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Showing papers by "Langley Research Center published in 2011"


Journal ArticleDOI
27 Oct 2011-Nature
TL;DR: It is demonstrated that chemical ozone destruction over the Arctic in early 2011 was—for the first time in the observational record—comparable to that in the Antarctic ozone hole.
Abstract: Chemical ozone destruction occurs over both polar regions in local winter–spring. In the Antarctic, essentially complete removal of lower-stratospheric ozone currently results in an ozone hole every year, whereas in the Arctic, ozone loss is highly variable and has until now been much more limited. Here we demonstrate that chemical ozone destruction over the Arctic in early 2011 was—for the first time in the observational record—comparable to that in the Antarctic ozone hole. Unusually long-lasting cold conditions in the Arctic lower stratosphere led to persistent enhancement in ozone-destroying forms of chlorine and to unprecedented ozone loss, which exceeded 80 per cent over 18–20 kilometres altitude. Our results show that Arctic ozone holes are possible even with temperatures much milder than those in the Antarctic. We cannot at present predict when such severe Arctic ozone depletion may be matched or exceeded. Since its emergence in the 1980s, the Antarctic ozone hole, the near-complete loss of lower-stratospheric ozone, has occurred every year. The possibility that a similar effect might occur in the Northern Hemisphere has been debated, but despite considerable variation in ozone levels in the Arctic, they had not reached the extremes seen in the south. Until this year. Observations made in the late winter and early spring of 2011 reveal ozone loss far outside the range previously observed over the Northern Hemisphere, comparable to some Antarctic ozone holes. The formation of the hole was driven by an unusually long cold snap and a high level of ozone-destroying chlorine. Although this effect is dramatic, it is difficult to predict whether similar Arctic ozone holes will develop in future.

597 citations


Journal ArticleDOI
12 Aug 2011-Science
TL;DR: An increase in the amount of aerosols in the stratosphere during the past decade has decreased the rate of global warming, and climate model projections neglecting these changes would continue to overestimate the radiative forcing and global warming in coming decades.
Abstract: Recent measurements demonstrate that the “background” stratospheric aerosol layer is persistently variable rather than constant, even in the absence of major volcanic eruptions. Several independent data sets show that stratospheric aerosols have increased in abundance since 2000. Near-global satellite aerosol data imply a negative radiative forcing due to stratospheric aerosol changes over this period of about –0.1 watt per square meter, reducing the recent global warming that would otherwise have occurred. Observations from earlier periods are limited but suggest an additional negative radiative forcing of about –0.1 watt per square meter from 1960 to 1990. Climate model projections neglecting these changes would continue to overestimate the radiative forcing and global warming in coming decades if these aerosols remain present at current values or increase.

502 citations


Journal ArticleDOI
TL;DR: In this article, a bath sonication-assisted exfoliation of hexagonal boron nitride (h-BN) nanosheets was demonstrated to be effective in exfoliating the layered h-BN structures.
Abstract: Hexagonal boron nitride (h-BN) is traditionally considered to be insoluble in water. However, here we demonstrate that water is effective to exfoliate the layered h-BN structures with the assistance of bath sonication, forming “clean” aqueous dispersions of h-BN nanosheets without the use of surfactants or organic functionalization. Besides few-layered h-BN nanosheets, there was also evidence on the presence of monolayered nanosheet and nanoribbon species. Most nanosheets were of reduced lateral sizes, which was attributed to the cutting of parent h-BN sheets induced by the sonication-assisted hydrolysis (evidenced by the ammonia test and spectroscopy results). The hydrolysis effect also assisted in the exfoliation of h-BN nanosheets in addition to the solvent polarity effect. The h-BN nanosheets in such “clean” aqueous dispersions were demonstrated to be conveniently processed via solution methods with retained physical properties. The dispersed h-BN nanosheets in water also exhibited strong affinity tow...

496 citations


Journal ArticleDOI
TL;DR: In this paper, the authors investigated the physical and chemical evolution of biomass burning (BB) organic aerosols (POA and SOA) using the Aerodyne Aerosol Mass Spectrometer.
Abstract: . Biomass burning (BB) is a large source of primary and secondary organic aerosols (POA and SOA). This study addresses the physical and chemical evolution of BB organic aerosols. Firstly, the evolution and lifetime of BB POA and SOA signatures observed with the Aerodyne Aerosol Mass Spectrometer are investigated, focusing on measurements at high-latitudes acquired during the 2008 NASA ARCTAS mission, in comparison to data from other field studies and from laboratory aging experiments. The parameter f 60 , the ratio of the integrated signal at m/z 60 to the total signal in the organic component mass spectrum, is used as a marker to study the rate of oxidation and fate of the BB POA. A background level of f 60 ~0.3% ± 0.06% for SOA-dominated ambient OA is shown to be an appropriate background level for this tracer. Using also f 44 as a tracer for SOA and aged POA and a surrogate of organic O:C, a novel graphical method is presented to characterise the aging of BB plumes. Similar trends of decreasing f 60 and increasing f 44 with aging are observed in most field and lab studies. At least some very aged BB plumes retain a clear f 60 signature. A statistically significant difference in f 60 between highly-oxygenated OA of BB and non-BB origin is observed using this tracer, consistent with a substantial contribution of BBOA to the springtime Arctic aerosol burden in 2008. Secondly, a summary is presented of results on the net enhancement of OA with aging of BB plumes, which shows large variability. The estimates of net OA gain range from ΔOA/ΔCO(mass) = −0.01 to ~0.05, with a mean ΔOA/POA ~19%. With these ratios and global inventories of BB CO and POA a global net OA source due to aging of BB plumes of ~8 ± 7 Tg OA yr −1 is estimated, of the order of 5 % of recent total OA source estimates. Further field data following BB plume advection should be a focus of future research in order to better constrain this potentially important contribution to the OA burden.

