence in these systems, and its environment is still questioned. In this paper, we present new results using Raman spectroscopy and 27Al nuclear magnetic resonance on MAS and CMAS glasses. We propose an Al/Si tetrahedral distribution in the glass network in different Qn species for silicon and essentially in Q4 and VAl for aluminum. For the CMAS glasses, an increase of VAl and VIAl is clearly visible as a function of the increase of Mg/Ca ratio in the (Ca,Mg)3Al2Si3O12 (garnet) and (Ca,Mg)AlSi2O8 (anorthite) glass compositions. In the MAS system, the proportion of VAl and VIAl increases with decreasing SiO2 and, similarly with calcium aluminosilicate glasses, the maximum of VAl is located in the center of the ternary system.

Boroxol Rings in Liquid and Vitreous B2O3 from First Principles.

Abstract: We investigate the structural and vibrational properties of glassy ${\mathrm{B}}_{2}{\mathrm{O}}_{3}$ using first-principles molecular dynamics simulations. In particular, we determine the boroxol rings fraction $f$ for which there is still no consensus in the literature. Two numerical models containing either a low or a high level of boroxol rings are tested against a gamut of experimental probes (static structure factor, Raman, $^{11}\mathrm{B}$ and $^{17}\mathrm{O}$ NMR data). We show that only the boroxol-rich model ($f=75%$) can reproduce the full set of observables. Total-energy calculations show that at the glass density, boroxol-rich structures are favored by about $6\text{ }\text{ }\mathrm{kcal}/(\mathrm{mol}\text{ }\text{ }\mathrm{\text{boroxol}})$. Finally, the liquid state is explored in the 2000--4000 K range and a reduction of $f$ to 10%--20% is obtained.

Inner structure of La Fossa di Vulcano (Vulcano Island, southern Tyrrhenian Sea, Italy) revealed by high-resolution electric resistivity tomography coupled with self-potential, temperature, and CO2 diffuse degassing measurements

Abstract: La Fossa cone is an active stratovolcano located on Vulcano Island in the Aeolian Archipelago (southern Italy). Its activity is characterized by explosive phreatic and phreatomagmatic eruptions producing wet and dry pyroclastic surges, pumice fall deposits, and highly viscous lava flows. Nine 2-D electrical resistivity tomograms (ERTs; electrode spacing 20 m, with a depth of investigation >200 m) were obtained to image the edifice. In addition, we also measured the self-potential, the CO2 flux from the soil, and the temperature along these profiles at the same locations. These data provide complementary information to interpret the ERT profiles. The ERT profiles allow us to identify the main structural boundaries (and their associated fluid circulations) defining the shallow architecture of the Fossa cone. The hydrothermal system is identified by very low values of the electrical resistivity ( 400 Ω m). Inside the crater it is possible to follow the plumbing system of the main fumarolic areas. On the flank of the edifice a thick layer of tuff is also marked by very low resistivity values (in the range 1–20 Ω m) because of its composition in clays and zeolites. The ashes and pyroclastic materials ejected during the nineteenth-century eruptions and partially covering the flank of the volcano correspond to relatively resistive materials (several hundreds to several thousands Ω m). We carried out laboratory measurements of the electrical resistivity and the streaming potential coupling coefficient of the main materials forming the volcanic edifice. A 2-D simulation of the groundwater flow is performed over the edifice using a commercial finite element code. Input parameters are the topography, the ERT cross section, and the value of the measured streaming current coupling coefficient. From this simulation we computed the self-potential field, and we found good agreement with the measured self-potential data by adjusting the boundary conditions for the flux of water. Inverse modeling shows that self-potential data can be used to determine the pattern of groundwater flow and potentially to assess water budget at the scale of the volcanic edifice.

High-precision analysis of chromium isotopes in terrestrial and meteorite samples by thermal ionization mass spectrometry

Abstract: We present a method for the chemical separation of Cr from meteorite and terrestrial samples for isotopic analysis by thermal ionization mass spectrometry (TIMS). After sample digestion, separation of Cr(III) is achieved by means of a two-column cation-exchange chromatography procedure using AG 50W-x8 resin. In a first column, Cr(III) is isolated from major elements and the majority of trace elements. In a second column, trace amounts of Fe, Al and Ti are further removed. Total procedural yields are > 80%. Cr isotopes are measured by TIMS in the static multicollection mode. Mn/Cr ratios are obtained by multi-collector inductively coupled plasma source mass spectrometry (MC-ICPMS). The accuracy of our protocol was tested by reference to terrestrial analogs and comparison of Cr isotopic data for samples that underwent Cr purification following the cation-exchange chromatography described here and an alternative separation method employing both a cationic and an anionic chromatography step. Using our technique, Mn/Cr ratios reproduce to <2% (2σ) and 53Cr/52Cr and 54Cr/52Cr to 6 ppm and 12 ppm, respectively (2σ). This highly precise procedure allows the variability of Cr isotopes in the inner solar system objects to be addressed. Our method enabled us to document an initial homogeneity for 50,52,53Cr isotopes within 10 ppm, while 20–70 ppm deficits in 54Cr abundances have been resolved for a number of meteorite samples.

