Showing papers by "Moscow State University published in 2009"

Ionic high-pressure form of elemental boron

Abstract: Boron is an element of fascinating chemical complexity. This arises from frustration: situated between metals and insulators in the periodic table, boron has only three valence electrons that could in principle favour metallicity, yet they are sufficiently localized to give rise to an insulating state. This delicately balanced electronic structure is easily modified by pressure, temperature and impurities, making it difficult to establish boron's structure and properties. Oganov et al. have now explored the high-pressure behaviour of boron and uncovered a previously unknown ionic phase consisting of negatively charged icosahedral B12 clusters and positively charged B2 pairs. The ionicity of the new phase strongly affects many of its properties, and arises from the different electronic properties of the B12 clusters and B2 pairs and the resultant charge transfer between them. This paper has explored the high-pressure behaviour of boron and uncovered a new phase that consists of negatively charged icosahedral B12 clusters and positively charged B2 pairs. The ionicity of the new phase strongly affects many of its properties, and arises from the different electronic properties of the B12 clusters and B2 pairs and the resultant charge transfer between them. Boron is an element of fascinating chemical complexity. Controversies have shrouded this element since its discovery was announced in 1808: the new ‘element’ turned out to be a compound containing less than 60–70% of boron, and it was not until 1909 that 99% pure boron was obtained1. And although we now know of at least 16 polymorphs2, the stable phase of boron is not yet experimentally established even at ambient conditions3. Boron’s complexities arise from frustration: situated between metals and insulators in the periodic table, boron has only three valence electrons, which would favour metallicity, but they are sufficiently localized that insulating states emerge. However, this subtle balance between metallic and insulating states is easily shifted by pressure, temperature and impurities. Here we report the results of high-pressure experiments and ab initio evolutionary crystal structure predictions4,5 that explore the structural stability of boron under pressure and, strikingly, reveal a partially ionic high-pressure boron phase. This new phase is stable between 19 and 89 GPa, can be quenched to ambient conditions, and has a hitherto unknown structure (space group Pnnm, 28 atoms in the unit cell) consisting of icosahedral B12 clusters and B2 pairs in a NaCl-type arrangement. We find that the ionicity of the phase affects its electronic bandgap, infrared adsorption and dielectric constants, and that it arises from the different electronic properties of the B2 pairs and B12 clusters and the resultant charge transfer between them.

Transparent dense sodium.

Abstract: Under pressure, metals exhibit increasingly shorter interatomic distances. Intuitively, this response is expected to be accompanied by an increase in the widths of the valence and conduction bands and hence a more pronounced free-electron-like behaviour. But at the densities that can now be achieved experimentally, compression can be so substantial that core electrons overlap. This effect dramatically alters electronic properties from those typically associated with simple free-electron metals such as lithium (Li; refs 1-3) and sodium (Na; refs 4, 5), leading in turn to structurally complex phases and superconductivity with a high critical temperature. But the most intriguing prediction-that the seemingly simple metals Li (ref. 1) and Na (ref. 4) will transform under pressure into insulating states, owing to pairing of alkali atoms-has yet to be experimentally confirmed. Here we report experimental observations of a pressure-induced transformation of Na into an optically transparent phase at approximately 200 GPa (corresponding to approximately 5.0-fold compression). Experimental and computational data identify the new phase as a wide bandgap dielectric with a six-coordinated, highly distorted double-hexagonal close-packed structure. We attribute the emergence of this dense insulating state not to atom pairing, but to p-d hybridizations of valence electrons and their repulsion by core electrons into the lattice interstices. We expect that such insulating states may also form in other elements and compounds when compression is sufficiently strong that atomic cores start to overlap strongly.

Superhard Monoclinic Polymorph of Carbon

Abstract: We report a novel phase of carbon possessing a monoclinic $C2/m$ structure ($8\text{ }\text{ }\mathrm{\text{atoms}}/\mathrm{\text{cell}}$) identified using an ab initio evolutionary structural search. This polymorph, which we call $M$-carbon, is related to the ($2\ifmmode\times\else\texttimes\fi{}1$) reconstruction of the (111) surface of diamond and can also be viewed as a distorted (through sliding and buckling of the sheets) form of graphite. It is stable over cold-compressed graphite above 13.4 GPa. The simulated x-ray diffraction pattern and near $K$-edge spectroscopy are in satisfactory agreement with the experimental data [W. L. Mao et al., Science 302, 425 (2003)] on overcompressed graphite. The hardness and bulk modulus of this new carbon polymorph are calculated to be 83.1 and 431.2 GPa, respectively, which are comparable to those of diamond.

