Showing papers by "Manchester Metropolitan University published in 2011"

The RCP greenhouse gas concentrations and their extensions from 1765 to 2300

Abstract: We present the greenhouse gas concentrations for the Representative Concentration Pathways (RCPs) and their extensions beyond 2100, the Extended Concentration Pathways (ECPs). These projections include all major anthropogenic greenhouse gases and are a result of a multi-year effort to produce new scenarios for climate change research. We combine a suite of atmospheric concentration observations and emissions estimates for greenhouse gases (GHGs) through the historical period (1750-2005) with harmonized emissions projected by four different Integrated Assessment Models for 2005-2100. As concentrations are somewhat dependent on the future climate itself (due to climate feedbacks in the carbon and other gas cycles), we emulate median response characteristics of models assessed in the IPCC Fourth Assessment Report using the reduced-complexity carbon cycle climate model MAGICC6. Projected 'best-estimate' global-mean surface temperature increases (using inter alia a climate sensitivity of 3°C) range from 1.5°C by 2100 for the lowest of the four RCPs, called both RCP3-PD and RCP2.6, to 4.5°C for the highest one, RCP8.5, relative to pre-industrial levels. Beyond 2100, we present the ECPs that are simple extensions of the RCPs, based on the assumption of either smoothly stabilizing concentrations or constant emissions: For example,

Emulating coupled atmosphere-ocean and carbon cycle models with a simpler model, MAGICC6 - Part 1: Model description and calibration

Abstract: Current scientific knowledge on the future response of the climate system to human-induced perturbations is comprehensively captured by various model intercomparison efforts In the preparation of the Fourth Assessment Report (AR4) of the Intergovernmental Panel on Climate Change (IPCC), intercomparisons were organized for atmosphere-ocean general circulation models (AOGCMs) and carbon cycle models, named "CMIP3" and "C 4 MIP", respectively Despite their tremendous value for the scientific community and policy makers alike, there are some difficulties in interpreting the results For example, radiative forcings were not standardized across the various AOGCM integrations and carbon cycle runs, and, in some models, key forcings were omitted Furthermore, the AOGCM analysis of plausible emissions pathways was restricted to only three SRES scenarios This study attempts to address these issues We present an updated version of MAGICC, the simple carbon cycle-climate model used in past IPCC Assessment Reports with enhanced representation of time-varying climate sensitivities, carbon cycle feedbacks, aerosol forcings and ocean heat uptake characteristics This new version, MAGICC6, is successfully calibrated against the higher complexity AOGCMs and carbon cycle models Parameterizations of MAGICC6 are provided The mean of the emulations presented here using MAGICC6 deviates from the mean AOGCM responses by only 22% on average for the SRES scenarios This enhanced emulation skill in comparison to previous calibrations is primarily due to: making a "like-with-like comparison" using AOGCM-specific subsets of forcings; employing a new calibration procedure; as well as the fact that the updated simple climate model can now successfully emulate some of the climate-state dependent effective climate sensitivities of AOGCMs The diagnosed effective climate sensitivity at the time of CO 2 doubling for the AOGCMs is on average 288 °C, about 033 °C cooler than the mean of the reported slab ocean climate sensitivities In the companion paper (Part 2) of this study, we examine the combined climate system and carbon cycle emulations for the complete range of IPCC SRES emissions scenarios and the new RCP pathways

Nonthermal Plasma Inactivation of Food-Borne Pathogens

Abstract: Nonthermal plasma (NTP) is electrically energized matter and is composed of highly reactive species including gas molecules, charged particles in the form of positive ions, negative ions, free radicals, electrons and quanta of electromagnetic radiation (photons) at near-room temperature. NTP technology is an emerging nonthermal technology with potential applications for sterilization in the food industries. An upsurge in the research activities for plasma-based inactivation of food-borne pathogens is evident in recent years. These studies have shown that NTP can be used for the surface decontamination of raw produce including; dried nuts and packaging materials. This paper reviews the action of plasma agents on the microbial classes and describes proven and potential applications in food processing. Novel developments in the technology and a future outlook for the application to foods are discussed.

New directions in screen printed electroanalytical sensors: an overview of recent developments.

