Nankai University

About: Nankai University is a education organization based out in Tianjin, China. It is known for research contribution in the topics: Catalysis & Adsorption. The organization has 42964 authors who have published 51866 publications receiving 1127896 citations. The organization is also known as: Nánkāi Dàxué.

Fused Heteroaromatic Organic Compounds for High‐Power Electrodes of Rechargeable Lithium Batteries

Abstract: Organic redox compounds are emerging electrode materials for rechargeable lithium batteries. However, their electrically insulating nature plagues efficient charge transport within the electroactive bulk. Alternative to the popular solution of elaborating nanocomposite materials, herein we report on a molecular-level engineering strategy towards high-power organic electrode materials with multi-electron reactions. Systematic comparisons of anthraquinone analogues incorporating fused heteroaromatic structures as cathode materials in rechargeable lithium batteries reveal that the judicious incorporation of heteroaromatics improves the cell performance in terms of specific gravimetric capacity, working potential, rate capability, and cyclability. Combination studies with morphological observation, electrochemical impedance characterization, and theoretical modeling provide insight into the advantage of heteroaromatic building blocks. In particular, benzofuro[5,6-b]furan-4,8-dione (BFFD) bearing furan moeities shows a reversible capacity of 181 mAh g−1 when charged/discharged at 100C, corresponding to a power density of 29.8 kW kg−1. These results have pointed to a general design route of high-rate organic electrode materials by rational functionalization of redox compounds with appropriate heteroaromatic units as versatile structural tools.

High-birefringence fiber loop mirrors and their applications as sensors.

Abstract: The reflection and transmission characteristics of a high-birefringence fiber loop mirror (HiBi-FLM), which is composed of a standard fiber coupler and one-section or multisection high-birefringence fibers (HBFs), are analyzed and discussed in detail. Theoretical reflectivity and transmissivity expressions for HiBi-FLMs with one-, two-, and three-section HBFs were obtained. The procedure for calculating reflectivity and transmissivity for HiBi-FLMs with n-section HBFs is given. Experimental results have verified the theoretical model. The basic characteristics of the one-section HiBi-FLM when strain and high temperature are applied to HBFs were analyzed and investigated theoretically and experimentally. The experimental results are in good agreement with the theoretical analysis. Furthermore, a strain– temperature sensor that makes use of those characteristics, which is new for applications of HiBi-FLMs, has been proposed and demonstrated.