Global observations of the interstellar interaction from the Interstellar Boundary Explorer (IBEX)

Abstract: The Sun moves through the local interstellar medium, continuously emitting ionized, supersonic solar wind plasma and carving out a cavity in interstellar space called the heliosphere. The recently launched Interstellar Boundary Explorer (IBEX) spacecraft has completed its first all-sky maps of the interstellar interaction at the edge of the heliosphere by imaging energetic neutral atoms (ENAs) emanating from this region. We found a bright ribbon of ENA emission, unpredicted by prior models or theories, that may be ordered by the local interstellar magnetic field interacting with the heliosphere. This ribbon is superposed on globally distributed flux variations ordered by both the solar wind structure and the direction of motion through the interstellar medium. Our results indicate that the external galactic environment strongly imprints the heliosphere.

An upper limit on the stochastic gravitational-wave background of cosmological origin

Abstract: A stochastic background of gravitational waves is expected to arise from a superposition of a large number of unresolved gravitational-wave sources of astrophysical and cosmological origin. It should carry unique signatures from the earliest epochs in the evolution of the Universe, inaccessible to standard astrophysical observations. Direct measurements of the amplitude of this background are therefore of fundamental importance for understanding the evolution of the Universe when it was younger than one minute. Here we report limits on the amplitude of the stochastic gravitational-wave background using the data from a two-year science run of the Laser Interferometer Gravitational-wave Observatory (LIGO). Our result constrains the energy density of the stochastic gravitational-wave background normalized by the critical energy density of the Universe, in the frequency band around 100 Hz, to be <6.9 times 10-6 at 95% confidence. The data rule out models of early Universe evolution with relatively large equation-of-state parameter, as well as cosmic (super)string models with relatively small string tension that are favoured in some string theory models. This search for the stochastic background improves on the indirect limits from Big Bang nucleosynthesis and cosmic microwave background at 100 Hz.

The Borexino detector at the Laboratori Nazionali del Gran Sasso

Abstract: Borexino, a large volume detector for low energy neutrino spectroscopy, is currently running underground at the Laboratori Nazionali del Gran Sasso, Italy. The main goal of the experiment is the real-time measurement of sub-MeV solar neutrinos, and particularly of the monoenergetic (862 keV) 7 Be electron capture neutrinos, via neutrino–electron scattering in an ultra-pure liquid scintillator. This paper is mostly devoted to the description of the detector structure, the photomultipliers, the electronics, and the trigger and calibration systems. The real performance of the detector, which always meets, and sometimes exceeds, design expectations, is also shown. Some important aspects of the Borexino project, i.e. the fluid handling plants, the purification techniques and the filling procedures, are not covered in this paper and are, or will be, published elsewhere (see Introduction and Bibliography).

IBEX-Interstellar Boundary Explorer

Abstract: The Interstellar Boundary Explorer (IBEX) is a small explorer mission that launched on 19 October 2008 with the sole, focused science objective to discover the global interaction between the solar wind and the interstellar medium. IBEX is designed to achieve this objective by answering four fundamental science questions: (1) What is the global strength and structure of the termination shock, (2) How are energetic protons accelerated at the termination shock, (3) What are the global properties of the solar wind flow beyond the termination shock and in the heliotail, and (4) How does the interstellar flow interact with the heliosphere beyond the heliopause? The answers to these questions rely on energy-resolved images of energetic neutral atoms (ENAs), which originate beyond the termination shock, in the inner heliosheath. To make these exploratory ENA observations IBEX carries two ultra-high sensitivity ENA cameras on a simple spinning spacecraft. IBEX’s very high apogee Earth orbit was achieved using a new and significantly enhanced method for launching small satellites; this orbit allows viewing of the outer heliosphere from beyond the Earth’s relatively bright magnetospheric ENA emissions. The combination of full-sky imaging and energy spectral measurements of ENAs over the range from ∼10 eV to 6 keV provides the critical information to allow us to achieve our science objective and understand this global interaction for the first time. The IBEX mission was developed to provide the first global views of the Sun’s interstellar boundaries, unveiling the physics of the heliosphere’s interstellar interaction, providing a deeper understanding of the heliosphere and thereby astrospheres throughout the galaxy, and creating the opportunity to make even greater unanticipated discoveries.

