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Showing papers by "Istanbul Technical University published in 2002"


Journal ArticleDOI
TL;DR: This work deals with the degradation of hydrolyzed Reactive Yellow 84 (Color Index), a widely used azo dye in textile finishing processes with two monochlorotriazine anchor groups by ozonation in a laboratory scale cylindric batch reactor.

292 citations


Journal ArticleDOI
TL;DR: The results indicated that alcoholysis products of cotton seed oil could be used as valuable intermediates in oleochemistry.

289 citations


Journal ArticleDOI
TL;DR: A number of strange attractors from the scroll grid attractor families are presented and have been experimentally verified using current feedback opamps to show the generalization of the nonlinear characteristics.
Abstract: In this paper a new family of scroll grid attractors is presented. These families are classified into three called 1D-, 2D- and 3D-grid scroll attractors depending on the location of the equilibrium points in state space. The scrolls generated from 1D-, 2D- and 3D-grid scroll attractors are located around the equilibrium points on a line, on a plane or in 3D, respectively. Due to the generalization of the nonlinear characteristics, it is possible to increase the number of scrolls in all state variable directions. A number of strange attractors from the scroll grid attractor families are presented. They have been experimentally verified using current feedback opamps. Also Lur'e representations are given for the scroll grid attractor families.

267 citations


Journal ArticleDOI
TL;DR: In this article, the DS5 DK type nanofiltration membranes were tested to recycle the reactive dye bath effluents and the effects of feed concentration, pressure and cross flow velocity on the permeate flux and color removal were investigated.

230 citations


Journal ArticleDOI
05 May 2002
TL;DR: Using these cash flows fuzzy present value, fuzzy future value, and fuzzy annual value formulas are developed for both discrete compounding and continuous compounding.
Abstract: Risk analysis involves the development of the probability distribution for the measure of effectiveness. The risk associated with an investment alternative is generally either given as the possibility of an unfavorable value of the measure of effectiveness or measured by the variance of the measure of effectiveness. In an uncertain economic decision environment, an expert's knowledge about discounting cash flows consists of a lot of vagueness instead of randomness. Cash amounts and interest rates are usually estimated by using educated guesses based on expected values or other statistical techniques to obtain them. Fuzzy numbers can capture the difficulties in estimating these parameters. In this paper, the formulas for the analyses of fuzzy present value, fuzzy equivalent uniform annual value, fuzzy future value, fuzzy benefit-cost ratio, and fuzzy payback period are developed and given some numeric examples. Then the examined cash flows are expanded to geometric and trigonometric cash flows and using these cash flows fuzzy present value, fuzzy future value, and fuzzy annual value formulas are developed for both discrete compounding and continuous compounding.

225 citations


Journal ArticleDOI
TL;DR: In this paper, a two-dimensional steady free convection in a square cavity bounded by isothermal vertical walls at different temperatures and adiabatic horizontal walls has been studied numerically by adopting a twotemperature model of heat transfer.

217 citations


Journal ArticleDOI
TL;DR: In this paper, the impact of ozone dose, pH, and initial dye concentration on color removal was examined for a 15 min batch of acid red-183 (AR-183) dye solution.
Abstract: The ozonation of wastewater supplied from a treatment plant (Samples A and B) and dye-bath effluent (Sample C) from a dyeing and finishing mill and acid dye solutions in a semi-batch reactor has been examined to explore the impact of ozone dose, pH, and initial dye concentration. Results revealed that the apparent rate constants were raised with increases in applied ozone dose and pH, and decreases in initial dye concentration. While the color removal efficiencies of both wastewater Samples A and C for 15 min ozonation at high ozone dosage were 95 and 97%, respectively, these were 81 and 87%, respectively at low ozone dosage. The chemical oxygen demand (COD) and dissolved organic carbon (DOC) removal efficiencies at several ozone dose applications for a 15 min ozonation time were in the ranges of 15–46% and 10–20%, respectively for Sample A and 15–33% and 9–19% respectively for Sample C. Ozone consumption per unit color, COD and DOC removal at any time was found to be almost the same while the applied ozone dose was different. Ozonation could improve the BOD5 (biological oxygen demand) COD ratio of Sample A by 1.6 times with 300 mg dm−3 ozone consumption. Ozonation of acid dyes was a pseudo-first order reaction with respect to dye. Increases in dye concentration increased specific ozone consumption. Specific ozone consumption for Acid Red 183 (AR-183) dye solution with a concentration of 50 mg dm−3 rose from 0.32 to 0.72 mg-O3 per mg dye decomposed as the dye concentration was increased to 500 mg dm−3. © 2002 Society of Chemical Industry

