Ladoke Akintola University of Technology

About: Ladoke Akintola University of Technology is a education organization based out in Ogbomoso, Nigeria. It is known for research contribution in the topics: Population & Adsorption. The organization has 2786 authors who have published 3066 publications receiving 36850 citations. The organization is also known as: Oyo State University of Technology & LAUTECH.

Impact of wastewater irrigation on soil physico-chemical properties, growth and water use pattern of two indigenous vegetables in southwest Nigeria

Abstract: The indiscriminate use of wastewater for irrigation as a result of freshwater shortage could impair soil functions and cause environmental pollution. The objective of this study was to evaluate soil physico-chemical properties, growth parameters and water use pattern of two indigenous vegetables irrigated with three kinds of wastewater in southwest Nigeria. The study was a 2 × 4 factorial (wastewater versus vegetable) pot experiment, laid out in randomized complete block design (RBCD) with three replications in a screen house. The tested vegetables were SM — Eggplant (Solanum macrocarpon) and CA — Spinach (Celosia angentea) while the wastewater treatments were abattoir wastewater (AW), bathroom, laundry wastewater (BW) cassava effluent (CE) and rainwater (RW) as control. The wastewaters were analyzed for physical, chemical and biological properties while the soil samples collected from the field at 0–20 cm soil layer and pots at 0–10 and 10–20 cm layer were analyzed for physico-chemical properties before and after the experiment, respectively. Soil hydrophobicity was determined using the water-droplet penetration time (WDPT) method, plant growth parameters were monitored every 5 days while leaf area was determined shortly before harvest. Consumptive water use was determined using the soil water balance technique. The wastewaters had moderate to very high degree of restriction for use in relation to salinity and sodicity. Except for CE treatment, wastewater irrigation increased the soil pH, Mg, K, Ca, TOC, TN and CEC at harvest. SAR surpassed the threshold value of 6 in the surface layer of CA soil irrigated with BW wastewater. Wastewater irrigation caused the occurrence of soil hydrophobicity, with the highest hydrophobic degree from CE treatment. The plant growth indices showed that the SM vegetable performed better under AW treatment while the CA vegetable performed better under BW treatment compared with RW treatment. The vegetables differed in relation to water use and there was no discernible trend among the different wastewater treatments as regards the temporal distribution of the consumptive water use. The CE wastewater had the most negative impact on both soil function and plant growth. The study showed that wastewater resources are valuable because of improvement of soil fertility and enhanced crop growth compared with rainwater, however they need to be managed with caution, preferably treatment, before reused in relation to soil functions and crop quality.

Silver‐gold alloy nanoparticles biofabricated by fungal xylanases exhibited potent biomedical and catalytic activities

Abstract: The search for biocompatible nanoparticles with vast applicability has impacted on exploration of various biomaterials for the synthesis of mono and bimetallic nanoparticles. Xylanase is widely regarded as an industrially important enzyme but its potentials in nanotechnological applications are yet to be fully explored. The current study investigates the exploit of xylanases of Aspergillus niger L3 (NE) and Trichoderma longibrachiatum L2 (TE) produced through valorization of corn-cob, to synthesize silver-gold alloy nanoparticles (Ag-AuNPs). Characterization of the Ag-AuNPs involved UV-vis spectroscopy, Fourier transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy and transmission electron microscopy, while their prospective use as antimicrobial, antioxidant, catalytic, anticoagulant, and thrombolytic agents were studied. The biosynthesized Ag-AuNPs were ruby red and light purple with surface plasmon resonance at 520 and 534 nm for NEAg-AuNPs and TEAg-AuNPs, respectively; while FTIR showed that protein molecules capped and stabilized the nanoparticles. The Ag-AuNPs were anisotropic with spherical, oval, and irregular shapes having sizes ranging from 6.98 to 52.51 nm. The nanoparticles appreciably inhibited the growth of tested clinical bacteria (23.40-90.70%) and fungi (70.10-89.05%), and also scavenged 2,2-diphenyl-1-picrylhydrazyl (48.51-53.79%) and hydrogen peroxide (80.5-95.50%). Furthermore, the Ag-AuNPs degraded malachite green (91.39%) and methylene blue (47.10%). Moreover, the Ag-AuNPs displayed outstanding anticoagulant and thrombolytic activities using human blood. This study further emphasizes the significance of xylanases in nanobiotechnology as it has established the potential of xylanases to synthesize Ag-AuNPs, which is being reported for the first time.