Chemical vapour deposition: Making graphene on a large scale

Abstract: Graphene samples with areas of several square centimetres and excellent electrical and optical properties have been fabricated using chemical vapour deposition.

Observation of single top-quark production

Abstract: We report observation of the electroweak production of single top quarks in pp collisions at s=1.96 TeV based on 2.3 fb(-1) of data collected by the D0 detector at the Fermilab Tevatron Collider. Using events containing an isolated electron or muon and missing transverse energy, together with jets originating from the fragmentation of b quarks, we measure a cross section of sigma(pp -> tb+X,tqb+X)=3.94 +/- 0.88 pb. The probability to measure a cross section at this value or higher in the absence of signal is 2.5x10(-7), corresponding to a 5.0 standard deviation significance for the observation.

Quark and Gluon Form Factors to Three Loops

Abstract: We compute the form factors of the photon-quark-anti-quark vertex and the effective vertex of a Higgs-boson and two gluons to three-loop order within massless perturbative quantum chromodynamics. These results provide building blocks for many third-order cross sections. Furthermore, this is the first calculation of complete three-loop vertex corrections.

Energy spectra of abundant nuclei of primary cosmic rays from the data of ATIC-2 experiment: Final results

Abstract: The final results of processing the data from the balloon-born experiment ATIC-2 (Antarctica, 2002–2003) for the energy spectra of protons and He, C, O, Ne, Mg, Si, and Fe nuclei, the spectrum of all particles, and the mean logarithm of atomic weight of primary cosmic rays as a function of energy are presented. The final results are based on improvement of the methods used earlier, in particular, considerably increased resolution of the charge spectrum. The preliminary conclusions on the significant difference in the spectra of protons and helium nuclei (the proton spectrum is steeper) and the non-power character of the spectra of protons and heavier nuclei (flattening of carbon spectrum at energies above 10 TeV) are confirmed. A complex structure of the energy dependence of the mean logarithm of atomic weight is found.

Filamentation of high-power femtosecond laser radiation

Abstract: The state of the art of investigations on filamentation of a high-power femtosecond laser radiation in transparent media is reviewed. The physical picture of this phenomenon is presented and its relation to the fundamental concepts of nonlinear optics and practical applications is demonstrated. Experimental and theoretical methods are briefly considered and laser radiation parameters in the case of filamentation are given. The review can be of interest both for specialists and researches wanting to become familiar with a new, rapidly developing direction in laser physics.

A Novel Class of Modular Transporters for Vitamins in Prokaryotes

Abstract: The specific and tightly controlled transport of numerous nutrients and metabolites across cellular membranes is crucial to all forms of life. However, many of the transporter proteins involved have yet to be identified, including the vitamin transporters in various human pathogens, whose growth depends strictly on vitamin uptake. Comparative analysis of the ever-growing collection of microbial genomes coupled with experimental validation enables the discovery of such transporters. Here, we used this approach to discover an abundant class of vitamin transporters in prokaryotes with an unprecedented architecture. These transporters have energy-coupling modules comprised of a conserved transmembrane protein and two nucleotide binding proteins similar to those of ATP binding cassette (ABC) transporters, but unlike ABC transporters, they use small integral membrane proteins to capture specific substrates. We identified 21 families of these substrate capture proteins, each with a different specificity predicted by genome context analyses. Roughly half of the substrate capture proteins (335 cases) have a dedicated energizing module, but in 459 cases distributed among almost 100 gram-positive bacteria, including numerous human pathogens, different and unrelated substrate capture proteins share the same energy-coupling module. The shared use of energy-coupling modules was experimentally confirmed for folate, thiamine, and riboflavin transporters. We propose the name energy-coupling factor transporters for the new class of membrane transporters.