495 citations


Journal ArticleDOI
TL;DR: This paper documents the CERES Edition-2 cloud property retrieval system used to analyze data from the Tropical Rainfall Measuring Mission Visible and Infrared Scanner and by the MODerate-resolution Imaging Spectrometer instruments on board the Terra and Aqua satellites covering the period 1998 through 2007.
Abstract: The National Aeronautics and Space Administration's Clouds and the Earth's Radiant Energy System (CERES) Project was designed to improve our understanding of the relationship between clouds and solar and longwave radiation. This is achieved using satellite broad-band instruments to map the top-of-atmosphere radiation fields with coincident data from satellite narrow-band imagers employed to retrieve the properties of clouds associated with those fields. This paper documents the CERES Edition-2 cloud property retrieval system used to analyze data from the Tropical Rainfall Measuring Mission Visible and Infrared Scanner and by the MODerate-resolution Imaging Spectrometer instruments on board the Terra and Aqua satellites covering the period 1998 through 2007. Two daytime retrieval methods are explained: the Visible Infrared Shortwave-infrared Split-window Technique for snow-free surfaces and the Shortwave-infrared Infrared Near-infrared Technique for snow or ice-covered surfaces. The Shortwave-infrared Infrared Split-window Technique is used for all surfaces at night. These methods, along with the ancillary data and empirical parameterizations of cloud thickness, are used to derive cloud boundaries, phase, optical depth, effective particle size, and condensed/frozen water path at both pixel and CERES footprint levels. Additional information is presented, detailing the potential effects of satellite calibration differences, highlighting methods to compensate for spectral differences and correct for atmospheric absorption and emissivity, and discussing known errors in the code. Because a consistent set of algorithms, auxiliary input, and calibrations across platforms are used, instrument and algorithm-induced changes in the data record are minimized. This facilitates the use of the CERES data products for studying climate-scale trends.

430 citations


Journal ArticleDOI
TL;DR: The GEISA database as mentioned in this paper is a computer-accessible system comprising three independent sub-databases devoted, respectively, to: line parameters, infrared and ultraviolet/visible absorption cross-sections, microphysical and optical properties of atmospheric aerosols.
Abstract: The updated 2009 edition of the spectroscopic database GEISA (Gestion et Etude des Informations Spectroscopiques Atmospheriques; Management and Study of Atmospheric Spectroscopic Information) is described in this paper. GEISA is a computer-accessible system comprising three independent sub-databases devoted, respectively, to: line parameters, infrared and ultraviolet/visible absorption cross-sections, microphysical and optical properties of atmospheric aerosols. In this edition, 50 molecules are involved in the line parameters sub-database, including 111 isotopologues, for a total of 3,807,997 entries, in the spectral range from 10−6 to 35,877.031 cm−1. The successful performances of the new generation of hyperspectral sounders depend ultimately on the accuracy to which the spectroscopic parameters of the optically active atmospheric gases are known, since they constitute an essential input to the forward radiative transfer models that are used to interpret their observations. Currently, GEISA is involved in activities related to the assessment of the capabilities of IASI (Infrared Atmospheric Sounding Interferometer; http://smsc.cnes.fr/IASI/index.htm) on board the METOP European satellite through the GEISA/IASI database derived from GEISA. Since the Metop-A (http://www.eumetsat.int) launch (19 October 2006), GEISA is the reference spectroscopic database for the validation of the level-1 IASI data. Also, GEISA is involved in planetary research, i.e., modeling of Titan's atmosphere, in the comparison with observations performed by Voyager, or by ground-based telescopes, and by the instruments on board the Cassini–Huygens mission. GEISA, continuously developed and maintained at LMD (Laboratoire de Meteorologie Dynamique, France) since 1976, is implemented on the IPSL/CNRS (France) “Ether” Products and Services Centre WEB site (http://ether.ipsl.jussieu.fr), where all archived spectroscopic data can be handled through general and user friendly associated management software facilities. More than 350 researchers are registered for on line use of GEISA.

332 citations


Journal ArticleDOI
TL;DR: In this paper, the authors compared 12 large-eddy simulations, with a wide range of microphysical representations, to each other and to independent measurements and the initial and forcing data for the simulations are taken from the undisturbed period of the Rain in Cumulus over the Ocean (RICO) field study.
Abstract: Twelve large-eddy simulations, with a wide range of microphysical representations, are compared to each other and to independent measurements. The measurements and the initial and forcing data for the simulations are taken from the undisturbed period of the Rain in Cumulus over the Ocean (RICO) field study. A regional downscaling of meteorological analyses is performed so as to provide forcing data consistent with the measurements. The ensemble average of the simulations plausibly reproduces many features of the observed clouds, including the vertical structure of cloud fraction, profiles of cloud and rain water, and to a lesser degree the population density of rain drops. The simulations do show considerable departures from one another in the representation of the cloud microphysical structure and the ensuant surface precipitation rates, increasingly so for the more simplified microphysical models. There is a robust tendency for simulations that develop rain to produce a shallower, somewhat more stable cloud layer. Relations between cloud cover and precipitation are ambiguous.