On new erosion models of Savage–Hutter type for avalanches

Abstract: In this work, we study the modeling of one-dimensional avalanche flows made of a moving layer over a static base, where the interface between the two can be time dependent. We propose a general model, obtained by looking for an approximate solution with constant velocity profile to the incompressible Euler equations. This model has an energy dissipation equation that is consistent with the depth integrated energy equation of the Euler system. It has physically relevant steady state solutions, and, for constant slope, it gives a particular exact solution to the incompressible hydrostatic Euler equations. Then, we propose a simplified model, for which the energy conservation holds only up to third-order terms. Its associated eigenvalues depend on the mass exchange velocity between the static and moving layers. We show that a simplification used in some previously proposed models gives a non-consistent energy equation. Our models do not use, nor provide, any equation for the moving interface, thus other arguments have to be used in order to close the system. With special assumptions, and in particular small velocity, we can nevertheless obtain an equation for the evolution of the interface. Furthermore, the unknown parameters of the model proposed by Bouchaud et al. (J Phys Paris I 4,1383–1410, 1994) can be derived. For the quasi-stationary case we compare and discuss the equation for the moving interface with Khakhar’s model (J Fluid Mech 441,225–264, 2001).

Environmental parameters affect the physical properties of fast-growing magnetosomes

Abstract: Magnetotactic bacteria are known to mediate the formation of intracellular magnetic nanoparticles in organelles called magnetosomes. These magnetite crystals are formed through a process called biologically controlled mineralization, in which the microorganisms exert a strict control over the formation and development of the mineral phase. By inducing magnetite nucleation and growth in resting, Fe-starved cells of Magnetospirillum gryphiswaldense, we have followed the dynamics of magnetosome development. By studying the properties of the crystals at several steps of maturity, we observed that freshly induced particles lacked a well-defined morphology. More surprisingly, although the mean particle size of mature magnetosomes is similar to that of magnetosomes formed by constantly growing and Fe-supplemented bacteria, we found that other physical properties such as crystal-size distribution, aspect ratio, and morphology significantly differ. Correlating these results with measurements of Fe uptake rates, we suggest that the expression of different faces is favored for different growth conditions. These results imply that the biological control over magnetite biomineralization by magnetotactic bacteria can be disturbed by environmental parameters. Specifically, the morphology of magnetite crystals is not exclusively determined by biological intervention through vectorial regulation at the organic boundaries or by molecular interaction with the magnetosome membrane, but also by the rates of Fe uptake. This insight may contribute to better define biomarkers and to an improved understanding of biomineralizing systems.

Environments around Al, Si, and Ca in aluminate and aluminosilicate melts by X-ray absorption spectroscopy at high temperature

Abstract: Structural data on silicate, aluminate, and aluminosilicate melts are difficult to measure and understand at high temperature. X-ray absorption spectroscopy (XAS) performed in situ at high temperature has been used to probe the local environment of low-Z elements (Al, Si, and Ca). For fully tetrahedral network glasses, CaAl2Si2O8 (anorthite) and CaAl2O4, the modifications in the Al K-edge spectra with increasing temperature can be attributed to a structural rearrangement of the network or to an increase of fivefold-coordinated Al. For the Ca3Al2O6 composition, where Al is localized in a depolymerized tetrahedral site associated with non-bridging O atoms, XAS spectra at the Al K-edge are barely affected by temperature. Depending on the composition, Ca K-edge spectra investigated in these experiments allow us to follow changes in the distortion of the Ca sites in melts at high temperature. The structural modifications at both short and intermediate range upon melting are well shown by these XAS measurements.