Abstract: Screen printing is widely used to fabricate disposable and economical electrochemical sensors and has helped us to establish the route from ‘lab-to-market’ for a plethora of sensors We overview recent developments in the field where screen printed electrochemical sensors are utilised Starting with their fundamental understanding, through to highlighting new developments in bulk metal and mediator modified electrodes, as well as novel advantageous electrode designs, we demonstrate the wide and diverse range of applications that sensors based on this fabrication approach have achieved

Aeolian processes and the biosphere

Abstract: Ravi, S., D'Odorico, P., Breshears, D. D., Field, J. P., Goudie, A. S., Huxman, T. E., Li, J., Okin, G. S., Swap, R. J., Thomas, A. D., Pelt, S. V., Whicker, J. J., Zobeck, T. M. (2011). Aeolian processes and the biosphere. Reviews of Geophysics, 49 (3).

Entrepreneurial marketing in small businesses: A conceptual exploration:

Abstract: This article proposes further development of the concept of entrepreneurial marketing towards the concept of entrepreneurial marketing orientation. Drawing on the earlier research and scales in the entrepreneurial orientation, market orientation, innovation orientation and customer orientation literatures, the article proposes a conceptual model for entrepreneurial marketing that identifies the components of such a model, together with specific indications of the overlap between scales in the different areas. This model implicitly suggests that marketing in SMEs is intertwined with other activities and behaviours in the small business enterprise, and argues that in order to understand marketing in SMEs it is essential to understand its context, specifically in relation to customer engagement, innovation and entrepreneurial approaches to marketing.

Electrochemical capacitors utilising transition metal oxides: an update of recent developments

Abstract: Transition metal oxides receive considerable attention in the area of electrochemistry not only due to their beneficial reported structural, mechanical or electronic properties, but because of their capacitive properties ascribed to their multiple oxide states they exhibit pseudo capacitances which carbon counterparts generally cannot. Typically transition metal oxides may be classified as noble transition metal oxides which exhibit excellent capacitive properties but have the drawback of generally being relatively expensive. Alternatively base metal oxides may also be utilised which are considerably cheaper and more environment friendly than noble transition metals as well as exhibiting good capacitive properties. In considering that nanostructured materials can help ameliorate the electrochemical performances of transition metal oxides, this review summarizes the recent investigations of fundamental advances in understanding the electrochemical reactivity of transition metal oxides, thus leading to an improved capacitive performance, which is essential for their continual use in a plethora of supercapacitor applications.

Towards a strategic place brand-management model

Abstract: Using earlier research into models of place branding-management processes, this paper develops a multi-level conceptual model of strategic place brand management designed to support managers in embracing a holistic approach to place brand management. The model identifies the following components for attention and activity: place brand evaluation; brand infrastructure relationships, including infrastructure (regeneration) and stakeholder engagement (management); place brand articulation; and brand communications. The model identifies the influences and action processes between these components, including brand identity and architecture, influencing brand experience. Existing place branding models take different perspectives on the branding process – respectively, relationship management, communications, and strategic planning; none of these models are comprehensive and neither are they widely adopted or tested. This paper proposes an integrative model that builds on and subsumes these earlier mode...

Effects of extrusion on the polyphenols, vitamins and antioxidant activity of foods

Abstract: Greater consumer demand for nutritious extruded food products with enhanced bioactive compounds has shifted research focus towards incorporation of bioactive rich ingredients with traditionally extruded starch materials. Recent research has highlighted the importance of bioactive compounds in human health and nutrition. An evaluation of the available literature reveals that the level of bioactive compounds in extruded products is influenced by extrusion process variables. Shear, temperature, resonance time and water content are all factors which contribute to the overall composition of extruded products. In addition, food structure may also exhibit a role in the potential release of functional bioactives. This paper reviews the effect of extrusion on bioactive compounds such as phenolic compounds, anthocyanins, isoflavones and their antioxidant activity. Factors influencing levels and stability during extrusion are also discussed.

Intermittent control: a computational theory of human control

Abstract: The paradigm of continuous control using internal models has advanced understanding of human motor control. However, this paradigm ignores some aspects of human control, including intermittent feedback, serial ballistic control, triggered responses and refractory periods. It is shown that event-driven intermittent control provides a framework to explain the behaviour of the human operator under a wider range of conditions than continuous control. Continuous control is included as a special case, but sampling, system matched hold, an intermittent predictor and an event trigger allow serial open-loop trajectories using intermittent feedback. The implementation here may be described as “continuous observation, intermittent action”. Beyond explaining unimodal regulation distributions in common with continuous control, these features naturally explain refractoriness and bimodal stabilisation distributions observed in double stimulus tracking experiments and quiet standing, respectively. Moreover, given that human control systems contain significant time delays, a biological-cybernetic rationale favours intermittent over continuous control: intermittent predictive control is computationally less demanding than continuous predictive control. A standard continuous-time predictive control model of the human operator is used as the underlying design method for an event-driven intermittent controller. It is shown that when event thresholds are small and sampling is regular, the intermittent controller can masquerade as the underlying continuous-time controller and thus, under these conditions, the continuous-time and intermittent controller cannot be distinguished. This explains why the intermittent control hypothesis is consistent with the continuous control hypothesis for certain experimental conditions.