211 citations


Journal ArticleDOI
TL;DR: In this paper, a nonlinear liquid sloshing inside a partially filled rectangular tank has been investigated, where the fluid is assumed to be homogeneous, isotropic, viscous, Newtonian and exhibit only limited compressibility.

191 citations


Journal ArticleDOI
TL;DR: In this paper, the authors used the Global Positioning System slip vectors and with stratigraphic results implies that the North Anatolian Fault reached into the Marmara Sea region about 3.5 million yr ago.

171 citations


Journal ArticleDOI
01 Aug 2002-Wear
TL;DR: In this paper, the mechanical and tribological properties of polyamide 6 and high density polyethylene (HDPE) polyblends made using maleic anhyride polypropylene as the compatibilizing agent were studied.

167 citations


Journal ArticleDOI
01 Sep 2002-Fuel
TL;DR: In this paper, the effect of coal properties on CWSs have been investigated using two Turkish coals of different ranks and a Siberian bituminous coal, and the results showed that coal-water slurries have a similar viscosity as water slurries.

Journal ArticleDOI
TL;DR: In this article, the authors presented an application of layered artificial neural network controller (ANN) to study automatic generation control (AGC) problem in a four-area interconnected power system that three areas include steam turbines and the other area includes a hydro turbine.

Journal ArticleDOI
TL;DR: Bottle adsorption tests conducted with untreated, acid- and heat-activated sepiolites exhibit two distinct regions, and the observed differences are explained on the basis of partial collapse of the sepiolite crystal structure, the removal of zeolitic and bound waters and modification of the pore size distribution of sepiolate upon treatments.

Journal ArticleDOI
01 Oct 2002-Lithos
TL;DR: In this paper, an Eocene fold-and-thrust belt with Triassic eclogite and blueschist facies metamorphism was studied along the Imagezmir-Ankara suture.

Journal ArticleDOI
TL;DR: In this paper, a study on the recovery of copper, cobalt, and zinc from copper smelter and converter slags by roasting with sulfuric acid has been conducted.

Proceedings ArticleDOI
07 Nov 2002
TL;DR: The key idea of the approach is to adapt the underlying optical connectivity by measuring the actual traffic load on lightpaths continuously (periodically based on a measurement period) and reacting promptly to the imbalances caused by fluctuations in the traffic by adding or deleting one lightpath at a time.
Abstract: We present a new approach to the virtual-topology reconfiguration problem for wavelength-routed, optical wide-area networks under dynamic traffic demand. By utilizing the measured Internet backbone traffic characteristics, an adaptation mechanism is proposed to follow the changes in traffic without assuming that the future traffic pattern is known. In that sense, our work differs from previous studies which redesign the virtual-topology according to an expected (or known) traffic pattern, and then modify the connectivity to reach the target topology. The key idea of our approach is to adapt the underlying optical connectivity by measuring the actual traffic load on lightpaths continuously (periodically based on a measurement period) and reacting promptly to the imbalances caused by fluctuations in the traffic by adding or deleting one lightpath at a time. We aim to correct the encountered load imbalance directly, either by tearing down a lightpath that is lightly loaded or by setting up a new lightpath when congestion occurs. We introduce high and low watermark parameters on lightpath loads to detect any over/underutilized lightpath, and to trigger an adaptation step. The adaptation method is evaluated through simulations and the effect of system parameters (high and low watermarks, length of the measurement period) are investigated.