Rediscovering ancient glass technologies through the examination of opacifier crystals

Abstract: The aim of the study is to understand how antimonate opacifying crystals were obtained throughout history. Two archaeological glass productions opacified with calcium and lead antimonates are studied in this paper, in order to rediscover ancient opaque glass technologies: Roman mosaic tesserae (1st cent. B.C.–4th cent. A.D.) and Nevers lampworking glass (18th cent. A.D.). The fine examination of crystalline phases and of the vitreous matrix is undertaken using various and complementary techniques. Results are compared with a modern reference production, for which the technological process is well known. We demonstrate that Ca-antimonate opacifiers in Roman mosaic tesserae, as well as in Nevers lampworking glass, were obtained by in situ crystallization. Nevertheless, Roman and Nevers glass would have undergone different firing processes. We propose that the addition of previously synthesized crystals or the use of “anime” could be the process used to obtain Pb-antimonate opacified glass, for both productions studied. We demonstrate that CaO, PbO and Sb2O3 concentrations in the bulk compositions and in the matrices, and their evolution with the crystallinity ratio, offer robust criteria for the distinction of the opacification process used. Also, the different crystalline structures help to provide information on the experimental conditions.

Giant nonadiabatic effects in layer metals: raman spectra of intercalated graphite explained.

Abstract: The occurrence of nonadiabatic effects in the vibrational properties of metals has been predicted since the 1960s, but hardly confirmed experimentally. We report the first fully ab initio calculations of nonadiabatic frequencies of a number of conventional (hcp Ti and Mg) and layered metals (MgB2, CaC6, and other intercalated graphites). Nonadiabatic effects can be spectacularly large (up to 30% of the phonon frequencies) in both cases, but they can only be experimentally observed in the Raman spectra of layered compounds. In layered metals nonadiabatic effects are crucial to explaining the observed Raman shifts and linewidths. Moreover, we show that those quantities can be used to extract the electron momentum-relaxation time.

Persistent thermal activity at the Eastern Gulf of Aden after continental break-up

Abstract: During the early stages in the formation of divergent margins, the lithosphere experiences large changes in temperature that can determine its strength and influence magma generation. Heat-flow data from the Eastern Gulf of Aden indicate a thermal anomaly that has persisted after continental break-up. This anomaly may have been caused by small-scale convection that occurred during and after rifting. During the early stages in the formation of divergent margins, the lithosphere experiences large changes in temperature that can determine its strength and influence magma generation1,2. This, in turn, may play a key role in continental rifting, break-up, and subsequent subsidence. Here we present surface heat-flow data from the Eastern Gulf of Aden, which is a recently formed divergent margin between Africa and Arabia3. In the deeper parts of the margin the heat flow is high and constant, but it decreases abruptly near the shelf-slope. Our numerical models, in conjunction with geophysical and geological constraints, suggest that the data are best explained by a thermal anomaly in the upper mantle that has persisted after continental break-up. We suggest that this anomaly is related to small-scale convection that occurred during and after rifting. Similar anomalies could have characterized other divergent margins: for example, the presence of shallow-water sediments deposited after the opening of the Atlantic Ocean4,5,6 hints at lower subsidence than would have occurred in the absence of persistent thermal anomalies.

Fe-binding dissolved organic ligands near the Kerguelen Archipelago in the Southern Ocean (Indian sector)

Abstract: During the Ke rguelen O cean and P lateau compared S tudy (KEOPS; January–February 2005) cruise, the area southeast of the Kerguelen Archipelago in the Indian sector of the Southern Ocean was investigated to identify the mechanisms of natural iron fertilization of the Kerguelen Plateau. In this study, the organic speciation of Fe is described. Samples were determined immediately on board using competing ligand-adsorptive cathodic stripping voltammetry (CL-AdCSV). The dissolved organic ligands were always in excess of the dissolved Fe concentration, increasing the residence time in the water column and the potential availability for phytoplankton. The concentration of the dissolved organic ligands ranged from 0.44 to 1.61 n Eq of M Fe (=complexation site for Fe), with an average concentration of 0.91 n Eq of M Fe (S.D.=0.28, n =113) and a mean logarithm of conditional stability constant (log K′) of 21.7 (S.D.=0.28, n =113). A second weaker dissolved organic ligand group was detected in 32% of the samples, with Fe-binding characteristics at the edge of the detection window of the applied method. The occurrence of the highest concentrations of dissolved organic ligands in the wind-mixed surface layer and near the sediment at the bottom of the water column indicated that both phytoplankton and the sediment act as sources. Both sources are in concert with the general conclusions from the KEOPS research on the sources of Fe, where Fe was regenerated, organic Fe-binding ligands were formed in the upper layers, and both Fe and ligands were supplied by the sediment.