Human control of an inverted pendulum: Is continuous control necessary? Is intermittent control effective? Is intermittent control physiological?

Abstract: Non-technical summary Homeostasis, the physiological control of variables such as body position, is founded on negative feedback mechanisms. The default understanding, consistent with a wealth of knowledge related to peripheral reflexes, is that feedback mechanisms controlling body position act continuously. For more than fifty years, it has been assumed that sustained control of position is best interpreted using continuous paradigms from engineering control theory such as those which regulate speed in a vehicle ‘cruise control’ system. Using a joystick to control an unstable load that falls over like a person fainting, we show that control using intermittent gentle taps is natural, more effective and robust to unexpected changes than continuous hand contact, works best with two taps per second, and can explain the upper frequency limit of control by both methods. Serial ballistic control, limited to an optimum rate, provides a new physiological paradigm for interpreting sustained control of posture and movement.

Raman spectroscopy for the analysis of coal: a review

Abstract: The advances in the characterization of amorphous carbons by Raman spectroscopy over the last four decades are of interest to many industries, especially those involving the combustion, gasification and pyrolysis of coal. Many researchers report on the Raman character of the natural organic matter in carbon-containing compounds, such as coal, and relate the Raman bands to the structural order of the amorphous carbons. The basis of most of these studies evolved around the assignment of the G (graphitic, ∼1580 cm−1) band to crystalline graphite and any other bands, called D bands, (disorder, various from 1100 to 1500 cm−1) to any type of structural disorder in the graphitic structure. Concerning coal analysis, the information gained by Raman investigations has been used to describe char evolution as a function of temperature, the presence of catalysts and different gasification conditions. In addition, researchers looked at maturation, grade, doppleritization and many more aspects of interest. One aspect that has, however, not been addressed by most of the researchers is the natural inorganic matter (NIM) in the carbon-containing compounds. Micro-Raman spectroscopy (MRS) has many advantages over other characterization tools, i.e. in situ analysis, nondestructive, no sample preparation, low detection limit, micrometer-scale characterization, versatility and sensitivity to many amorphous compounds. With the distinct advantages it has over that of other molecular characterization tools, such as powder X-ray diffraction (PXRD), Fourier-transform infrared spectrometry (FT-IR) and scanning electron microscopy with X-ray detection (SEM/EDS), it is surprising that it has not yet been fully exploited up to this point for the characterization of the NIM in coal and other amorphous carbons. This paper reviews the work published on the Raman characterization of the natural organic matter (NOM) of coals and reports on preliminary results of the NIM character of various South African coals, whereby various inorganic compounds and minerals in the coal have been characterized. Copyright © 2010 John Wiley & Sons, Ltd.

Electrochemistry of graphene : not such a beneficial electrode material?

Abstract: We critically evaluate the reported electro-catalysis of graphene using inner-sphere and outer-sphere electrochemical redox probes, namely potassium ferrocyanide (II) and hexaammine-ruthenium(III) chloride, in addition to L-ascorbic acid and β-nicotinamide adenine dinucleotide. Well characterised commercially available graphene is utilised which has not been chemically treated, is free from surfactants, and as a result of its fabrication has an extremely low oxygen content allowing the electronic properties to be properly de-convoluted. Surprisingly we observe that graphene exhibits slow electron transfer towards the electrochemical probes studied, effectively blocking underlying electron transfer of the supporting electrode substrate likely due to its large basal and low edge plane content. Such observations, never reported before, suggest that graphene may not be such a beneficial electrode material as widely reported in the literature. Density Functional Theory is conducted on symmetric graphene flakes of varying sizes indicating that the HOMO and LUMO energies are concentrated around the edge of the graphene sheet, at the edge plane sites, rather than the central basal plane region, consistent with experimental observations. We define differentiating coverage-based working regions for the electrochemical utilisation of graphene: ‘Zone I’, where graphene additions do not result in complete coverage of the underlying electrode and thus increasing basal contribution from graphene modification leads to increasingly reduced electron transfer and electrochemical activity; ‘Zone II’, once complete single-layer coverage is achieved, layered graphenevizgraphite materialises with increased edge plane content and thus an increase in heterogeneous electron transfer is observed with increased layering. We offer insight into the electrochemical properties of these carbon materials, invaluable where electrode design for electrochemical sensing applications is sought.

