Nankai University

About: Nankai University is a education organization based out in Tianjin, China. It is known for research contribution in the topics: Catalysis & Enantioselective synthesis. The organization has 42964 authors who have published 51866 publications receiving 1127896 citations. The organization is also known as: Nánkāi Dàxué.

Biomonitoring of perfluoroalkyl acids in human urine and estimates of biological half-life.

Abstract: Perfluoroalkyl acids (PFAAs) are persistent and bioaccumulative compounds that have been associated with adverse health outcomes. In human blood, PFAAs exist as both linear and branched isomers, yet for most linear homologues, and for all branched isomers, elimination rates are unknown. Paired blood and urine samples (n = 86) were collected from adults in China. They were analyzed by a sensitive isomer-specific method that permitted the detection of many PFAAs in human urine for the first time. For all PFAAs except perfluoroundecanoate (PFUnA), levels in urine correlated positively with levels in blood. Perfluoroalkyl carboxylates (PFCAs) were excreted more efficiently than perfluoroalkane sulfonates (PFSAs) of the same carbon chain-length. In general, shorter PFCAs were excreted more efficiently than longer ones, but for PFSAs, perfluorooctanesulfonate (PFOS, a C8 compound) was excreted more efficiently than perfluorohexanesulfonate (PFHxS, a C6 compound). Among PFOS and perfluorooctanoate (PFOA) isomers, major branched isomers were more efficiently excreted than the corresponding linear isomer. A one-compartment model was used to estimate the biological elimination half-lives of PFAAs. Among all PFAAs, the estimated arithmetic mean elimination half-lives ranged from 0.5 ± 0.1 years (for one branched PFOA isomer, 5m-PFOA) to 90 ± 11 years (for one branched PFOS isomer, 1m-PFOS). Urinary excretion was the major elimination route for short PFCAs (C ≤ 8), but for longer PFCAs, PFOS and PFHxS, other routes of excretion likely contribute to overall elimination. Urinary concentrations are good biomarkers of the internal dose, and this less invasive strategy can therefore be used in future epidemiological and biomonitoring studies. The very long half-lives of long-chain PFCAs, PFHxS, and PFOS isomers in humans stress the importance of global and domestic exposure mitigation strategies.

GMS: Grid-Based Motion Statistics for Fast, Ultra-Robust Feature Correspondence

Abstract: Incorporating smoothness constraints into feature matching is known to enable ultra-robust matching. However, such formulations are both complex and slow, making them unsuitable for video applications. This paper proposes GMS (Grid-based Motion Statistics), a simple means of encapsulating motion smoothness as the statistical likelihood of a certain number of matches in a region. GMS enables translation of high match numbers into high match quality. This provides a real-time, ultra-robust correspondence system. Evaluation on videos, with low textures, blurs and wide-baselines show GMS consistently out-performs other real-time matchers and can achieve parity with more sophisticated, much slower techniques.

Constraining the coordination geometries of lanthanide centers and magnetic building blocks in frameworks: a new strategy for molecular nanomagnets

Abstract: Single-molecule magnets (SMMs) and single-chain magnets (SCMs), also known as molecular nanomagnets, are molecular species of nanoscale proportions with the potential for high information storage density and spintronics applications. Metal–organic frameworks (MOFs) are three-dimensional ordered assemblies of inorganic nodes and organic linkers, featuring structural diversity and multiple chemical and physical properties. The concept of using these frameworks as scaffolds in the study of molecular nanomagnets provides an opportunity to constrain the local coordination geometries of lanthanide centers and organize the individual magnetic building blocks (MBBs, including both transition-metal and lanthanide MBBs) into topologically well-defined arrays that represent two key factors governing the magnetic properties of molecular nanomagnets. In this tutorial review, we summarize recent progress in this newly emerging field.

Evolution of public cooperation on interdependent networks: The impact of biased utility functions

Abstract: We study the evolution of public cooperation on two interdependent networks that are connected by means of a utility function, which determines to what extent payoffs in one network influence the success of players in the other network. We find that the stronger the bias in the utility function, the higher the level of public cooperation. Yet the benefits of enhanced public cooperation on the two networks are just as biased as the utility functions themselves. While cooperation may thrive on one network, the other may still be plagued by defectors. Nevertheless, the aggregate level of cooperation on both networks is higher than the one attainable on an isolated network. This positive effect of biased utility functions is due to the suppressed feedback of individual success, which leads to a spontaneous separation of characteristic time scales of the evolutionary process on the two interdependent networks. As a result, cooperation is promoted because the aggressive invasion of defectors is more sensitive to the slowing-down than the build-up of collective efforts in sizable groups.