Globally aligned photomosaic of the Lucky Strike hydrothermal vent field (Mid‐Atlantic Ridge, 37°18.5′N): Release of georeferenced data, mosaic construction, and viewing software

Abstract: [1] We present a georeferenced photomosaic of the Lucky Strike hydrothermal vent field (Mid-Atlantic Ridge, 37°18′N). The photomosaic was generated from digital photographs acquired using the ARGO II seafloor imaging system during the 1996 LUSTRE cruise, which surveyed a ∼1 km2 zone and provided a coverage of ∼20% of the seafloor. The photomosaic has a pixel resolution of 15 mm and encloses the areas with known active hydrothermal venting. The final mosaic is generated after an optimization that includes the automatic detection of the same benthic features across different images (feature-matching), followed by a global alignment of images based on the vehicle navigation. We also provide software to construct mosaics from large sets of images for which georeferencing information exists (location, attitude, and altitude per image), to visualize them, and to extract data. Georeferencing information can be provided by the raw navigation data (collected during the survey) or result from the optimization obtained from image matching. Mosaics based solely on navigation can be readily generated by any user but the optimization and global alignment of the mosaic requires a case-by-case approach for which no universally software is available. The Lucky Strike photomosaics (optimized and navigated-only) are publicly available through the Marine Geoscience Data System (MGDS, http://www.marine-geo.org). The mosaic-generating and viewing software is available through the Computer Vision and Robotics Group Web page at the University of Girona (http://eia.udg.es/∼rafa/mosaicviewer.html).

Structure and dynamics of oxide melts and glasses: A view from multinuclear and high temperature NMR

Abstract: From a presentation of the various nuclear magnetic resonance (NMR) experiments that allows to characterize the local structure and dynamics of oxide glasses and melts, we show that it becomes possible to evidence not only the details of the coordination state of the constituting atoms but also the nature of polyatomic molecular motifs extending over several chemical bonds.

Relations between the dynamo region geometry and the magnetic behavior of stars and planets

Abstract: The geo and solar magnetic fields have long been thought to be very different objects both in terms of spatial structure and temporal behavior. The recently discovered field structure of a fully convective star is more reminiscent of planetary magnetic fields than the Sun's magnetic field (Donati J.-F. et al., Science, 311 (2006) 633), despite the fact that the physical and chemical properties of these objects clearly differ. This observation suggests that a simple controlling parameter could be responsible for these different behaviors. We report here the results of three-dimensional simulations which show that varying the aspect ratio of the active dynamo region can yield a sharp transition from Earth-like steady dynamos to Sun-like dynamo waves.

Theoretical infrared absorption coefficient of OH groups in minerals

Abstract: The integrated molar absorption coefficient of isolated and localized OH groups in selected minerals is theoretically investigated within the density functional theory framework. The overall decrease in absorption coefficient of stretching modes observed with increasing frequency is consistent with the experimental observations. It is related to a decrease in the magnitude of the hydrogen Born effective charge tensor projected along the OH bond as a function of increasing H-bonding. The scatter of theoretical data shows that the use of a general calibration of infrared absorbances in minerals cannot lead to accurate water contents. In contrast, the combination of theoretical modeling and experimental measurements should improve the determination of the hydrogen distribution among structurally distinct OH defects in nominally anhydrous minerals.

Double origin of hydrothermal convective flux variations in the Fossa of Vulcano (Italy)

Abstract: Soil-temperature measurements can provide information on the distribution of degassing fissures, their relationship to the internal structure of the volcano, and the temporal evolution of the system. At Vulcano Island (Italy), heat flux from a <3 km-deep magma body drives a hydrothermal system which extends across the main Fossa crater. This heat flux is also associated with variable magmatic gas flow. A high-density map of soil-temperatures was made in 1996 at a constant depth of 30 cm on the central and southern inner flanks of the Fossa crater. These measurements extended over an area covering about 0.04 km2, across which the heat flux is predominantly associated with a shallow boiling aquifer. The map shows that hot zones relate to structures of higher permeability, mainly associated with a fissure system dating from the last eruptive cycle (1888–1890). From 1996 to January 2005, we studied the evolution of the heat flux for the high temperature part of the map, both by repeating our measurements as part of 14 visits, during which temperatures were measured at a constant depth, and using data from permanent stations which allowed soil-temperatures to be continuously measured for selected vertical profiles. These data allowed us to calculate the heat flux, and its variation, with good precision for values lower than about 100 W m−2, which is generally the case in the study area. Above 100 W m−2, although the heat flux value is underestimated, its variations are recorded with an error less than 10%. During the period 1996–2004, two increases in the thermal flux were recorded. The first one was related to the seismic crisis of November 1998 which opened existing or new fissures. The second, in November 2004, was probably due to magma migration, and was associated with minor seismic activity.