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Institution

Lehigh University

EducationBethlehem, Pennsylvania, United States
About: Lehigh University is a education organization based out in Bethlehem, Pennsylvania, United States. It is known for research contribution in the topics: Catalysis & Fracture mechanics. The organization has 12684 authors who have published 26550 publications receiving 770061 citations.


Papers
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Journal ArticleDOI
14 Jan 2011-Science
TL;DR: It is reported here that supported gold-palladium nanoparticles on carbon or TiO2 are active for the oxidation of the primary carbon-hydrogen bonds in toluene and related molecules, giving high selectivities to benzyl benzoate under mild solvent-free conditions.
Abstract: Selective oxidation of primary carbon-hydrogen bonds with oxygen is of crucial importance for the sustainable exploitation of available feedstocks. To date, heterogeneous catalysts have either shown low activity and/or selectivity or have required activated oxygen donors. We report here that supported gold-palladium (Au-Pd) nanoparticles on carbon or TiO2 are active for the oxidation of the primary carbon-hydrogen bonds in toluene and related molecules, giving high selectivities to benzyl benzoate under mild solvent-free conditions. Differences between the catalytic activity of the Au-Pd nanoparticles on carbon and TiO2 supports are rationalized in terms of the particle/support wetting behavior and the availability of exposed corner/edge sites.

678 citations

Journal ArticleDOI
TL;DR: In this paper, the elastic stress field equations for blunt cracks are derived and presented in a form equivalent to the usual sharp crack tip stress fields, which are employed in analyzing a dissolution model for the arrest of stress corrosion cracking by crack tip blunting.
Abstract: The elastic stress field equations for blunt cracks are derived and presented in a form equivalent to the usual sharp crack tip stress fields. These stress field equations are employed in analyzing a dissolution model for the arrest of stress corrosion cracking by crack tip blunting, which is often observed with the arrest of stress corrosion cracks.

656 citations

Journal ArticleDOI
TL;DR: In this paper, the similarities and differences in structural characteristics and physico-chemical properties between titania-silica mixed and supported oxides are emphasized, and the generation of new catalytic active sites either on the silica surface or in the matrix is discussed with respect to the formation of Ti-O-Si bonds and the local structure.

649 citations

Journal ArticleDOI
TL;DR: In this article, a comparison of the molecular structure and reactivity information of supported vanadium oxide catalysts is presented, which provides new fundamental insights into the catalytic properties of surface vanadia species during hydrocarbon oxidation reactions.
Abstract: Supported vanadium oxide catalysts, containing surface vanadia species on oxide supports, are extensively employed as catalysts for many hydrocarbon oxidation reactions. This paper discusses the current fundamental information available about the structure and reactivity of surface vanadia species on oxide supports: monolayer surface coverage, stability of the surface vanadia monolayer, oxidation state of the surface vanadia species, molecular structures of the surface vanadia species (as a function of environment and catalyst composition), acidity of the surface vanadia species and reactivity of the surface vanadia species. Comparison of the molecular structure and reactivity information provides new fundamental insights into the catalytic properties of surface vanadia species during hydrocarbon oxidation reactions: (1) the role of terminal VO, bridging VOV and bridging VO-support bonds, (2) the number of surface vanadia sites required, (3) the influence of metal oxide additives, (4) the influence of surface acidic and basic sites, (5) the influence of preparation methods and (6) the influence of the specific oxide support phase. The unique physical and chemical characteristics of supported vanadia catalysts, compared to other supported metal oxide catalysts, for hydrocarbon oxidation reactions are also discussed.

644 citations

Journal ArticleDOI
TL;DR: In this paper, the influence of recommendations on consumer decision making during online shopping experiences was examined and it was found that consumers use the mere availability of peer recommendations as a decision-making heuristic, irrespective of the peer recommender's personal characteristics.

641 citations


Authors

Showing all 12785 results

NameH-indexPapersCitations
Yang Yang1712644153049
Gang Chen1673372149819
Yi Yang143245692268
Mark D. Griffiths124123861335
Michael Gill12181086338
Masaki Mori110220066676
Kai Nan An10995351638
James R. Rice10827868943
Vinayak P. Dravid10381743612
Andrew M. Jones10376437253
Israel E. Wachs10342732029
Demetrios N. Christodoulides10070451093
Bert M. Weckhuysen10076740945
José Luis García Fierro100102747228
Mordechai Segev9972940073
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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
202338
2022140
20211,040
20201,054
2019933
2018935