National University of Defense Technology

About: National University of Defense Technology is a education organization based out in Changsha, China. It is known for research contribution in the topics: Computer science & Radar. The organization has 39430 authors who have published 40181 publications receiving 358979 citations. The organization is also known as: Guófáng Kēxuéjìshù Dàxué & NUDT.

Lanthanide-doped inorganic nanoparticles turn molecular triplet excitons bright

Abstract: The generation, control and transfer of triplet excitons in molecular and hybrid systems is of great interest owing to their long lifetime and diffusion length in both solid-state and solution phase systems, and to their applications in light emission1, optoelectronics2,3, photon frequency conversion4,5 and photocatalysis6,7. Molecular triplet excitons (bound electron-hole pairs) are 'dark states' because of the forbidden nature of the direct optical transition between the spin-zero ground state and the spin-one triplet levels8. Hence, triplet dynamics are conventionally controlled through heavy-metal-based spin-orbit coupling9-11 or tuning of the singlet-triplet energy splitting12,13 via molecular design. Both these methods place constraints on the range of properties that can be modified and the molecular structures that can be used. Here we demonstrate that it is possible to control triplet dynamics by coupling organic molecules to lanthanide-doped inorganic insulating nanoparticles. This allows the classically forbidden transitions from the ground-state singlet to excited-state triplets to gain oscillator strength, enabling triplets to be directly generated on molecules via photon absorption. Photogenerated singlet excitons can be converted to triplet excitons on sub-10-picosecond timescales with unity efficiency by intersystem crossing. Triplet exciton states of the molecules can undergo energy transfer to the lanthanide ions with unity efficiency, which allows us to achieve luminescent harvesting of the dark triplet excitons. Furthermore, we demonstrate that the triplet excitons generated in the lanthanide nanoparticle-molecule hybrid systems by near-infrared photoexcitation can undergo efficient upconversion via a lanthanide-triplet excitation fusion process: this process enables endothermic upconversion and allows efficient upconversion from near-infrared to visible frequencies in the solid state. These results provide a new way to control triplet excitons, which is essential for many fields of optoelectronic and biomedical research.

Low-frequency locally resonant band gaps induced by arrays of resonant shunts with Antoniou’s circuit: experimental investigation on beams

Abstract: A periodic array of resistive inductive (RL) shunted piezoelectric (PZT) patches is applied to achieve tunable low-frequency locally resonant (LR) band gaps in a flexible isotropic beam. Each pair of surface-bonded PZT patches is linked to an independent RL circuit. All the circuits are the same and are tuned synchronously. A transfer matrix methodology is used to calculate the frequency range and attenuation properties of the LR band gap. Two main differences are found between the LR band gaps induced by shunting circuits and traditional oscillators. Antoniou's circuits are used to produce large ideal inductances necessary for low eigenfrequencies. The theoretical results are experimentally validated by measuring the harmonic response of the beam. Significant attenuation in the low-frequency LR band gap is observed.

Co-hierarchical analysis of shape structures

Abstract: We introduce an unsupervised co-hierarchical analysis of a set of shapes, aimed at discovering their hierarchical part structures and revealing relations between geometrically dissimilar yet functionally equivalent shape parts across the set. The core problem is that of representative co-selection. For each shape in the set, one representative hierarchy (tree) is selected from among many possible interpretations of the hierarchical structure of the shape. Collectively, the selected tree representatives maximize the within-cluster structural similarity among them. We develop an iterative algorithm for representative co-selection. At each step, a novel cluster-and-select scheme is applied to a set of candidate trees for all the shapes. The tree-to-tree distance for clustering caters to structural shape analysis by focusing on spatial arrangement of shape parts, rather than their geometric details. The final set of representative trees are unified to form a structural co-hierarchy. We demonstrate co-hierarchical analysis on families of man-made shapes exhibiting high degrees of geometric and finer-scale structural variabilities.

Manipulating metals for adaptive thermal camouflage

Abstract: Many species in nature have evolved remarkable strategies to visually adapt to the surroundings for the purpose of protection and predation. Similarly, acquiring the capabilities of adaptively camouflaging in the infrared (IR) spectrum has emerged as an intriguing but highly challenging technology in recent years. Here, we report adaptive thermal camouflage devices by bridging the optical and radiative properties of nanoscopic platinum (Pt) films and silver (Ag) electrodeposited Pt films. Specifically, these metal-based devices have large, uniform, and consistent IR tunabilities in mid-wave IR (MWIR) and long-wave IR (LWIR) atmospheric transmission windows (ATWs). Furthermore, these devices can be easily multiplexed, enlarged, applied to rough and flexible substrates, or colored, demonstrating their multiple adaptive camouflaging capabilities. We believe that this technology will be advantageous not only in various adaptive camouflage platforms but also in many thermal radiation management–related technologies.