New Measures for Performance Evaluation

Abstract: This paper characterizes performance measures satisfying a set of proposed axioms. We develop four new measures consistent with the axioms and show that they improve on the economic properties of the Sharpe Ratio and the Gain-Loss Ratio. In our treatment, the performance measures, or the indexes of acceptability, are linked to positive expectations resulting from a stressed sampling of the cash-flow distribution. Theoretically, it is shown that the level of acceptability varies directly with the amount of stress tolerated. In an empirical application, the performance measures are applied to cash flows generated by writing options on the SPX and the FTSE. This exercise reveals that acceptability levels are U-shaped in the strike direction. The Author 2008. Published by Oxford University Press on behalf of The Society for Financial Studies. All rights reserved. For Permissions, please e-mail: journals.permissions@oxfordjournals.org, Oxford University Press.

Comparative genomic analyses of nickel, cobalt and vitamin B12 utilization.

Abstract: Nickel (Ni) and cobalt (Co) are trace elements required for a variety of biological processes. Ni is directly coordinated by proteins, whereas Co is mainly used as a component of vitamin B12. Although a number of Ni and Co-dependent enzymes have been characterized, systematic evolutionary analyses of utilization of these metals are limited. We carried out comparative genomic analyses to examine occurrence and evolutionary dynamics of the use of Ni and Co at the level of (i) transport systems, and (ii) metalloproteomes. Our data show that both metals are widely used in bacteria and archaea. Cbi/NikMNQO is the most common prokaryotic Ni/Co transporter, while Ni-dependent urease and Ni-Fe hydrogenase, and B12-dependent methionine synthase (MetH), ribonucleotide reductase and methylmalonyl-CoA mutase are the most widespread metalloproteins for Ni and Co, respectively. Occurrence of other metalloenzymes showed a mosaic distribution and a new B12-dependent protein family was predicted. Deltaproteobacteria and Methanosarcina generally have larger Ni- and Co-dependent proteomes. On the other hand, utilization of these two metals is limited in eukaryotes, and very few of these organisms utilize both of them. The Ni-utilizing eukaryotes are mostly fungi (except saccharomycotina) and plants, whereas most B12-utilizing organisms are animals. The NiCoT transporter family is the most widespread eukaryotic Ni transporter, and eukaryotic urease and MetH are the most common Ni- and B12-dependent enzymes, respectively. Finally, investigation of environmental and other conditions and identity of organisms that show dependence on Ni or Co revealed that host-associated organisms (particularly obligate intracellular parasites and endosymbionts) have a tendency for loss of Ni/Co utilization. Our data provide information on the evolutionary dynamics of Ni and Co utilization and highlight widespread use of these metals in the three domains of life, yet only a limited number of user proteins.

The OPERA experiment in the CERN to Gran Sasso neutrino beam

Abstract: The OPERA neutrino oscillation experiment has been designed to prove the appearance of ντ in a nearly pure νμ beam (CNGS) produced at CERN and detected in the underground Hall C of the Gran Sasso Laboratory, 730 km away from the source. In OPERA, τ leptons resulting from the interaction of ντ are produced in target units called bricks made of nuclear emulsion films interleaved with lead plates. The OPERA target contains 150000 of such bricks, for a total mass of 1.25 kton, arranged into walls interleaved with plastic scintillator strips. The detector is split into two identical supermodules, each supermodule containing a target section followed by a magnetic spectrometer for momentum and charge measurement of penetrating particles. Real time information from the scintillators and the spectrometers provide the identification of the bricks where the neutrino interactions occurred. The candidate bricks are extracted from the walls and, after X-ray marking and an exposure to cosmic rays for alignment, their emulsion films are developed and sent to the emulsion scanning laboratories to perform the accurate scan of the event. In this paper, we review the design and construction of the detector and of its related infrastructures, and report on some technical performances of the various components. The construction of the detector started in 2003 and it was completed in Summer 2008. The experiment is presently in the data taking phase. The whole sequence of operations has proven to be successful, from triggering to brick selection, development, scanning and event analysis.