321 citations


Journal ArticleDOI
TL;DR: The VAMOS(1) Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) was an international field program designed to make observations of poorly understood but critical components of the coupled climate system of the southeast Pacific as discussed by the authors.
Abstract: The VAMOS(1) Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) was an international field program designed to make observations of poorly understood but critical components of the coupled climate system of the southeast Pacific. This region is characterized by strong coastal upwelling, the coolest SSTs in the tropical belt, and is home to the largest subtropical stratocumulus deck on Earth. The field intensive phase of VOCALS-REx took place during October and November 2008 and constitutes a critical part of a broader CLIVAR program (VOCALS) designed to develop and promote scientific activities leading to improved understanding, model simulations, and predictions of the southeastern Pacific (SEP) coupled ocean-atmosphere-land system, on diurnal to interannual timescales. The other major components of VOCALS are a modeling program with a model hierarchy ranging from the local to global scales, and a suite of extended observations from regular research cruises, instrumented moorings, and satellites. The two central themes of VOCALS-REx focus upon (a) links between aerosols, clouds and precipitation and their impacts on marine stratocumulus radiative properties, and (b) physical and chemical couplings between the upper ocean and the lower atmosphere, including the role that mesoscale ocean eddies play. A set of hypotheses designed to be tested with the combined field, monitoring and modeling work in VOCALS is presented here. A further goal of VOCALS-REx is to provide datasets for the evaluation and improvement of large-scale numerical models. VOCALS-REx involved five research aircraft, two ships and two surface sites in northern Chile. We describe the instrument pay-loads and key mission strategies for these platforms and give a summary of the missions conducted.

280 citations


Journal ArticleDOI
TL;DR: In this article, the variability of stratospheric aerosol loading between 1985 and 2010 is explored with measurements from SAGE II, CALIPSO, GOMOS/ENVISAT, and OSIRIS/Odin space-based instruments.
Abstract: The variability of stratospheric aerosol loading between 1985 and 2010 is explored with measurements from SAGE II, CALIPSO, GOMOS/ENVISAT, and OSIRIS/Odin space-based instruments. We find that, following the 1991 eruption of Mount Pinatubo, stratospheric aerosol levels increased by as much as two orders of magnitude and only reached "background levels" between 1998 and 2002. From 2002 onwards, a systematic increase has been reported by a number of investigators. Recently, the trend, based on ground-based lidar measurements, has been tentatively attributed to an increase of SO2 entering the stratosphere associated with coal burning in Southeast Asia. However, we demonstrate with these satellite measurements that the observed trend is mainly driven by a series of moderate but increasingly intense volcanic eruptions primarily at tropical latitudes. These events injected sulfur directly to altitudes between 18 and 20 km. The resulting aerosol particles are slowly lofted into the middle stratosphere by the Brewer-Dobson circulation and are eventually transported to higher latitudes.

278 citations


Journal ArticleDOI
13 May 2011-Polymer
TL;DR: In this article, molecular dynamics and molecular mechanics simulations are used to establish well-equilibrated, validated molecular models of the EPON 862-DETDA epoxy system with a range of crosslink densities using a united atom force field.

268 citations


Journal ArticleDOI
TL;DR: The aerosol data were grouped into four categories based on gas-phase composition as mentioned in this paper : diffuse, sulfate-rich aerosol, organic-rich smoke from open biomass fires in southern Russia and southeastern Siberia, and some aerosol layers were dominated by components originating from fossil fuel combustion.
Abstract: . We present an overview of the background, scientific goals, and execution of the Aerosol, Radiation, and Cloud Processes affecting Arctic Climate (ARCPAC) project of April 2008. We then summarize airborne measurements, made in the troposphere of the Alaskan Arctic, of aerosol particle size distributions, composition, and optical properties and discuss the sources and transport of the aerosols. The aerosol data were grouped into four categories based on gas-phase composition. First, the background troposphere contained a relatively diffuse, sulfate-rich aerosol extending from the top of the sea-ice inversion layer to 7.4 km altitude. Second, a region of depleted (relative to the background) aerosol was present within the surface inversion layer over sea-ice. Third, layers of dense, organic-rich smoke from open biomass fires in southern Russia and southeastern Siberia were frequently encountered at all altitudes from the top of the inversion layer to 7.1 km. Finally, some aerosol layers were dominated by components originating from fossil fuel combustion. Of these four categories measured during ARCPAC, the diffuse background aerosol was most similar to the average springtime aerosol properties observed at a long-term monitoring site at Barrow, Alaska. The biomass burning (BB) and fossil fuel layers were present above the sea-ice inversion layer and did not reach the sea-ice surface during the course of the ARCPAC measurements. The BB aerosol layers were highly scattering and were moderately hygroscopic. On average, the layers produced a noontime net heating of ~0.1 K day −1 between 3 and 7 km and a slight cooling at the surface. The ratios of particle mass to carbon monoxide (CO) in the BB plumes, which had been transported over distances >5000 km, were comparable to the high end of literature values derived from previous measurements in wildfire smoke. These ratios suggest minimal precipitation scavenging and removal of the BB particles between the time they were emitted and the time they were observed in dense layers above the sea-ice inversion layer.

