National University of La Plata

About: National University of La Plata is a education organization based out in La Plata, Argentina. It is known for research contribution in the topics: Population & Stars. The organization has 12993 authors who have published 30013 publications receiving 495118 citations. The organization is also known as: UNLP & Universidad Nacional de La Plata.

The Chemistry of the Sulfur–Gold Interface: In Search of a Unified Model

Abstract: Over the last three decades, self-assembled molecular films on solid surfaces have attracted widespread interest as an intellectual and technological challenge to chemists, physicists, materials scientists, and biologists. A variety of technological applications of nanotechnology rely on the possibility of controlling topological, chemical, and functional features at the molecular level. Self-assembled monolayers (SAMs) composed of chemisorbed species represent fundamental building blocks for creating complex structures by a bottom-up approach. These materials take advantage of the flexibility of organic and supramolecular chemistry to generate synthetic surfaces with well-defined chemical and physical properties. These films already serve as structural or functional parts of sensors, biosensors, drug-delivery systems, molecular electronic devices, protecting capping for nanostructures, and coatings for corrosion protection and tribological applications.Thiol SAMs on gold are the most popular molecular fi...

Correlated X-Ray Spectral and Timing Behavior of the Black Hole Candidate XTE J1550–564: A New Interpretation of Black Hole States

Abstract: We present an analysis of data of the black hole candidate and X-ray transient XTE J1550-564, taken with the Rossi X-Ray Timing Explorer between 1998 November 22 and 1999 May 20. During this period the source went through several different states, which could be divided into soft and hard states based on the relative strength of the high-energy spectral component. These states showed up as distinct branches in the color-color and hardness-intensity diagrams, connecting to form a structure with a comblike topology, the branch corresponding to the soft state forming the spine and the branches corresponding to the various hard states forming the teeth of the comb. The power spectral properties of the source were strongly correlated with its position on the branches. The broadband noise became stronger and changed from power law-like to band-limited, as the spectrum became harder. Three types of quasi-periodic oscillations (QPOs) were found: 1-18 Hz and 102-284 Hz QPOs on the hard branches, and 16-18 Hz QPOs on and near the soft branch. The 1-18 Hz QPOs on the hard branches could be divided into three subtypes. The frequencies of the high- and low-frequency QPOs on the hard branches were correlated with each other and were anticorrelated with spectral hardness. The changes in QPO frequency suggest that the inner disk radius only increases by a factor of 3-4 as the source changes from a soft to a hard state. Our results on XTE J1550-564 strongly favor a two-dimensional description of black hole behavior, where the regions near the spine of the comb in the color-color diagram can be identified with the high state, and the teeth with transitions from the high state, via the intermediate state (which includes the very high state) to the low state, and back. The two physical parameters underlying this two-dimensional behavior vary to a large extent independently and could for example be the accretion rate through the disk and the size of the Comptonizing region causing the hard tail. The difference between the various teeth is then associated with the mass accretion rate through the disk, suggesting that high state ↔ low state transitions can occur at any disk mass accretion rate and that these transitions are primarily caused by another, independent parameter. We discuss how this picture could tie in with the canonical, one-dimensional behavior of black hole candidates that has usually been observed.

Type I and Type II Photosensitized Oxidation Reactions: Guidelines and Mechanistic Pathways

Abstract: Here, 10 guidelines are presented for a standardized definition of type I and type II photosensitized oxidation reactions. Because of varied notions of reactions mediated by photosensitizers, a checklist of recommendations is provided for their definitions. Type I and type II photoreactions are oxygen-dependent and involve unstable species such as the initial formation of radical cation or neutral radicals from the substrates and/or singlet oxygen (1 O21 ∆g ) by energy transfer to molecular oxygen. In addition, superoxide anion radical (O2·-) can be generated by a charge-transfer reaction involving O2 or more likely indirectly as the result of O2 -mediated oxidation of the radical anion of type I photosensitizers. In subsequent reactions, O2·- may add and/or reduce a few highly oxidizing radicals that arise from the deprotonation of the radical cations of key biological targets. O2·- can also undergo dismutation into H2 O2 , the precursor of the highly reactive hydroxyl radical (·OH) that may induce delayed oxidation reactions in cells. In the second part, several examples of type I and type II photosensitized oxidation reactions are provided to illustrate the complexity and the diversity of the degradation pathways of mostly relevant biomolecules upon one-electron oxidation and singlet oxygen reactions.