Physical and ecological changes associated with warming permafrost and thermokarst in Interior Alaska

Abstract: Observations and measurements were made of physical and ecological changes that have occurred since 1985 at a tundra site near Healy, Alaska. Air temperatures decreased (1985 through 1999) while permafrost warmed and thawed creating thermokarst terrain, probably as a result of increased snow depths. Permafrost, active layer and ground-ice conditions at the Healy site are the result of the interaction of climatic, ecologic and other factors. The slow accumulation of ground ice in an intermediate permafrost layer formed by upward freezing from the permafrost surface leads to long-term differential frost heave and microrelief. When ground ice in the permafrost melts, the ground surface settles differentially resulting in thermokarst terrain (pits, gullies). Windblown snow fills the thermokarst depressions causing further warming and thawing of the underlying permafrost — a positive feedback effect that enhances permafrost degradation. Thermokarst-induced changes in relief alter the near-surface hydrology and ecological processes. Changes in vegetation included differential tussock growth and mortality and a shift in moss species abundance and relative productivity, depending on microtopographic position created by the thermokarst terrain. Water redistribution towards thermokarst depressions caused adjacent higher areas to become drier and resulted in increased moss mortality and shrub abundance. Copyright # 2009 John Wiley & Sons, Ltd.

Novel High Pressure Structures of Polymeric Nitrogen

Abstract: The search for the stable monatomic forms of solid nitrogen is of great importance in view of its potential application as a high-energy-density material. Based on the results of evolutionary structure searches, we proposed two high-pressure polymeric structures to be stable beyond the stability field of the synthesized cubic gauche structure--the layered Pba2 or Iba2 (188-320 GPa) and the helical tunnel P2_{1}2_{1}2_{1} structure (>320 GPa). We rule out the low-temperature stability of the earlier proposed black phosphorus structure. Stability fields of the newly predicted polymorphs are within the reach of current experimental techniques.

Electroexcitation of Nucleon Resonances from CLAS Data on Single Pion Electroproduction

Abstract: We present results on the electroexcitation of the low mass resonances $\ensuremath{\Delta}(1232){P}_{33}$, $N(1440){P}_{11}$, $N(1520){D}_{13}$, and $N(1535){S}_{11}$ in a wide range of ${Q}^{2}$. The results were obtained in the comprehensive analysis of data from the Continuous Electron Beam Accelerator Facility (CEBAF) large acceptance spectrometer (CLAS) detector at the Thomas Jefferson National Accelerator Facility (JLab) on differential cross sections, longitudinally polarized beam asymmetries, and longitudinal target and beam-target asymmetries for $\ensuremath{\pi}$ electroproduction off the proton. The data were analyzed using two conceptually different approaches---fixed-$t$ dispersion relations and a unitary isobar model---allowing us to draw conclusions on the model sensitivity of the obtained electrocoupling amplitudes. The amplitudes for the $\ensuremath{\Delta}(1232){P}_{33}$ show the importance of a meson-cloud contribution to quantitatively explain the magnetic dipole strength, as well as the electric and scalar quadrupole transitions. They do not show any tendency of approaching the pQCD regime for ${Q}^{2}\ensuremath{\leqslant}6$ GeV${}^{2}$. For the Roper resonance, $N(1440){P}_{11}$, the data provide strong evidence that this state is a predominantly radial excitation of a three-quark ($3q$) ground state. Measured in pion electroproduction, the transverse helicity amplitude for the $N(1535){S}_{11}$ allowed us to obtain the branching ratios of this state to the $\ensuremath{\pi}N$ and $\ensuremath{\eta}N$ channels via comparison with the results extracted from $\ensuremath{\eta}$ electroproduction. The extensive CLAS data also enabled the extraction of the ${\ensuremath{\gamma}}^{*}p\ensuremath{\rightarrow}N(1520){D}_{13}$ and $N(1535){S}_{11}$ longitudinal helicity amplitudes with good precision. For the $N(1535){S}_{11}$, these results became a challenge for quark models and may be indicative of large meson-cloud contributions or of representations of this state that differ from a $3q$ excitation. The transverse amplitudes for the $N(1520){D}_{13}$ clearly show the rapid changeover from helicity-3/2 dominance at the real photon point to helicity-1/2 dominance at ${Q}^{2}g1$ GeV${}^{2}$, confirming a long-standing prediction of the constituent quark model.