Journal ArticleDOI
TL;DR: In this paper, the A-Train constellation is used to estimate the top-of-atmosphere (TOA) and surface shortwave and long-wave irradiances.
Abstract: [1] One year of instantaneous top-of-atmosphere (TOA) and surface shortwave and longwave irradiances are computed using cloud and aerosol properties derived from instruments on the A-Train Constellation: the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) on the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite, the CloudSat Cloud Profiling Radar (CPR), and the Aqua Moderate Resolution Imaging Spectrometer (MODIS). When modeled irradiances are compared with those computed with cloud properties derived from MODIS radiances by a Clouds and the Earth's Radiant Energy System (CERES) cloud algorithm, the global and annual mean of modeled instantaneous TOA irradiances decreases by 12.5 W m−2 (5.0%) for reflected shortwave and 2.5 W m−2 (1.1%) for longwave irradiances. As a result, the global annual mean of instantaneous TOA irradiances agrees better with CERES-derived irradiances to within 0.5W m−2 (out of 237.8 W m−2) for reflected shortwave and 2.6W m−2 (out of 240.1 W m−2) for longwave irradiances. In addition, the global annual mean of instantaneous surface downward longwave irradiances increases by 3.6 W m−2 (1.0%) when CALIOP- and CPR-derived cloud properties are used. The global annual mean of instantaneous surface downward shortwave irradiances also increases by 8.6 W m−2 (1.6%), indicating that the net surface irradiance increases when CALIOP- and CPR-derived cloud properties are used. Increasing the surface downward longwave irradiance is caused by larger cloud fractions (the global annual mean by 0.11, 0.04 excluding clouds with optical thickness less than 0.3) and lower cloud base heights (the global annual mean by 1.6 km). The increase of the surface downward longwave irradiance in the Arctic exceeds 10 W m−2 (∼4%) in winter because CALIOP and CPR detect more clouds in comparison with the cloud detection by the CERES cloud algorithm during polar night. The global annual mean surface downward longwave irradiance of 345.4 W m−2 is estimated by combining the modeled instantaneous surface longwave irradiance computed with CALIOP and CPR cloud profiles with the global annual mean longwave irradiance from the CERES product (AVG), which includes the diurnal variation of the irradiance. The estimated bias error is −1.5 W m−2 and the uncertainty is 6.9 W m−2. The uncertainty is predominately caused by the near-surface temperature and column water vapor amount uncertainties.

Journal ArticleDOI
04 Jun 2011
TL;DR: Directed Incremental Symbolic Execution (DiSE), a novel technique for detecting and characterizing the effects of program changes, to combine the efficiencies of static analysis techniques to compute program difference information with the precision of symbolic execution to explore program execution paths and generate path conditions affected by the differences.
Abstract: The last few years have seen a resurgence of interest in the use of symbolic execution -- a program analysis technique developed more than three decades ago to analyze program execution paths. Scaling symbolic execution and other path-sensitive analysis techniques to large systems remains challenging despite recent algorithmic and technological advances. An alternative to solving the problem of scalability is to reduce the scope of the analysis. One approach that is widely studied in the context of regression analysis is to analyze the differences between two related program versions. While such an approach is intuitive in theory, finding efficient and precise ways to identify program differences, and characterize their effects on how the program executes has proved challenging in practice.In this paper, we present Directed Incremental Symbolic Execution (DiSE), a novel technique for detecting and characterizing the effects of program changes. The novelty of DiSE is to combine the efficiencies of static analysis techniques to compute program difference information with the precision of symbolic execution to explore program execution paths and generate path conditions affected by the differences. DiSE is a complementary technique to other reduction or bounding techniques developed to improve symbolic execution. Furthermore, DiSE does not require analysis results to be carried forward as the software evolves -- only the source code for two related program versions is required. A case-study of our implementation of DiSE illustrates its effectiveness at detecting and characterizing the effects of program changes.

Journal ArticleDOI
TL;DR: In this article, the absolute values of gravity wave momentum flux are derived from global temperature measurements by the satellite instruments High Resolution Dynamics Limb Sounder (HIRDLS) and Sounding of the Atmosphere using Broadband Emission Radiometry (SABER).
Abstract: [1] In this work absolute values of gravity wave (GW) momentum flux are derived from global temperature measurements by the satellite instruments High Resolution Dynamics Limb Sounder (HIRDLS) and Sounding of the Atmosphere using Broadband Emission Radiometry (SABER). Momentum fluxes in the stratosphere are derived for both instruments and for SABER in the whole mesosphere. The large-scale atmospheric background state is removed by a two-dimensional Fourier decomposition in longitude and time, covering even planetary-scale waves with periods as short as 1–2 days. Therefore, it is possible to provide global distributions of GW momentum flux from observations for the first time in the mesosphere. Seasonal as well as longer-term variations of the global momentum flux distribution are discussed. GWs likely contribute significantly to the equatorward tilt of the polar night jet and to the poleward tilt of the summertime mesospheric jet. Our results suggest that GWs can undergo large latitudinal shifts while propagating upward. In particular, GWs generated by deep convection in the subtropical monsoon regions probably contribute significantly to the mesospheric summertime wind reversal at mid- and high latitudes. Variations in the GW longitudinal distribution caused by those convectively generated GWs are still observed in the mesosphere and could be important for the generation of the quasi two-day wave. Indications for quasi-biennial oscillation (QBO) induced variations of GW momentum flux are found in the subtropics. Also variations at time scales of about one 11-year solar cycle are observed and might indicate a negative correlation between solar flux and GW momentum flux.

Journal ArticleDOI
TL;DR: In this article, the initiation and evolution of transverse matrix cracks and delaminations are predicted within a mesh-independent cracking (MIC) framework, which is a regularized extended finite element method (x-FEM) that allows the insertion of cracks in directions that are independent of the mesh orientation.
Abstract: The initiation and evolution of transverse matrix cracks and delaminations are predicted within a mesh-independent cracking (MIC) framework MIC is a regularized extended finite element method (x-FEM) that allows the insertion of cracks in directions that are independent of the mesh orientation The Heaviside step function that is typically used to introduce a displacement discontinuity across a crack surface is replaced by a continuous function approximated by using the original displacement shape functions Such regularization allows the preservation of the Gaussian integration schema regardless of the enrichment required to model cracking in an arbitrary direction The interaction between plies is anchored on the integration point distribution, which remains constant through the entire simulation Initiation and propagation of delaminations between plies as well as intra-ply MIC opening is implemented by using a mixed-mode cohesive formulation in a fully three-dimensional model that includes residual thermal stresses The validity of the proposed methodology was tested against a variety of problems ranging from simple evolution of delamination from existing transverse cracks to strength predictions of complex laminates withouttextita priori knowledge of damage location or initiation Good agreement with conventional numerical solutions and/or experimental data was observed in all the problems considered Published 2011 This article is a US Government work and is in the public domain in the USA

