Nanjing University of Science and Technology

About: Nanjing University of Science and Technology is a education organization based out in Nanjing, China. It is known for research contribution in the topics: Catalysis & Computer science. The organization has 31581 authors who have published 36390 publications receiving 525474 citations. The organization is also known as: Nánjīng Lǐgōng Dàxué & Nánlǐgōng.

A Facile and Versatile Synthesis of Energetic Furazan-Functionalized 5-Nitroimino-1,2,4-Triazoles

Abstract: An analogue-oriented synthetic route for the formulation of furazan-functionalized 5-nitroimino-1,2,4-triazoles has been explored. The process was found to be straightforward, high yielding, and highly efficient, and scalable. Nine compounds were synthesized and the physicochemical and energetic properties, including density, thermal stability, and sensitivity, were investigated, as well as the energetic performance (e.g., detonation velocities and detonation pressures) as evaluated by using EXPLO5 code. Among the new materials, compounds 4-6 and 11 possess high densities, acceptable sensitivities, and good detonation performances, and thereby demonstrate the potential applications as new secondary explosives.

Microstructure; bonding strength and thickness ratio of Al/Mg/Al alloy laminated composites prepared by hot rolling

Abstract: In this study, 7075 Al/AZ31B Mg/7075 Al laminated composites were prepared by hot roll bonding method. Microstructure and bonding strength of the experimental laminated composites, and thickness ratio of the constituent layers after hot rolling were evaluated. Effects of reduction ratio and rolling temperature on the microstructure, bonding strength and thickness ratio were also studied. Dynamic recrystallization microstructures were observed in the composite. The bonding strength decreased with reduction ratio and rolling temperature due to the increase in the grain size and diffusion layer width with the reduction ratio and rolling temperature. The maximal bonding strength of the experimental laminated composite was 66 MPa. The thickness fraction of the Mg alloy plate after hot rolling decreased with the reduction ratio and rolling temperature.

Exciton versus free carrier photogeneration in organometal trihalide perovskites probed by broadband ultrafast polarization memory dynamics.

Abstract: We studied the ultrafast transient response of photoexcitations in two hybrid organic-inorganic perovskite films used for high efficiency photovoltaic cells, namely, CH(3)NH(3)PbI(3) and CH(3)NH(3)PbI(1.1)Br(1.9) using polarized broadband pump-probe spectroscopy in the spectral range of 0.3-2.7 eV with 300 fs time resolution. For CH(3)NH(3)PbI(3) with above-gap excitation we found both photogenerated carriers and excitons, but only carriers are photogenerated with below-gap excitation. In contrast, mainly excitons are photogenerated in CH(3)NH(3)PbI(1.1)Br(1.9). Surprisingly, we also discovered in CH(3)NH(3)PbI(3), but not in CH(3)NH(3)PbI(1.1)Br(1.9), transient photoinduced polarization memory for both excitons and photocarriers, which is also reflected in the steady state photoluminescence. From the polarization memory dynamics we obtained the excitons diffusion constant in CH(3)NH(3)PbI(3), D≈0.01 cm(2) s(-1).