Towards an innovation‐type mapping tool

Abstract: Purpose – Seeking to distil and integrate a range of previous definitions, models, frameworks and classifications relating to types of innovation, this paper aims to make a contribution to clarity in innovation research and practice through offering insights into the definitions of the different types of innovation, and, specifically, the relationships between them.Design/methodology/approach – This theoretical paper is based on a review of extant models and frameworks of types of innovation, which includes earlier foundation models, and more recent integrative models.Findings – This distillation results in a diagrammatic representation of the key frameworks, which is used as a platform to propose a new framework of types of innovation.Originality/value – This paper draws on all the terminologies used for types of innovation and creates an innovation type‐mapping tool that can be used to clarify the various definitions and terminologies of the innovation type concept.

Disuse of the musculo-skeletal system in space and on earth

Abstract: Muscle mass and strength are well known to decline in response to actual and simulated microgravity exposure. However, despite the considerable knowledge gained on the physiological changes induced by spaceflight, the mechanisms of muscle atrophy and the effectiveness of in-flight countermeasures still need to be fully elucidated. The present review examines the effects and mechanisms of actual and simulated microgravity on single fibre and whole muscle structural and functional properties, protein metabolism, tendon mechanical properties, neural drive and reflex excitability. The effects of inflight countermeasures are also discussed in the light of recent advances in resistive loading techniques, in combined physical, pharmacological and nutritional interventions as well as in the development of artificial gravity systems. Emphasis has been given to the pioneering work of Pietro Enrico di Prampero in the development of artificial gravity systems and in the progress of knowledge on the limits of human muscular performance in space.

Graduate entrepreneurship in the developing world: intentions, education and development

Abstract: Purpose – The purpose of this paper is to introduce the special issue by positioning and examining some of the key issues, tensions and challenges in graduate entrepreneurship in the developing world.Design/methodology/approach – The paper recognises the complexity and diversity of approaches considered by the different authors, highlighting a range of issues and challenges in their contributions. The paper is divided into the following sections: entrepreneurial intentions, attitudes and motivations; the role of higher education; and contextual cases, opportunities and challenges in graduate entrepreneurship.Findings – The paper suggests that there is a lack of research in the field of graduate entrepreneurship in the developing world, and that further research in developing countries may help to understand and shed light on the issues evolving around graduate entrepreneurial intentions, business start‐up and education. Some preliminary themes emerge from research included in this special issue. First, en...

Conservative biomechanical strategies for knee osteoarthritis

Abstract: Knee osteoarthritis (OA) is one of the most prevalent forms of this disease, with the medial compartment most commonly affected. The direction of external forces and limb orientation during walking results in an adduction moment that acts around the knee, and this parameter is regarded as a surrogate measure of medial knee compression. The knee adduction moment is intimately linked with the development and progression of knee OA and is, therefore, a target for conservative biomechanical intervention strategies, which are the focus of this Review. We examine the evidence for walking barefoot and the use of lateral wedge insoles and thin-soled, flexible shoes to reduce the knee adduction moment in patients with OA. We review strategies that directly affect the gait, such as walking with the foot externally rotated ('toe-out gait'), using a cane, lateral trunk sway and gait retraining. Valgus knee braces and muscle strengthening are also discussed for their effect upon reducing the knee adduction moment.