Journal ArticleDOI
TL;DR: In this paper, the authors measured the size distributions of black carbon (BC) and organic aerosols (OA) using an SP2 based on the laser-induced incandescence technique on board the DC-8 aircraft during the NASA ARCTAS campaign.
Abstract: Reliable assessment of the impact of aerosols emitted from boreal forest fires on the Arctic climate necessitates improved understanding of emissions and the microphysical properties of carbonaceous (black carbon (BC) and organic aerosols (OA)) and inorganic aerosols. The size distributions of BC were measured by an SP2 based on the laser-induced incandescence technique on board the DC-8 aircraft during the NASA ARCTAS campaign. Aircraft sampling was made in fresh plumes strongly impacted by wildfires in North America (Canada and California) in summer 2008 and in those transported from Asia (Siberia in Russia and Kazakhstan) in spring 2008. We extracted biomass burning plumes using particle and tracer (CO, CH3CN, and CH2Cl2) data. OA constituted the dominant fraction of aerosols mass in the submicron range. The large majority of the emitted particles did not contain BC. We related the combustion phase of the fire as represented by the modified combustion efficiency (MCE) to the emission ratios between BC and other species. In particular, we derived the average emission ratios of BC/CO = 2.3 +/- 2.2 and 8.5 +/- 5.4 ng/cu m/ppbv for BB in North America and Asia, respectively. The difference in the BC/CO emission ratios is likely due to the difference in MCE. The count median diameters and geometric standard deviations of the lognormal size distribution of BC in the BB plumes were 136-141 nm and 1.32-1.36, respectively, and depended little on MCE. These BC particles were thickly coated, with shell/core ratios of 1.3-1.6. These parameters can be used directly for improving model estimates of the impact of BB in the Arctic.

Journal ArticleDOI
TL;DR: In this paper, the authors estimate that boreal forest fires release 2.4 ± 0.6 Tg C yr−1 in the form of NMVOCs, with approximately 41 % of the carbon released as C1-C2 NMVs and 21 % as pinenes.
Abstract: . Boreal regions comprise about 17 % of the global land area, and they both affect and are influenced by climate change. To better understand boreal forest fire emissions and plume evolution, 947 whole air samples were collected aboard the NASA DC-8 research aircraft in summer 2008 as part of the ARCTAS-B field mission, and analyzed for 79 non-methane volatile organic compounds (NMVOCs) using gas chromatography. Together with simultaneous measurements of CO2, CO, CH4, CH2O, NO2, NO, HCN and CH3CN, these measurements represent the most comprehensive assessment of trace gas emissions from boreal forest fires to date. Based on 105 air samples collected in fresh Canadian smoke plumes, 57 of the 80 measured NMVOCs (including CH2O) were emitted from the fires, including 45 species that were quantified from boreal forest fires for the first time. After CO2, CO and CH4, the largest emission factors (EFs) for individual species were formaldehyde (2.1 ± 0.2 g kg−1), followed by methanol, NO2, HCN, ethene, α-pinene, β-pinene, ethane, benzene, propene, acetone and CH3CN. Globally, we estimate that boreal forest fires release 2.4 ± 0.6 Tg C yr−1 in the form of NMVOCs, with approximately 41 % of the carbon released as C1-C2 NMVOCs and 21 % as pinenes. These are the first reported field measurements of monoterpene emissions from boreal forest fires, and we speculate that the pinenes, which are relatively heavy molecules, were detected in the fire plumes as the result of distillation of stored terpenes as the vegetation is heated. Their inclusion in smoke chemistry models is expected to improve model predictions of secondary organic aerosol (SOA) formation. The fire-averaged EF of dichloromethane or CH2Cl2, (6.9 ± 8.6) × 10−4 g kg−1, was not significantly different from zero and supports recent findings that its global biomass burning source appears to have been overestimated. Similarly, we found no evidence for emissions of chloroform (CHCl3) or methyl chloroform (CH3CCl3) from boreal forest fires. The speciated hydrocarbon measurements presented here show the importance of carbon released by short-chain NMVOCs, the strong contribution of pinene emissions from boreal forest fires, and the wide range of compound classes in the most abundantly emitted NMVOCs, all of which can be used to improve biomass burning inventories in local/global models and reduce uncertainties in model estimates of trace gas emissions and their impact on the atmosphere.

Journal ArticleDOI
TL;DR: In this article, the authors present the main results from the second model intercomparison within the GEWEX (Global Energy and Water cycle EXperiment) Atmospheric Boundary Layer Study (GABLS).
Abstract: We present the main results from the second model intercomparison within the GEWEX (Global Energy and Water cycle EXperiment) Atmospheric Boundary Layer Study (GABLS). The target is to examine the diurnal cycle over land in today’s numerical weather prediction and climate models for operational and research purposes. The set-up of the case is based on observations taken during the Cooperative Atmosphere-Surface Exchange Study-1999 (CASES-99), which was held in Kansas, USA in the early autumn with a strong diurnal cycle with no clouds present. The models are forced with a constant geostrophic wind, prescribed surface temperature and large-scale divergence. Results from 30 different model simulations and one large-eddy simulation (LES) are analyzed and compared with observations. Even though the surface temperature is prescribed, the models give variable near-surface air temperatures. This, in turn, gives rise to differences in low-level stability affecting the turbulence and the turbulent heat fluxes. The increase in modelled upward sensible heat flux during the morning transition is typically too weak and the growth of the convective boundary layer before noon is too slow. This is related to weak modelled near-surface winds during the morning hours. The agreement between the models, the LES and observations is the best during the late afternoon. From this intercomparison study, we find that modelling the diurnal cycle is still a big challenge. For the convective part of the diurnal cycle, some of the first-order schemes perform somewhat better while the turbulent kinetic energy (TKE) schemes tend to be slightly better during nighttime conditions. Finer vertical resolution tends to improve results to some extent, but is certainly not the solution to all the deficiencies identified.

