Missouri University of Science and Technology

About: Missouri University of Science and Technology is a education organization based out in Rolla, Missouri, United States. It is known for research contribution in the topics: Control theory & Artificial neural network. The organization has 9380 authors who have published 21161 publications receiving 462544 citations. The organization is also known as: Missouri S&T & University of Missouri–Rolla.

Demographic impacts on environmentally friendly purchase behaviors

Abstract: Researchers have continued to study green consumer demographics with mixed results. The relevant literature since 1998 (the last review) was summarized to determine what demographics seemed to impact environmental purchasing. The greatest consistency was found for gender with women more likely to exhibit green behaviors. This research article analyzed survey responses to determine the environmentally friendly behaviors of consumers and their relationships to demographics. Several demographics were found to be related to a number of specific environmentally friendly behaviors, more than in prior research. The authors concluded that using specific behaviors, in contrast to general statements or attitudes, may be more sensitive to the effects of demographics.

3D Janus Plasmonic Helical Nanoapertures for Polarization-Encrypted Data Storage

Abstract: Helical structures have attracted considerable attention due to their inherent optical chirality. Here, we report a unique type of 3D Janus plasmonic helical nanoaperture with direction-controlled polarization sensitivity, which is simply fabricated via the one-step grayscale focused ion beam milling method. Circular dichroism in transmission of as large as 0.72 is experimentally realized in the forward direction due to the spin-dependent mode coupling process inside the helical nanoaperture. However, in the backward direction, the nanoaperture acquires giant linear dichroism in transmission of up to 0.87. By encoding the Janus metasurface with the two nanoaperture enantiomers having specified rotation angles, direction-controlled polarization-encrypted data storage is demonstrated for the first time, where a binary quick-response code image is displayed in the forward direction under the circularly polarized incidence of a specified handedness, while a distinct grayscale image is revealed in the backward direction under linearly polarized illumination with a specified azimuthal angle. We envision that the proposed Janus helical nanoapertures will provide an appealing platform for a variety of applications, which will range from multifunctional polarization control, enantiomer sensing, data encryption and decryption to optical information processing.

A versatile tripodal Cu(I) reagent for C-N bond construction via nitrene-transfer chemistry: catalytic perspectives and mechanistic insights on C-H aminations/amidinations and olefin aziridinations.

Abstract: A CuI catalyst (1), supported by a framework of strongly basic guanidinato moieties, mediates nitrene-transfer from PhI═NR sources to a wide variety of aliphatic hydrocarbons (C–H amination or amidination in the presence of nitriles) and olefins (aziridination). Product profiles are consistent with a stepwise rather than concerted C–N bond formation. Mechanistic investigations with the aid of Hammett plots, kinetic isotope effects, labeled stereochemical probes, and radical traps and clocks allow us to conclude that carboradical intermediates play a major role and are generated by hydrogen-atom abstraction from substrate C–H bonds or initial nitrene-addition to one of the olefinic carbons. Subsequent processes include solvent-caged radical recombination to afford the major amination and aziridination products but also one-electron oxidation of diffusively free carboradicals to generate amidination products due to carbocation participation. Analyses of metal- and ligand-centered events by variable temperat...

Rejection sensitivity and social outcomes of young adult men with ADHD

Abstract: Objective: Attention-Deficit/Hyperactivity Disorder (ADHD) has been consistently linked to social maladjustment. This study investigated whether elevated rejection sensitivity (RS) could contribute to the relational problems that adults with ADHD encounter. Method: Undergraduate men in ADHD-Combined Type (ADHD-C; n = 31), ADHD-Primarily Inattentive Type (ADHD-IA; n = 22), and nondiagnosed control (NC; n = 25) groups completed questionnaires concerning RS, relational history, current relationships, and self-esteem. Results: The hypothesis that those with ADHD would have elevated RS (versus NC peers) was not supported. However, low RS predicted divergent outcomes across groups. Furthermore, ADHD-IA men reported more negative relational outcomes than their ADHD-C peers, although both groups reported lower general self-esteem than controls. Conclusion: Perhaps the positive illusory bias associated with childhood ADHD could buffer RS development. Findings provide evidence of ADHD-related impairment in adult relationships, further differentiate the principal ADHD subtypes, and extend the RS literature to this clinical population.