Emulating atmosphere-ocean and carbon cycle models with a simpler model, MAGICC6 – Part 2: Applications

Abstract: . Intercomparisons of coupled atmosphere-ocean general circulation models (AOGCMs) and carbon cycle models are important for galvanizing our current scientific knowledge to project future climate. Interpreting such intercomparisons faces major challenges, not least because different models have been forced with different sets of forcing agents. Here, we show how an emulation approach with MAGICC6 can address such problems. In a companion paper (Meinshausen et al., 2011a), we show how the lower complexity carbon cycle-climate model MAGICC6 can be calibrated to emulate, with considerable accuracy, globally aggregated characteristics of these more complex models. Building on that, we examine here the Coupled Model Intercomparison Project's Phase 3 results (CMIP3). If forcing agents missed by individual AOGCMs in CMIP3 are considered, this reduces ensemble average temperature change from pre-industrial times to 2100 under SRES A1B by 0.4 °C. Differences in the results from the 1980 to 1999 base period (as reported in IPCC AR4) to 2100 are negligible, however, although there are some differences in the trajectories over the 21st century. In a second part of this study, we consider the new RCP scenarios that are to be investigated under the forthcoming CMIP5 intercomparison for the IPCC Fifth Assessment Report. For the highest scenario, RCP8.5, relative to pre-industrial levels, we project a median warming of around 4.6 °C by 2100 and more than 7 °C by 2300. For the lowest RCP scenario, RCP3-PD, the corresponding warming is around 1.5 °C by 2100, decreasing to around 1.1 °C by 2300 based on our AOGCM and carbon cycle model emulations. Implied cumulative CO2 emissions over the 21st century for RCP8.5 and RCP3-PD are 1881 GtC (1697 to 2034 GtC, 80% uncertainty range) and 381 GtC (334 to 488 GtC), when prescribing CO2 concentrations and accounting for uncertainty in the carbon cycle. Lastly, we assess the reasons why a previous MAGICC version (4.2) used in IPCC AR4 gave roughly 10% larger warmings over the 21st century compared to the CMIP3 average. We find that forcing differences and the use of slightly too high climate sensitivities inferred from idealized high-forcing runs were the major reasons for this difference.

Iron in Earth Surface Systems: A Major Player in Chemical and Biological Processes

Abstract: As an essential nutrient and energy source for the growth of microbial organisms, iron is metabolically cycled between reduced and oxidized chemical forms. The resulting flow of electrons is invariably tied to reactions with other redox-sensitive elements, including oxygen, carbon, nitrogen, and sulfur. Therefore, iron is intimately involved in the geochemistry, mineralogy, and petrology of modern aquatic systems and their associated sediments, particulates, and porewaters. In the geological past, iron played an even greater role in marine geochemistry, as evidenced by the vast deposits of Precambrian iron-rich sediments, the “banded iron formations.” These deposits are now being used as proxies for understanding the chemical composition of the ancient oceans and atmosphere.

Evidence-based resistance training recommendations

Abstract: Resistance training produces an array of health benefits, as well as the potential to promote muscular adaptations of strength, size, power and endurance. The American College of Sports Medicine (ACSM) regularly publish a position stand making recommendations for optimal achievement of the desired training goals. However, the most recent position stand (as well as previous ones) has come under heavy criticism for misrepresentation of research, lack of evidence and author bias. Therefore this paper proposes a set of scientifically rigorous resistance training guidelines, reviewing and summarising the relevant research for the purpose of proposing more logical, evidence-based training advice. We recommend that appreciably the same muscular strength and endurance adaptations can be attained by performing a single set of ~8-12 repetitions to momentary muscular failure, at a repetition duration that maintains muscular tension throughout the entire range of motion, for most major muscle groups once or twice each week. All resistance types (e.g. free-weights, resistance machines, bodyweight, etc.) show potential for increases in strength, with no significant difference between them, although resistance machines appear to pose a lower risk of injury. There is a lack of evidence to suggest that balance from free weights or use of unstable surfaces shows any transference to sporting improvement, and explosive movements are also not recommended as they present a high injury risk and no greater benefit than slow, controlled weight training. Finally, we consider genetic factors in relation to body type and growth potential.

Trace Metals as Biomarkers for Eumelanin Pigment in the Fossil Record

Abstract: Well-preserved fossils of pivotal early bird and nonavian theropod species have provided unequivocal evidence for feathers and/or downlike integuments. Recent studies have reconstructed color on the basis of melanosome structure; however, the chemistry of these proposed melanosomes has remained unknown. We applied synchrotron x-ray techniques to several fossil and extant organisms, including Confuciusornis sanctus, in order to map and characterize possible chemical residues of melanin pigments. Results show that trace metals, such as copper, are present in fossils as organometallic compounds most likely derived from original eumelanin. The distribution of these compounds provides a long-lived biomarker of melanin presence and density within a range of fossilized organisms. Metal zoning patterns may be preserved long after melanosome structures have been destroyed.