Ocean University of China

About: Ocean University of China is a education organization based out in Qingdao, China. It is known for research contribution in the topics: Population & Sea surface temperature. The organization has 27604 authors who have published 27886 publications receiving 440181 citations. The organization is also known as: Zhōngguó Hǎiyáng Dàxué & OUC.

Gold(I)‐Catalyzed Glycosylation with Glycosyl ortho‐Alkynylbenzoates as Donors: General Scope and Application in the Synthesis of a Cyclic Triterpene Saponin

Abstract: Glycosyl ortho-alkynylben- zoates have emerged as a new genera- tion of donors for glycosidation under the catalysis of gold(I) complexes such as Ph3PAuOTf and Ph3PAuNTf2 (Tf = trifluoromethanesulfonate). A wide va- riety of these donors, including 2-deoxy sugar and sialyl donors, are easily pre- pared and shelf stable. The glycosidic coupling yields with alcohols are gener- ally excellent; even direct coupling with the poorly nucleophilic amides gives satisfactory yields. Moreover, ex- cellent a-selective glycosylation with a 2-deoxy sugar donor and b-selective sialylation have been realized. Applica- tion of the present glycosylation proto- col in the efficient synthesis of a cyclic triterpene tetrasaccharide have further demonstrated the versatility and effica- cy of this new method, in that a novel chemoselective glycosylation of the car- boxylic acid and a new one-pot sequen- tial glycosylation sequence have been implemented.

Powerful and Tunable THz Emitters Based on the Fe/Pt Magnetic Heterostructure

Abstract: In this work, we report our study on the THz emission in Fe/Pt magnetic heterostructures. We have carried out a comprehensive investigation of THz emission from Fe/Pt magnetic heterostructures, employing time-domain THz spectroscopy. We reveal that by properly tuning the thickness of Fe or Pt layer, THz emission can be greatly improved in this type of heterostructure. We further demonstrate that the THz field strength emitted from a newly designed multilayer (Pt/Fe/MgO)$_n$ with n=3 can reach a value of ~1.6 kV/cm, which is comparable to the values from the conventional GaAs antenna with a bias of 4 kV/cm, and the nonlinear crystals, e.g., 100 micrometer GaP and 2 mm ZnTe. For the first time, the intensity and spectrum of THz wave is demonstrated to be tunable by the magnetic field applied on the patterned magnetic Fe/Pt heterostructures. These findings thus promise novel approaches to fabricate powerful and tunable THz emitters based on magnetic heterostructure.

Intensification of decadal and multi-decadal sea level variability in the western tropical Pacific during recent decades

Abstract: Previous studies have linked the rapid sea level rise (SLR) in the western tropical Pacific (WTP) since the early 1990s to the Pacific decadal climate modes, notably the Pacific Decadal Oscillation in the north Pacific or Interdecadal Pacific Oscillation (IPO) considering its basin wide signature. Here, the authors investigate the changing patterns of decadal (10-20 years) and multidecadal (> 20 years) sea level variability (global mean SLR removed) in the Pacific associated with the IPO, by analyzing satellite and in situ observations, together with reconstructed and reanalysis products, and performing ocean and atmosphere model experiments. Robust intensification is detected for both decadal and multidecadal sea level variability in the WTP since the early 1990s. The IPO intensity, however, did not increase and thus cannot explain the faster SLR. The observed, accelerated WTP SLR results from the combined effects of Indian Ocean and WTP warming and central-eastern tropical Pacific cooling associated with the IPO cold transition. The warm Indian Ocean acts in concert with the warm WTP and cold central-eastern tropical Pacific to drive intensified easterlies and negative Ekman pumping velocity in western-central tropical Pacific, thereby enhancing the western tropical Pacific SLR. On decadal timescales, the intensified sea level variability since the late 1980s or early 1990s results from the "out of phase" relationship of sea surface temperature anomalies between the Indian and central-eastern tropical Pacific since 1985, which produces "in phase" effects on the WTP sea level variability.