Journal ArticleDOI
01 Feb 2002-Polymer
TL;DR: In this article, the elastic modulus of a series of strong polyelectrolyte hydrogels based on acrylamide and 2-acrylamido-2-methylpropane sulfonic acid sodium salt (AMPS) was investigated.

Journal ArticleDOI
TL;DR: Sodic metapelites with jadeite, chloritoid, glaucophane and lawsonite formed a coherent regional metamorphic sequence, several tens of square kilometres in size, and over a kilometre thick, in the Orhaneli region of northwest Turkey as mentioned in this paper.
Abstract: Sodic metapelites with jadeite, chloritoid, glaucophane and lawsonite form a coherent regional metamorphic sequence, several tens of square kilometres in size, and over a kilometre thick, in the Orhaneli region of northwest Turkey. The low-variance mineral assemblage in the sodic metapelites is quartz + phengite + jadeite + glaucophane + chloritoid + lawsonite. The associated metabasites are characterized by sodic amphibole + lawsonite ± garnet paragenesis. The stable coexistence of jadeite + chloritoid + glaucophane + lawsonite, not reported before, indicates metamorphic pressures of 24 ± 3 kbar and temperatures of 430 ± 30 °C for the peak blueschist facies conditions. These P–T conditions correspond to a geotherm of 5 °C km−1, one of the lowest recorded in continental crustal rocks. The low geotherm, and the known rate of convergence during the Cretaceous subduction suggest low shear stresses at the top of the downgoing continental slab.

Journal ArticleDOI
TL;DR: In this paper, a block copolymer (BASFk Pluronic p123) was employed as a template to generate the mesoporous structure and an ultraviolet (UV) illumination method was employed to remove the polymer templates at room temperature.

Journal ArticleDOI
TL;DR: A series of systematic zeta potential measurements have been performed to determine the isoelectric point (Ip) and potential determining ions (pdi) of clinoptilolite.

Journal ArticleDOI
TL;DR: In this article, a new design equation for predicting the shear strength of monotonically loaded exterior beam column joints is proposed, which considers the influence of beam longitudinal reinforcement ratio, which was not taken into account in previously suggested design equations.

Journal ArticleDOI
TL;DR: In this paper, a novel Lorenz-type system of nonlinear differential equations is proposed, where the chaotic dynamics remain confined to the positive half-space with respect to the Z state variable due to a limiting threshold effect, the proposed system enables bipolar swing of this state variable.
Abstract: A novel Lorenz-type system of nonlinear differential equations is proposed. Unlike the original Lorenz system, where the chaotic dynamics remain confined to the positive half-space with respect to the Z state variable due to a limiting threshold effect, the proposed system enables bipolar swing of this state variable. In addition, the classical set of parameters (a, b, c) controlling the behavior of the Lorenz system are reduced to a single parameter, namely a. Two possible modes of operation are admitted by the system; switching between these two modes results in the creation of a complex butterfly chaotic attractor. Numerical simulations and results from an experimental setup are presented.

Journal ArticleDOI
TL;DR: In this article, the authors calculate stress evolution along the fault zone due to both seismic and tectonic loading since 1822 and identify two areas of particular seismic risk, one of which might be expected to yield a large event.

Journal ArticleDOI
TL;DR: In this article, the improvement of mechanical properties of hydroxyapatite (HA) with reinforcement of two (45.5 wt.% CaO) and three-oxide (28 wt% Na 2 O) glasses with different sintering temperatures is studied.