Journal ArticleDOI
TL;DR: In this article, a variety of grid systems (both structured and unstructured) were used, and trends due to flap angle were analyzed, and effects of grid family, grid density, solver, and turbulence model were addressed.
Abstract: CFD results. A variety of grid systems (both structured and unstructured) were used. Trends due to flap angle were analyzed, and effects of grid family, grid density, solver, and turbulence model were addressed. Some participants alsoassessed theeffects of supportbrackets used toattach the flapandslatto themain wing.Thispaper analyzesthe combined results from all workshop participants. Comparisons with experimental data are made. A statistical summary of the CFD results is also included.

Journal ArticleDOI
TL;DR: The first four years of the CALIPSO lidar measurements have revealed the existence of an aerosol layer at the tropopause level associated with the Asian monsoon season in June, July and August as discussed by the authors.
Abstract: The first four years of the CALIPSO lidar measurements have revealed the existence of an aerosol layer at the tropopause level associated with the Asian monsoon season in June, July and August. This Asian Tropopause Aerosol Layer (ATAL) extends geographically from Eastern Mediterranean (down to North Africa) to Western China (down to Thailand), and vertically from 13 to 18 km. The Scattering Ratio inferred from CALIPSO shows values between 1.10. 1.15 on average with associated depolarization ratio of less than 5%. The Gaussian distribution of the points indicates that the mean value is statistically driven by an enhancement of the background aerosol level and not by episodic events such as a volcanic eruption or cloud contamination. Further satellite observations of aerosols and gases as well as field campaigns are urgently needed to characterize this layer, which is likely to be a significant source of non-volcanic aerosols for the global upper troposphere with a potential impact on its radiative and chemical balance

Journal ArticleDOI
TL;DR: In this paper, the authors summarized recent improvements in the development of bulk scattering/absorption models at solar wavelengths and combined microphysical measurements from various field campaigns with single-scattering properties for nine habits including droxtals, plates, solid/hollow columns, solid-hollow bullet rosettes, and several types of aggregates.
Abstract: This study summarizes recent improvements in the development of bulk scattering/absorption models at solar wavelengths. The approach combines microphysical measurements from various field campaigns with single-scattering properties for nine habits including droxtals, plates, solid/hollow columns, solid/hollow bullet rosettes, and several types of aggregates. Microphysical measurements are incorporated from a number of recent field campaigns in both the Northern and Southern Hemisphere. A set of 12 815 particle size distributions is used for which Tcld ≤ −40°C. The ice water content in the microphysical data spans six orders of magnitude. For evaluation, a library of ice-particle single-scattering properties is employed for 101 wavelengths between 0.4 and 2.24 μm. The library includes the full phase matrix as well as properties for smooth, moderately roughened, and severely roughened particles. Habit mixtures are developed for generalized cirrus, midlatitude cirrus, and deep tropical convection. Th...

Journal ArticleDOI
TL;DR: In this article, the in situ aircraft-derived cloud property values were constructed from the drop size distributions measured by the Cloud Droplet Probe (drop diameter <52 micron) and Two-Dimensional Cloud Probe (two-dimensional cloud probe) during 20 vertical profiles during the Chile-Peru stratocumulus cloud deck during October-November 2008 were used to assess MODIS Level 2 cloud property retrievals.
Abstract: [1] Cloud microphysical observations collected in situ during the VAMOS Ocean-Cloud-Atmosphere-Land Study Regional Experiment within the Chile-Peru stratocumulus cloud deck during October–November 2008 were used to assess MODIS Level 2 cloud property retrievals. The in situ aircraft-derived cloud property values were constructed from the drop size distributions measured by the Cloud Droplet Probe (drop diameter <52 micron) and Two-Dimensional Cloud Probe (drop diameters up to 1600 micron) during 20 vertical profiles. Almost all of the MODIS cloud scenes were highly homogeneous. MODIS cloud optical thickness correlated well with the aircraft-derived value with a slight offset within instrumental/retrieval uncertainties. In contrast, the standard 2.1 micron-derived MODIS effective radius (re) systematically exceeded the in situ cloud top reby 15%–20%, for an absolute error that increased with droplet size. The individual effective radius retrievals at 1.6, 2.1, and 3.7 micron did not provide additional information on cloud vertical structure for our data sample. The secondarily derived MODIS liquid water path also exceeded the in situ value. A MODIS-derived cloud droplet number concentration (Nd) estimate agreed the best of the four MODIS variables with the aircraft observations. The analysis also highlighted a lack of agreement in published satellite-derivedNd values, despite drawing on the same sources. A best a priori formula choice for Nd is likely to vary regionally. Four sources of errors within the MODIS reretrieval were investigated further: the cloud mode droplet size distribution breadth, the presence of a drizzle mode, above-cloud water vapor absorption, and sensor viewing angles. These processes combined conspired to explain most of the observed bias. The above-cloud water vapor paths were poorly specified, primarily because the cloud top heights are placed too high, and secondarily because the water vapor paths are unrealistic. Improvement of the above-cloud water vapor path specification can most easily and systematically improve the MODIS effective radius and liquid water path retrievals.