Adsorptive Removal of Malachite Green Dye Using Durian Seed-Based Activated Carbon

Abstract: Chemically prepared activated carbon derived from durian seed (DSAC) was used as adsorbent to adsorb Malachite green (MG) dye. The prepared DSAC was characterized using Brunauer–Emmet–Teller (BET), Fourier transform infrared (FTIR), scanning electron microscope (SEM), and proximate analysis, respectively. Batch adsorption studies were carried out for the removal of MG dye from aqueous solutions by varying operational parameters like contact time, initial MG dye concentration, solution temperature, and initial solution pH. Maximum dye removal of 97 % was obtained at pH 8. Experimental data were analyzed by eight model equations—Langmuir, Freundlich, Temkin, Dubinin–Radushkevich, Radke–Prausnitz, Sips, Vieth–Sladek, and Brouers–Sotolongo isotherms—and it was found that the Freundlich isotherm model fitted the adsorption data the most. Adsorption rate constants were determined using pseudo-first-order and pseudo-second-order rate equations, Elovich, intraparticle diffusion, and Avrami kinetic model. The results clearly showed that the adsorption of MG dye onto DSAC followed the pseudo-second-order model, and the mechanism of adsorption was controlled both by film diffusion and intraparticle diffusion. Thermodynamic parameters such as ∆G, ∆H, and ∆S were also calculated for the adsorption process. The process was found to be spontaneous and endothermic in nature. This work provided an attractive adsorbent for the removal of MG dye from wastewaters.

Bioremediation of Soil Artificially Contaminated with Petroleum Hydrocarbon Oil Mixtures: Evaluation of the Use of Animal Manure and Chemical Fertilizer

Abstract: The search for cheaper and environmentally friendly options of enhancing petroleum hydrocarbon degradation has continued to elicit research interest. One of such options is the use of animal manure as biostimulating agents. A combination of treatments consisting of the application of poultry manure, piggery manure, goat manure, and chemical fertilizer was evaluated in situ during a period of 4 weeks of remediation. Each treatment contained petroleum hydrocarbon mixture (kerosene, diesel oil, and gasoline mixtures) (10% w/w) in soil as a sole source of carbon and energy. After 4 weeks of remediation, the results showed that poultry manure, piggery manure, goat manure, and NPK (nitrogen, phosphorous, and potash [potassium]) fertilizer exhibited 73%, 63%, 50%, and 39% total petroleum hydrocarbon degradation, respectively. Thus, all the biostimulating treatment strategies showed the ability to enhance petroleum hydrocarbon microbial degradation. However, poultry manure, piggery manure, and goat manur...

Biodiesel: Sustainable Energy Replacement to Petroleum‐Based Diesel Fuel – A Review

Abstract: Biodiesel is a sustainable and renewable source of fuel. It has been considered as a comparable substitute to petro-diesel, which is a fast depleting resource. Many studies have been undertaken on biodiesel production from various feedstock as a result of its importance. The differences between the physico-chemical properties of biodiesel and petro-diesel were considered with the aim of justifying the applicability of biodiesel in compression ignition engines (CIE). It was established that biodiesel has relatively close BTE (brake thermal efficiency) and BSFC (brake specific fuel consumption) values with petro-diesel, hence, is suitable for CIE operation without any modification. The exhaust from CIE using biodiesel was lower compared to petro-diesel and this confirms the environmental friendliness of biodiesel. The catalyst being an important substance in the transesterification reaction of vegetable oil/animal fat to produce biodiesel was comprehensively discussed, and heterogeneous catalysts were established to be preferred due to several advantages over homogenous catalysts. This paper reviews biodiesel production, prospects, benefits and challenges as a replacement for petrol diesel.