Journal ArticleDOI
TL;DR: In this paper, a new method for the dynamic analysis of mistuned bladed disks is presented, which is based on exact calculation of the response of a mistimed system using response levels for the tuned assembly togeher with a modification matrix constructed from the frequency response function (FRF) matrix of the tamed system and a matrix describing the mistuning.
Abstract: A new method for the dynamic analysis of mistuned bladed disks is presented. The method is based on exact calculation of the response of a mistimed system using response levels for the tuned assembly togeher with a modification matrix constructed from the frequency response function (FRF) matrix of the tamed system and a matrix describing the mistuning. The train advantages of the method are its efficiency and accuracy, which allow the use of large finite element models of practical bladed disk assemblies in parametric studies of mistuning effects on vibration amplitudes. A new method of calculating the FRF matrix of the tuned system using a sector model is also developed so as to improve the efficiency of the method even further, making the proposed method a very attractive tool for mistuning steadies. various numerical aspects of the proposed method are addressed and its accuracy and efficiency are demonstrated using representative test cases

Journal ArticleDOI
TL;DR: In this article, an end-chain and mid-chain functional macrophotoinitiators of poly(caprolactone) have been synthesized, which are used as initiators for the stannous 2-ethylhexanoate (Sn(Oct)2) catalyzed living ring-opening polymerization of -caprolACTone, and their success is confirmed by a strong change in the molecular weight of the prepolymer and the block copolymer as well as by NMR spectral measurements.
Abstract: Novel end-chain and midchain functional macrophotoinitiators of poly(-caprolactone) have been synthesized. For this purpose, mono- and dihydroxy functional photoinitiators namely, benzoin (B) and 2-hydroxy-2-methyl-1-phenyl propan-1-one (HMPP), Darocure 1173, and 2-hydroxy-1-(4-(2-hydroxy- ethoxy)phenyl)-2-methyl propan-1-one (HE-HMPP), Irgacure 2959, respectively, were used as initiators for the stannous-2-ethylhexanoate (Sn(Oct)2) catalyzed living ring-opening polymerization of -caprolactone. The gpc and IR, H NMR, UV, and fluorescence spectroscopic studies revealed that low-polydispersity poly(-caprolactone) with desired photoinitiator functionality at the end or in the middle of the chain were obtained. These prepolymers were used to induce radical polymerization of methyl methacrylate (MMA) upon irradiation via R-cleavage of the incorporated phenyl ketone groups. While end-chain functional macrophotoiniators led to the formation of both homo and block copolymers, only block copolymers of -CL and MMA were formed with midchain functional macrophotoinitiator. Successful blocking has been confirmed by a strong change in the molecular weight of the prepolymer and the block copolymer as well as by NMR spectral measurements.

Journal ArticleDOI
TL;DR: A survey of Turkish university students was undertaken to assess their on-line shopping and behaviour preferences, and these were compared with the results derived from 64 US university students to provide guidelines for specific design of features for the Turkish population that may not be necessary for the US population.
Abstract: With internationalization of commerce and business and with increased use of e-business and e-commerce, it is important to ensure that these systems can be effectively utilized across cultural boundaries. To increase effectiveness, appropriate changes and modifications in the systems may be required. With this in mind, a survey of 300 Turkish university students was undertaken to assess their on-line shopping and behaviour preferences, and these were compared with the results derived from 64 US university students. The results provide guidelines for specific design of features for the Turkish population that may not be necessary for the US population.

Journal ArticleDOI
TL;DR: In establishing a number of limitations inherent in traditional appraisal techniques, the concept of multivalent, or fuzzy logic, is used to demonstrate how inter-relationships can be modeled between key dimensions identified in a proposed conceptual model for investment evaluation.

Journal ArticleDOI
TL;DR: In this article, the mechanical properties and the swelling behavior of a series of N-isopropylacrylamide copolymers with the sodium salt of 2-acRYlamido-2-methylpropanesulfonic acid were investigated.
Abstract: The mechanical properties and the swelling behavior of a series of N-isopropylacrylamide copolymers with the sodium salt of 2-acrylamido-2-methylpropanesulfonic acid were investigated. The increase...

Journal ArticleDOI
TL;DR: Pleistocene raised coastal deposits characterized by locally abundant shells, aragonite-cemented beachrock and associated nearshore deposits border the western Marmara Sea at elevations of 0-50 m.