Journal ArticleDOI
TL;DR: In this paper, the development of L1 adaptive-control theory and its application to safety critical flight control system (FCS) development is presented, and several architectures of the theory and benchmark examples are analyzed.
Abstract: This article presents the development of L1 adaptive-control theory and its application to safety critical flight control system (FCS) development. Several architectures of the theory and benchmark examples are analyzed. The key feature of L1 adaptive-control architectures is the decoupling of estimation and control, which enables the use of arbitrarily fast estimation rates without sacrificing robustness. Rohrs's example and the two-cart system are used as benchmark problems for illustration. NASA's flight tests on subscale commercial jet verify the theoretical claims in a set of safety-critical test flights.

Journal ArticleDOI
TL;DR: In this article, the amount of light-absorbing organic carbon and black carbon from AERONET measurements is estimated, showing that the columnar ab- sorbing carbon (brown carbon) levels in biomass burning regions of South America and Africa are relatively high (about 15-20 mg m 2 during biomass burning season), while the concentrations are significantly lower in urban ar- eas in US and Europe.
Abstract: Black carbon, light-absorbing organic carbon (of- ten called "brown carbon") and mineral dust are the ma- jor light-absorbing aerosols. Currently the sources and formation of brown carbon aerosol in particular are not well understood. In this study we estimated the amount of light-absorbing organic carbon and black carbon from AERONET measurements. We find that the columnar ab- sorbing organic carbon (brown carbon) levels in biomass burning regions of South America and Africa are relatively high (about 15-20 mg m 2 during biomass burning season), while the concentrations are significantly lower in urban ar- eas in US and Europe. However, we estimated significant ab- sorbing organic carbon amounts from the data of megacities of newly industrialized countries, particularly in India and China, showing also clear seasonality with peak values up to 30-35 mg m 2 during the coldest season, likely caused by the coal and biofuel burning used for heating. We also com- pared our retrievals with the modeled organic carbon by the global Oslo CTM for several sites. Model values are higher in biomass burning regions than AERONET-based retrievals, while the opposite is true in urban areas in India and China.

Journal ArticleDOI
TL;DR: In this paper, the authors investigated the impact of missing or discarded high-resolution data on the integrity of the Baseline Surface Radiation Network (BSRN) radiation monthly averages by investigating the impact on monthly means due to the frequency of data gaps caused by missing or discard high time resolution data.
Abstract: . The integrity of the Baseline Surface Radiation Network (BSRN) radiation monthly averages are assessed by investigating the impact on monthly means due to the frequency of data gaps caused by missing or discarded high time resolution data. The monthly statistics, especially means, are considered to be important and useful values for climate research, model performance evaluations and for assessing the quality of satellite (time- and space-averaged) data products. The study investigates the spread in different algorithms that have been applied for the computation of monthly means from 1-min values. The paper reveals that the computation of monthly means from 1-min observations distinctly depends on the method utilized to account for the missing data. The intra-method difference generally increases with an increasing fraction of missing data. We found that a substantial fraction of the radiation fluxes observed at BSRN sites is either missing or flagged as questionable. The percentage of missing data is 4.4%, 13.0%, and 6.5% for global radiation, direct shortwave radiation, and downwelling longwave radiation, respectively. Most flagged data in the shortwave are due to nighttime instrumental noise and can reasonably be set to zero after correcting for thermal offsets in the daytime data. The study demonstrates that the handling of flagged data clearly impacts on monthly mean estimates obtained with different methods. We showed that the spread of monthly shortwave fluxes is generally clearly higher than for downwelling longwave radiation. Overall, BSRN observations provide sufficient accuracy and completeness for reliable estimates of monthly mean values. However, the value of future data could be further increased by reducing the frequency of data gaps and the number of outliers. It is shown that two independent methods for accounting for the diurnal and seasonal variations in the missing data permit consistent monthly means to within less than 1 W m−2 in most cases. The authors suggest using a standardized method for the computation of monthly means which addresses diurnal variations in the missing data in order to avoid a mismatch of future published monthly mean radiation fluxes from BSRN. The application of robust statistics would probably lead to less biased results for data records with frequent gaps and/or flagged data and outliers. The currently applied empirical methods should, therefore, be completed by the development of robust methods.

Journal ArticleDOI
TL;DR: Cloud properties were retrieved by applying the Clouds and Earth's Radiant Energy System (CERES) project Edition-2 algorithms to 3.5 years of Tropical Rainfall Measuring Mission Visible and Infrared Scanner data and 5.5 and 8 years of MODerate Resolution Imaging Spectroradiometer (MODIS) data from Aqua and Terra.
Abstract: Cloud properties were retrieved by applying the Clouds and Earth's Radiant Energy System (CERES) project Edition-2 algorithms to 3.5 years of Tropical Rainfall Measuring Mission Visible and Infrared Scanner data and 5.5 and 8 years of MODerate Resolution Imaging Spectroradiometer (MODIS) data from Aqua and Terra, respectively. The cloud products are consistent quantitatively from all three imagers; the greatest discrepancies occur over ice-covered surfaces. The retrieved cloud cover (~59%) is divided equally between liquid and ice clouds. Global mean cloud effective heights, optical depth, effective particle sizes, and water paths are 2.5 km, 9.9, 12.9 μm , and 80 g·m-2, respectively, for liquid clouds and 8.3 km, 12.7, 52.2 μm, and 230 g·m-2 for ice clouds. Cloud droplet effective radius is greater over ocean than land and has a pronounced seasonal cycle over southern oceans. Comparisons with independent measurements from surface sites, the Ice Cloud and Land Elevation Satellite, and the Aqua Advanced Microwave Scanning Radiometer-Earth Observing System are used to evaluate the results. The mean CERES and MODIS Atmosphere Science Team cloud properties have many similarities but exhibit large discrepancies in certain parameters due to differences in the algorithms and the number of unretrieved cloud pixels. Problem areas in the CERES algorithms are identified and discussed.

