Lehigh University

About: Lehigh University is a education organization based out in Bethlehem, Pennsylvania, United States. It is known for research contribution in the topics: Catalysis & Fracture mechanics. The organization has 12684 authors who have published 26550 publications receiving 770061 citations.

Within the Accountability Era: Principals' Instructional Leadership Behaviors and Student Achievement:

Abstract: Researchers randomly selected Pennsylvania public middle level schools to identify significant relationships between principals' instructional leadership behaviors and student achievement, with school socioeconomic status (SES) as a secondary variable of interest. For each participant school, four teachers and the principal were asked to complete Hallinger's (1987) Principal Instructional Management Rating Scale. This instrument includes 50 behaviors that have been identified by the research on effective schools. Data analysis includes achievement test data from the Pennsylvania System of School Assessment. Findings indicate that teacher perceptions of principal behaviors focused on improving school learning climate were identified as predictors of student achievement. In addition, principals of schools with high SES who believe they frequently exhibit behaviors associated with defining their schools' respective missions are related to higher reading achievement.

"Rainbow" trapping and releasing at telecommunication wavelengths.

Abstract: The reported "trapped rainbow" storage of THz light in metamaterials and plasmonic graded structures has opened an attractive new method to control electromagnetic radiation Here, we show how, by incorporating the frequency-dependent dielectric properties of the metal, the graded grating structures developed for "trapped rainbow" storage of THz light in mum level can be scaled to nm level for telecommunication waves for applications in optical communication and various nanophotonic circuits

Volcanic arcs fed by rapid pulsed fluid flow through subducting slabs

Abstract: During subduction, the seawater-altered lithosphere becomes dehydrated and expels fluids. Isotopic analysis of an exhumed oceanic slab in the Tianshan Mountain Range shows that although subduction can continue for many millions of years, fluids are expelled in short-lived channels over periods of just a few hundred years. At subduction zones, oceanic lithosphere that has interacted with sea water is returned to the mantle, heats up during descent and releases fluids by devolatilization of hydrous minerals. Models for the formation of magmas feeding volcanoes above subduction zones require largescale transport of these fluids into overlying mantle wedges1,2,3. Fluid flow also seems to be linked to seismicity in subducting slabs. However, the spatial and temporal scales of this fluid flow remain largely unknown, with suggested timescales ranging from tens to tens of thousands of years3,4,5. Here we use the Li–Ca–Sr isotope systems to consider fluid sources and quantitatively constrain the duration of subduction-zone fluid release at ∼ 70 km depth within subducting oceanic lithosphere, now exhumed in the Chinese Tianshan Mountains. Using lithium-diffusion modelling, we find that the wall-rock porosity adjacent to the flowpath of the fluids increased ten times above the background level. We show that fluids released by devolatilization travelled through the slab along major conduits in pulses with durations of about ∼ 200 years. Thus, although the overall slab dehydration process is continuous over millions of years and over a wide range of pressures and temperatures, we conclude that the fluids produced by dehydration in subducting slabs are mobilized in short-lived, channelized fluid-flow events.

Methanol: A “Smart” Chemical Probe Molecule

Abstract: A novel chemisorption method was employed for the dissociative adsorption of methanol to surface methoxy intermediates in order to quantitatively determine the number of surface active sites on one-component metal oxide catalysts (MgO, CaO, SrO, BaO, Y2O3, La2O3, CeO2, TiO2, ZrO2, HfO2, V2O5, Nb2O5, Ta2O5, Cr2O3, MoO3, WO3, Mn2O3, Fe2O3, Co3O4, Rh2O3, NiO, PdO, PtO, CuO, Ag2O, Au2O3, ZnO, Al2O3, Ga2O3, In2O3, SiO2, GeO2, SnO2, P2O5, Sb2O3, Bi2O3, SeO2 and TeO2). The number of surface active sites for methanol dissociative adsorption corresponds to ∼3 μmol/m2 on average for many of the metal oxide catalysts. Furthermore, the methanol oxidation product distribution at low conversions reflects the nature of the surface active sites on metal oxides since redox sites yield H2CO, acidic sites yield CH3OCH3 and basic sites yield CO2. The distribution of the different types of surface active sites was found to vary widely for the different metal oxide catalysts. In addition, the commonality of the surface methoxy intermediate during dissociative chemisorption of methanol and methanol oxidation on oxide catalysts also allows for the quantitative determination of the turnover frequency (TOF) values. The TOF values for the various metal oxide catalysts were found to vary over seven orders of magnitude (10−3 to 104 s−1). An inverse relationship (for metal oxide catalysts displaying high (>85%) selectivity to either redox or acidic products) was found between the methanol oxidation TOF values and the decomposition temperatures of the surface M–OCH3 intermediates reflecting that the decomposition of the surface M–OCH3 species is the rate-determining step during methanol oxidation over the metal oxide catalysts.