King Abdullah University of Science and Technology

About: King Abdullah University of Science and Technology is a education organization based out in Jeddah, Saudi Arabia. It is known for research contribution in the topics: Membrane & Catalysis. The organization has 6221 authors who have published 22019 publications receiving 625706 citations. The organization is also known as: KAUST.

Face Super-resolution Guided by Facial Component Heatmaps

Abstract: State-of-the-art face super-resolution methods leverage deep convolutional neural networks to learn a mapping between low-resolution (LR) facial patterns and their corresponding high-resolution (HR) counterparts by exploring local appearance information. However, most of these methods do not account for facial structure and suffer from degradations due to large pose variations and misalignments. In this paper, we propose a method that explicitly incorporates structural information of faces into the face super-resolution process by using a multi-task convolutional neural network (CNN). Our CNN has two branches: one for super-resolving face images and the other branch for predicting salient regions of a face coined facial component heatmaps. These heatmaps encourage the upsampling stream to generate super-resolved faces with higher-quality details. Our method not only uses low-level information (i.e., intensity similarity), but also middle-level information (i.e., face structure) to further explore spatial constraints of facial components from LR inputs images. Therefore, we are able to super-resolve very small unaligned face images \((16\,\times \,16\hbox { pixels})\) with a large upscaling factor of 8\(\times \), while preserving face structure. Extensive experiments demonstrate that our network achieves superior face hallucination results and outperforms the state-of-the-art.

Chlorine Vacancy Passivation in Mixed Halide Perovskite Quantum Dots by Organic Pseudohalides Enables Efficient Rec. 2020 Blue Light-Emitting Diodes

Abstract: Blue-emitting perovskites can be easily attained by precisely tuning the halide ratio of mixed halide (Br/Cl) perovskites (MHPs). However, the adjustable halide ratio hinders the passivation of Cl ...

Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism

Abstract: Classical and frustrated Lewis pairs (LPs) of the strong Lewis acid (LA) Al(C6F5)3 with several Lewis base (LB) classes have been found to exhibit exceptional activity in the Lewis pair polymerization (LPP) of conjugated polar alkenes such as methyl methacrylate (MMA) as well as renewable α-methylene-γ-butyrolactone (MBL) and γ-methyl-α-methylene-γ-butyrolactone (γ-MMBL), leading to high molecular weight polymers, often with narrow molecular weight distributions. This study has investigated a large number of LPs, consisting of 11 LAs as well as 10 achiral and 4 chiral LBs, for LPP of 12 monomers of several different types. Although some more common LAs can also be utilized for LPP, Al(C6F5)3-based LPs are far more active and effective than other LA-based LPs. On the other hand, several classes of LBs, when paired with Al(C6F5)3, can render highly active and effective LPP of MMA and γ-MMBL; such LBs include phosphines (e.g., PtBu3), chiral chelating diphosphines, N-heterocyclic carbenes (NHCs), and phosphazene superbases (e.g., P4-tBu). The P4-tBu/Al(C6F5)3 pair exhibits the highest activity of the LP series, with a remarkably high turn-over frequency of 9.6 × 104 h−1 (0.125 mol% catalyst, 100% MMA conversion in 30 s, Mn = 2.12 × 105 g mol−1, PDI = 1.34). The polymers produced by LPs at RT are typically atactic (PγMMBL with ∼47% mr) or syndio-rich (PMMA with ∼70–75% rr), but highly syndiotactic PMMA with rr ∼91% can be produced by chiral or achiral LPs at −78 °C. Mechanistic studies have identified and structurally characterized zwitterionic phosphonium and imidazolium enolaluminates as the active species of the current LPP system, which are formed by the reaction of the monomer·Al(C6F5)3 adduct with PtBu3 and NHC bases, respectively. Kinetic studies have revealed that the MMA polymerization by the tBu3P/Al(C6F5)3 pair is zero-order in monomer concentration after an initial induction period, and the polymerization is significantly catalyzed by the LA, thus pointing to a bimetallic, activated monomer propagation mechanism. Computational study on the active species formation as well as the chain initiation and propagation events involved in the LPP of MMA with some of the most representative LPs has added our understanding of fundamental steps of LPP. The main difference between NHC and PR3 bases is in the energetics of zwitterion formation, with the NHC-based zwitterions being remarkably more stable than the PR3-based zwitterions. Comparison of the monometallic and bimetallic mechanisms for MMA addition shows a clear preference for the bimetallic mechanism.

Pure crystal orientation and anisotropic charge transport in large-area hybrid perovskite films

Abstract: Controlling crystal orientations and macroscopic morphology is vital to develop the electronic properties of hybrid perovskites. Here we show that a large-area, orientationally pure crystalline (OPC) methylammonium lead iodide (MAPbI3) hybrid perovskite film can be fabricated using a thermal-gradient-assisted directional crystallization method that relies on the sharp liquid-to-solid transition of MAPbI3 from ionic liquid solution. We find that the OPC films spontaneously form periodic microarrays that are distinguishable from general polycrystalline perovskite materials in terms of their crystal orientation, film morphology and electronic properties. X-ray diffraction patterns reveal that the film is strongly oriented in the (112) and (200) planes parallel to the substrate. This film is structurally confined by directional crystal growth, inducing intense anisotropy in charge transport. In addition, the low trap-state density (7.9 × 1013 cm-3) leads to strong amplified stimulated emission. This ability to control crystal orientation and morphology could be widely adopted in optoelectronic devices.

Terahertz communication: The opportunities of wireless technology beyond 5G

Abstract: Over the past years, carrier frequencies used for wireless communications have been increasing to meet bandwidth requirements. The engineering community witnessed the development of wide radio bands such as the millimeter-wave (mmW) frequencies to fulfill the explosive growth of mobile data demand and pave the way towards 5G networks. Other research interests have been steered towards optical wireless communication to allow higher data rates, improve physical security and avoid electromagnetic interference. Nevertheless, a paradigm change in the electromagnetic wireless world has been witnessed with the exploitation of the Terahertz (THz) frequency band (0.1–10 THz). With the dawn of THz technology, which fills the gap between radio and optical frequency ranges, ultimate promise is expected for the next generation of wireless networks. In this paper, the light is shed on a number of opportunities associated with the deployment of the THz wireless links. These opportunities offer a plethora of applications to meet the future communication requirements and satisfy the ever increasing user demand of higher data rates.