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Institution

Pacific Northwest National Laboratory

FacilityRichland, Washington, United States
About: Pacific Northwest National Laboratory is a facility organization based out in Richland, Washington, United States. It is known for research contribution in the topics: Catalysis & Aerosol. The organization has 11581 authors who have published 27934 publications receiving 1120489 citations. The organization is also known as: PNL & PNNL.
Topics: Catalysis, Aerosol, Mass spectrometry, Population, Ion


Papers
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Journal ArticleDOI
TL;DR: In this article, the authors combined active and passive remote sensing instrumentation to derive radiative and macrophysical properties of tropical cirrus clouds, and found that two different types of clouds exist in the tropical western Pacific: high, thin, laminar cirrus with cloud base higher than 15 km, and lower, physically thicker, more structured clouds.
Abstract: Ground based active and passive remote sensing instrumentation are combined to derive radiative and macrophysical properties of tropical cirrus clouds. Eight months of cirrus observations at the Department of Energy Atmospheric Radiation Measurement site located on Nauru Island provide independent retrieval of cloud height and visible optical depth using lidar and radar techniques. Comparisons reveal the millimeter cloud radar does not detect 13% of cirrus clouds with a cloud base higher than 15 km that are detected by the lidar. Lidar and radar cloud heights demonstrate good agreement when the cloud lies below 15 km. Radar and lidar retrievals of visible optical depth also compare well for all but the optically thinnest clouds. Cloud occurrence at Nauru as measured by lidar, reveal clear sky conditions occur on average 40%, low clouds 16%, and high clouds 44% of the time. Analysis of observed cirrus macrophysical and radiative properties suggests that two different types of cirrus exist in the tropical western Pacific: high, thin, laminar cirrus with cloud base higher than 15 km, and lower, physically thicker, more structured cirrus clouds. Differences in cirrus types are likely linked to their formation mechanisms. Radiosonde profiles of temperature and equivalent potential temperature near themore » tropical tropopause show a clear transition between neutrally stable and stable air at ~15 km, which may also explain the presence of two distinct cirrus types. Radiative heating rate and cloud forcing calculations for specific cirrus cases reveal the impact of tropical cirrus clouds on the earth?s radiation budget.« less

225 citations

Journal ArticleDOI
TL;DR: In this article, the adsorption of liquid and vapor water on defective and nearly defect-free TiO 2 (110) surfaces has been studied using X-ray photoelectron spectroscopy (XPS) and ultraviolet photoemission spectrum analysis (UPS).

224 citations

Journal ArticleDOI
TL;DR: Collisional activation and collision-activated dissociation of multiply protonated molecular ions produced by electrospray ionization using an atmospheric pressure source are described and the feasibility of fingerprinting for proteins is illustrated by the CAD spectra of cytochrome c from nine species.

224 citations

Journal ArticleDOI
TL;DR: The present work presents the first spectropotentiometric and voltammetric characterization of MtrC, using protein purified from Shewanella oneidensis MR-1, and demonstrates reversible electrochemistry over a potential window similar to that disclosed spectroscopically.
Abstract: MtrC is a decaheme c-type cytochrome associated with the outer cell membrane of Fe(III)-respiring species of the Shewanella genus. It is proposed to play a role in anaerobic respiration by mediating electron transfer to extracellular mineral oxides that can serve as terminal electron acceptors. The present work presents the first spectropotentiometric and voltammetric characterization of MtrC, using protein purified from Shewanella oneidensis MR-1. Potentiometric titrations, monitored by UV–vis absorption and electron paramagnetic resonance (EPR) spectroscopy, reveal that the hemes within MtrC titrate over a broad potential range spanning between approximately +100 and approximately −500 mV (vs. the standard hydrogen electrode). Across this potential window the UV–vis absorption spectra are characteristic of low-spin c-type hemes and the EPR spectra reveal broad, complex features that suggest the presence of magnetically spin-coupled low-spin c-hemes. Non-catalytic protein film voltammetry of MtrC demonstrates reversible electrochemistry over a potential window similar to that disclosed spectroscopically. The voltammetry also allows definition of kinetic properties of MtrC in direct electron exchange with a solid electrode surface and during reduction of a model Fe(III) substrate. Taken together, the data provide quantitative information on the potential domain in which MtrC can operate.

224 citations

Journal ArticleDOI
TL;DR: In this paper, the MI-LAGRO field campaign in Mexico City used a high resolution AMS spectra to identify a biomass burning organic aerosol component, which includes several large plumes that appear to be from forest fires within the region.
Abstract: Submicron aerosol was analyzed during the MI- LAGRO field campaign in March 2006 at the T0 urban su- persite in Mexico City with a High-Resolution Aerosol Mass Spectrometer (AMS) and complementary instrumentation. Positive Matrix Factorization (PMF) of high resolution AMS spectra identified a biomass burning organic aerosol (BBOA) component, which includes several large plumes that appear to be from forest fires within the region. Here, we show

224 citations


Authors

Showing all 11848 results

NameH-indexPapersCitations
Yi Cui2201015199725
Derek R. Lovley16858295315
Xiaoyuan Chen14999489870
Richard D. Smith140118079758
Taeghwan Hyeon13956375814
Jun Liu13861677099
Federico Capasso134118976957
Jillian F. Banfield12756260687
Mary M. Horowitz12755756539
Frederick R. Appelbaum12767766632
Matthew Jones125116196909
Rainer Storb12390558780
Zhifeng Ren12269571212
Wei Chen122194689460
Thomas E. Mallouk12254952593
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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
2023130
2022459
20211,793
20201,795
20191,598
20181,619