National Autonomous University of Mexico

About: National Autonomous University of Mexico is a education organization based out in Mexico City, Distrito Federal, Mexico. It is known for research contribution in the topics: Population & Galaxy. The organization has 72868 authors who have published 127797 publications receiving 2285543 citations. The organization is also known as: UNAM & Universidad Nacional Autónoma de México.

Hydrogen-hydrogen bonding: a stabilizing interaction in molecules and crystals.

Abstract: Bond paths linking two bonded hydrogen atoms that bear identical or similar charges are found between the ortho-hydrogen atoms in planar biphenyl, between the hydrogen atoms bonded to the C1–C4 carbon atoms in phenanthrene and other angular polybenzenoids, and between the methyl hydrogen atoms in the cyclobutadiene, tetrahedrane and indacene molecules corseted with tertiary-tetra-butyl groups. It is shown that each such H–H interaction, rather than denoting the presence of “nonbonded steric repulsions”, makes a stabilizing contribution of up to 10 kcal mol−1 to the energy of the molecule in which it occurs. The quantum theory of atoms in molecules—the physics of an open system—demonstrates that while the approach of two bonded hydrogen atoms to a separation less than the sum of their van der Waals radii does result in an increase in the repulsive contributions to their energies, these changes are dominated by an increase in the magnitude of the attractive interaction of the protons with the electron density distribution, and the net result is a stabilizing change in the energy. The surface virial that determines the contribution to the total energy decrease resulting from the formation of the H–H interatomic surface is shown to account for the resulting stability. It is pointed out that H–H interactions must be ubiquitous, their stabilization energies contributing to the sublimation energies of hydrocarbon molecular crystals, as well as solid hydrogen. H–H bonding is shown to be distinct from “dihydrogen bonding”, a form of hydrogen bonding with a hydridic hydrogen in the role of the base atom.

Accretion Disks around Young Objects. I. The Detailed Vertical Structure

Abstract: We discuss the properties of an accretion disk around a star with parameters typical of classical T Tauri stars (CTTSs) and with the average accretion rate for these disks The disk is assumed steady and geometrically thin The turbulent viscosity coefficient is expressed using the α prescription, and the main heating mechanisms considered are viscous dissipation and irradiation by the central star The energy is transported by radiation, turbulent conduction, and convection We find that irradiation from the central star is the main heating agent of the disk, except in the innermost regions, R 5 AU) becomes less dense, optically thin, and almost vertically isothermal, with a temperature distribution T ∝ R-1/2 The decrease in surface density at the outer disk decreases the disk mass by a factor of 4 with respect to a purely viscous case In addition, irradiation tends to make the outer disk regions stable against gravitational instabilities

Accretion disks around young objects. iii. grain growth

Abstract: We present detailed models of irradiated T Tauri disks including dust grain growth with power-law size distributions. The models assume complete mixing between dust and gas and solve for the vertical disk structure self-consistently including the heating effects of stellar irradiation as well as local viscous heating. For a given total dust mass, grain growth is found to decrease the vertical height of the surface where the optical depth to the stellar radiation becomes unity and thus the local irradiation heating, while increasing the disk emission at mm and submillimeter wavelengths. The resulting disk models are less geometrically thick than our previous models assuming interstellar medium dust, and agree better with observed spectral energy distributions and images of edge-on disks, like HK Tau/c and HH 30. The implications of models with grain growth for determining disk masses from long-wavelength emission are considered.

Man and the last great wilderness: human impact on the deep sea.

Abstract: The deep sea, the largest ecosystem on Earth and one of the least studied, harbours high biodiversity and provides a wealth of resources. Although humans have used the oceans for millennia, technological developments now allow exploitation of fisheries resources, hydrocarbons and minerals below 2000 m depth. The remoteness of the deep seafloor has promoted the disposal of residues and litter. Ocean acidification and climate change now bring a new dimension of global effects. Thus the challenges facing the deep sea are large and accelerating, providing a new imperative for the science community, industry and national and international organizations to work together to develop successful exploitation management and conservation of the deep-sea ecosystem. This paper provides scientific expert judgement and a semi-quantitative analysis of past, present and future impacts of human-related activities on global deep-sea habitats within three categories: disposal, exploitation and climate change. The analysis is the result of a Census of Marine Life – SYNDEEP workshop (September 2008). A detailed review of known impacts and their effects is provided. The analysis shows how, in recent decades, the most significant anthropogenic activities that affect the deep sea have evolved from mainly disposal (past) to exploitation (present). We predict that from now and into the future, increases in atmospheric CO2 and facets and consequences of climate change will have the most impact on deep-sea habitats and their fauna. Synergies between different anthropogenic pressures and associated effects are discussed, indicating that most synergies are related to increased atmospheric CO2 and climate change effects. We identify deep-sea ecosystems we believe are at higher risk from human impacts in the near future: benthic communities on sedimentary upper slopes, cold-water corals, canyon benthic communities and seamount pelagic and benthic communities. We finalise this review with a short discussion on protection and management methods.