Nagoya Institute of Technology

About: Nagoya Institute of Technology is a education organization based out in Nagoya, Japan. It is known for research contribution in the topics: Thin film & Catalysis. The organization has 10766 authors who have published 19140 publications receiving 255696 citations. The organization is also known as: Nagoya Kōgyō Daigaku & Nitech.

Diffusion Path and Conduction Mechanism of Oxide Ions in Apatite-Type Lanthanum Silicates

Abstract: Apatite-type lanthanum silicates of general formula La9.33+2x/3(SiO4)6O2+x have appeared recently as a new promising class of oxide ion conductors with potential applications as electrolytes for solid oxide fuel cells (SOFCs). They have been shown to demonstrate relatively high oxide ion conductivity at moderate temperatures as well as at low oxygen partial pressures. In this paper, the diffusion pathways and the conduction mechanism of oxide ions in these phases are reinvestigated. This is done by means of atomic scale computer modeling techniques with both semiempirical and bond valence methods. Our results support that oxide ion conduction along the c-axis proceeds by an interstitial mechanism. They also support the presence of interstitial sites located within the conduction channel. However, contrarily to recent research, it is shown that the channel oxide ions are involved in the conduction process by a push−pull type mechanism. This mechanism brings into play a cooperative movement of both two adja...

The Gathering Problem for Two Oblivious Robots with Unreliable Compasses

Abstract: Anonymous mobile robots are often classified into synchronous, semi-synchronous, and asynchronous robots when discussing the pattern formation problem. For semi-synchronous robots, all patterns formable with memory are also formable without memory, with the single exception of forming a point (i.e., the gathering) by two robots. (All patterns formable with memory are formable without memory for synchronous robots, and little is known for asynchronous robots.) However, the gathering problem for two semi-synchronous robots without memory (called oblivious robots in this paper) is trivially solvable when their local coordinate systems are consistent, and the impossibility proof essentially uses the inconsistencies in their coordinate systems. Motivated by this, this paper investigates the magnitude of consistency between the local coordinate systems necessary and sufficient to solve the gathering problem for two oblivious robots under semi-synchronous and asynchronous models. To discuss the magnitude of consistency, we assume that each robot is equipped with an unreliable compass, the bearings of which may deviate from an absolute reference direction, and that the local coordinate system of each robot is determined by its compass. We consider two families of unreliable compasses, namely, static compasses with (possibly incorrect) constant bearings and dynamic compasses the bearings of which can change arbitrarily (immediately before a new look-compute-move cycle starts and after the last cycle ends). For each of the combinations of robot and compass models, we establish the condition on deviation $\phi$ that allows an algorithm to solve the gathering problem, where the deviation is measured by the largest angle formed between the $x$-axis of a compass and the reference direction of the global coordinate system: $\phi < \pi/2$ for semi-synchronous and asynchronous robots with static compasses, $\phi < \pi/4$ for semi-synchronous robots with dynamic compasses, and $\phi < \pi/6$ for asynchronous robots with dynamic compasses. Except for asynchronous robots with dynamic compasses, these sufficient conditions are also necessary.

Chiral recognition in cucurbituril cavities.

Abstract: For the first time, achiral cucurbiturils (CBs) were endowed with significant enantiomeric and distereomeric discrimination by incorporating a strong chiral binder. Calorimetric, nuclear magnetic, light-scattering, and mass spectral studies revealed that (S)-2-methylbutylamine (as a strong binder) can be discriminated by two enantiomeric supramolecular hosts, composed of CB[6] and (R)- or (S)-2-methylpiperazine, with an unprecedented 95% enantioselectivity in aqueous NaCl solution. This is the highest enantioselectivity ever reported for a supramolecular system derived from an achiral host. Similarly, CB[7], with a larger cavity, exhibited diastereoselectivities up to 8 times higher for diastereomeric dipeptides, as demonstrated for L-Phe-L-Leu-NH3+ versus L-Phe-D-Leu-NH3+.