Measurement of D ± and D 0 production in deep inelastic scattering using a lifetime tag at HERA

Abstract: The production of D-+/-- and D-0-mesons has been measured with the ZEUS detector at HERA using an integrated luminosity of 133.6 pb(-1). The measurements cover the kinematic range 5 < Q(2) < 1000 GeV2, 0.02 < y < 0.7, 1.5 < p(T)(D) < 15 GeV and |eta(D)| < 1.6. Combinatorial background to the D-meson signals is reduced by using the ZEUS microvertex detector to reconstruct displaced secondary vertices. Production cross sections are compared with the predictions of next-to-leading-order QCD, which is found to describe the data well. Measurements are extrapolated to the full kinematic phase space in order to obtain the open-charm contribution, F-2(c (c) over bar), to the proton structure function, F-2.

Adipose Stromal Cells Stimulate Angiogenesis via Promoting Progenitor Cell Differentiation, Secretion of Angiogenic Factors, and Enhancing Vessel Maturation

Abstract: Adipose-derived stromal cells (ASCs) are suggested to be potent candidates for cell therapy of ischemic conditions due to their ability to stimulate blood vessel growth. ASCs produce many angiogenic and anti-apoptotic growth factors, and their secretion is significantly enhanced by hypoxia. Utilizing a Matrigel implant model, we showed that hypoxia-treated ASCs stimulated angiogenesis as well as maturation of the newly formed blood vessels in vivo. To elucidate mechanisms of ASC angiogenic action, we used a co-culture model of ASCs with cells isolated from early postnatal hearts (cardiomyocyte fraction, CMF). CMF contained mature cardiomyocytes, endothelial cells, and progenitor cells. On the second day of culture CMF cells formed spontaneously beating colonies with CD31+ capillary-like structures outgrowing from those cell aggregates. However, these vessel-like structures were not stable, and disassembled within next 5 days. Co-culturing of CMF with ASCs resulted in the formation of stable and branched C...

Validating Formative Partial Least Squares (PLS) Models: Methodological Review and Empirical Illustration

Abstract: The issue of formative constructs, as opposed to th e more frequently used reflective ones, has recently gained momentum among IS and Management re searchers. Most researchers maintain that formative constructs have been understudied, a nd that there is paucity in methodological literature to guide researchers on how such constru cts should be developed and estimated. A survey of IS research has revealed that about 29% o f constructs were misspecified as reflective rather than formative constructs. Furthermore, guid elines about how models containing formative constructs should be indentified and estimated are fragmented and inconsistent. Thus, this paper aims to present a methodological review of formativ e model identification and evaluation. We bring a brief theoretical overview of formative con structs, and put together a guideline for estimating formative measurement and structural mod els. We then present a simplified model composed of three formative constructs and illustra te how it is assessed and estimated using SmartPLS.

β- and γ-cytoplasmic actins display distinct distribution and functional diversity

Abstract: Using newly generated monoclonal antibodies, we have compared the distribution of beta- and gamma-cytoplasmic actin in fibroblastic and epithelial cells, in which they play crucial roles during various key cellular processes. Whereas beta-actin is preferentially localized in stress fibers, circular bundles and at cell-cell contacts, suggesting a role in cell attachment and contraction, gamma-actin displays a more versatile organization, according to cell activities. In moving cells, gamma-actin is mainly organized as a meshwork in cortical and lamellipodial structures, suggesting a role in cell motility; in stationary cells, gamma-actin is also recruited into stress fibers. beta-actin-depleted cells become highly spread, display broad protrusions and reduce their stress-fiber content; by contrast, gamma-actin-depleted cells acquire a contractile phenotype with thick actin bundles and shrinked lamellar and lamellipodial structures. Moreover, beta- and gamma-actin depleted fibroblasts exhibit distinct changes in motility compared with their controls, suggesting a specific role for each isoform in cell locomotion. Our results reveal new aspects of beta- and gamma-actin organization that support their functional diversity.

Resonant level formed by tin in Bi 2 Te 3 and the enhancement of room-temperature thermoelectric power

Abstract: Tin is a known resonant impurity in the valence band of ${\text{Bi}}_{2}{\text{Te}}_{3}$ that was previously reported to enhance the thermoelectric power $S$ of the host material at cryogenic temperatures through resonant scattering. We show here that Sn provides an excess density of states (DOS) about 15 meV below the valence band edge and that it is the increases in DOS itself that enhances $S$ of this technologically important semiconductor even at room temperature. The experimental proof for the existence of this resonant level comes from Shubnikov-de Haas measurements combined with galvanomagnetic and thermomagnetic properties measurements.