01 Jul 2011
TL;DR: The Multi-Attribute Task Battery (MAT Battery), a computer-based task designed to evaluate operator performance and workload, has been redeveloped to operate in Windows XP Service Pack 3, Windows Vista and Windows 7 operating systems.
Abstract: The Multi-Attribute Task Battery (MAT Battery). is a computer-based task designed to evaluate operator performance and workload, has been redeveloped to operate in Windows XP Service Pack 3, Windows Vista and Windows 7 operating systems.MATB-II includes essentially the same tasks as the original MAT Battery, plus new configuration options including a graphical user interface for controlling modes of operation. MATB-II can be executed either in training or testing mode, as defined by the MATB-II configuration file. The configuration file also allows set up of the default timeouts for the tasks, the flow rates of the pumps and tank levels of the Resource Management (RESMAN) task. MATB-II comes with a default event file that an experimenter can modify and adapt

Journal ArticleDOI
TL;DR: In this article, a new physical-geometric optics hybrid (PGOH) method is developed to compute the scattering and absorption properties of ice particles, which is suitable for studying the optical properties of icicles with arbitrary orientations, complex refractive indices (i.e., particles with significant absorption), and size parameters (proportional to the ratio of particle size to incident wavelength) larger than ∼20.
Abstract: A new physical-geometric optics hybrid (PGOH) method is developed to compute the scattering and absorption properties of ice particles. This method is suitable for studying the optical properties of ice particles with arbitrary orientations, complex refractive indices (i.e., particles with significant absorption), and size parameters (proportional to the ratio of particle size to incident wavelength) larger than ∼20, and includes consideration of the edge effects necessary for accurate determination of the extinction and absorption efficiencies. Light beams with polygon-shaped cross sections propagate within a particle and are traced by using a beam-splitting technique. The electric field associated with a beam is calculated using a beam-tracing process in which the amplitude and phase variations over the wavefront of the localized wave associated with the beam are considered analytically. The geometric-optics near field for each ray is obtained, and the single-scattering properties of particles are calculated from electromagnetic integral equations. The present method does not assume additional physical simplifications and approximations, except for geometric optics principles, and may be regarded as a “benchmark” within the framework of the geometric optics approach. The computational time is on the order of seconds for a single-orientation simulation and is essentially independent of the size parameter. The single-scattering properties of oriented hexagonal ice particles (ice plates and hexagons) are presented. The numerical results are compared with those computed from the discrete-dipole-approximation (DDA) method.

Journal ArticleDOI
TL;DR: Airborne measurements of CO(2) column abundance conducted during two 2009 campaigns using a 2.05 μm laser absorption spectrometer provide insight into the capabilities of the IPDA method for both airborne measurements and future global-scale CO( 2) measurements from low Earth orbit pertinent to the NASA Active Sensing of CO (2) Emissions over Nights, Days, and Seasons mission.
Abstract: We report airborne measurements of CO2 column abundance conducted during two 2009 campaigns using a 2.05 μm laser absorption spectrometer. The two flight campaigns took place in the California Mojave desert and in Oklahoma. The integrated path differential absorption (IPDA) method is used for the CO2 column mixing ratio retrievals. This instrument and the data analysis methodology provide insight into the capabilities of the IPDA method for both airborne measurements and future global-scale CO2 measurements from low Earth orbit pertinent to the NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons mission. The use of a favorable absorption line in the CO22 μm band allows the on-line frequency to be displaced two (surface pressure) half-widths from line center, providing high sensitivity to the lower tropospheric CO2. The measurement repeatability and measurement precision are in good agreement with predicted estimates. We also report comparisons with airborne in situ measurements conducted during the Oklahoma campaign.

Journal ArticleDOI
TL;DR: In this article, the authors identify the pathways and mechanisms of transport of black carbon aerosol to the Arctic from the Asian continent using these data, and demonstrate that the impact of biomass burning (BB) emitted from East Asia on the Arctic was very limited in both spring and summer.
Abstract: [1] Extensive measurements of black carbon (BC) aerosol were conducted in and near the North American Arctic during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) aircraft campaign in April and June–July 2008. We identify the pathways and mechanisms of transport of BC to the Arctic from the Asian continent using these data. The concentration, transport efficiency, and measured altitude of BC over the North American Arctic were highly dependent on season and origin of air parcels, e.g., biomass burning (BB) in Russia (Russian BB) and anthropogenic (AN) in East Asia (Asian AN). Russian BB air was mainly measured in the middle troposphere and caused maximum BC concentrations at this altitude in spring. The median BC concentration and transport efficiency of the Russian BB air were 270 ng m−3 (at STP) and 80% in spring and 20 ng m−3 and 4% in summer, respectively. Asian AN air was measured most frequently in the upper troposphere, with median values of 20 ng m−3 and 13% in spring and 5 ng m−3 and 0.8% in summer. These distinct differences are explained by differences in the transport mechanisms and accumulated precipitation along trajectories (APT), which is a measure of wet removal processes during transport. The transport of Russian BB air to the Arctic was nearly isentropic with slow ascent (low APT), while Asian AN air underwent strong uplift associated with warm conveyor belts (high APT). The APT values in summer were much larger than those in spring due to the increase in humidity in summer. These results show that the impact of BC emitted from AN sources in East Asia on the Arctic was very limited in both spring and summer. The BB emissions in Russia in spring are demonstrated to be the most important sources of BC transported to the North American Arctic.