Paul Sabatier University

About: Paul Sabatier University is a education organization based out in Toulouse, France. It is known for research contribution in the topics: Population & Adipose tissue. The organization has 15431 authors who have published 23386 publications receiving 858364 citations.

Surface chemistry and dissolution kinetics of divalent metal carbonates.

Abstract: A surface complexation model (SCM) for divalent metal carbonates (Ca, Mg, Sr, Ba, Mn, Fe, Co, Ni, Zn, Cd, and Pb) is developed based on new electrophoretic measurements and correlation between aqueous and surface reactions stability constants. This SCM postulates the formation of the following surface species: >CO3H0, >CO3-, >CO3Me+, >MeOH0, >MeO-, >MeOH2+, >MeHCO30, and MeCO3- within the framework of a constant capacitance of the electric double layer. It can be used to describe the surface-controlled dissolution kinetics of divalent metal carbonates and allows determination of the order of dissolution reactions with respect to rate-controlling protonated carbonate surface groups in acid solutions (>CO3H0) and hydrated metal groups (>MeOH2+) in neutral to alkaline solutions. The reaction order with respect to protonated carbonate groups increases from 2 for MnCO3 and ZnCO3 to 4 for NiCO3, whereas for hydrated surface metals, it augments from 2 for ZnCO3 to approximately 4 for MnCO3 and NiCO3. The dissolution rates at 5 < or = pH < or = 8 increase in the order Ni < Mg < Co < Fe < Mn < Zn < Cd < Sr < or = Ca approximately = Ba approximately = Pb and correlate nicely with water exchange rates from the aqueous solution into the hydration sphere of the corresponding dissolved cations. Such a correlation allows the generation for all carbonates of a model describing their dissolution/precipitation kinetics, including the effect of various ligands, provided that rate constants and their activation volumes for water exchange around Me(II)-ligand dissolved complexes are available.

Transition from glow silent discharge to micro-discharges in nitrogen gas

Abstract: At atmospheric pressure, the electrical breakdown of a silent discharge can occur in many thin filaments (leading to micro-discharges) or in a single discharge canal covering the entire electrode surface (leading to a glow discharge). The aim of this paper is to contribute to a better understanding of the transition from a glow silent discharge to micro-discharges in nitrogen at atmospheric pressure. For this purpose, the two types of regime have been studied by emission spectroscopy and electrical measurements. The transition is always observed due to an increase of the power dissipated in the gas gap, but the maximum power that can be used while maintaining a glow discharge depends on the nature of the dielectric surface in contact with the gas. These results have been explained by the predominance of the density of metastable nitrogen molecules on the discharge regime. Due to the creation of seed electrons via Penning ionization, these metastable molecules can control the gas breakdown and so the discharge regime. Their density essentially depends on their quenching rate. The products etched from the surfaces in contact with the discharge appear to be the main source of the metastable molecules quenching. Therefore, the nature of the surface controls the nature of the quenching of the metastable molecules and the power dissipated in the discharge the quencher density.

Optimal traffic organization in ants under crowded conditions

Abstract: Efficient transportation, a hot topic in nonlinear science, is essential for modern societies and the survival of biological species. Biological evolution has generated a rich variety of successful solutions, which have inspired engineers to design optimized artificial systems. Foraging ants, for example, form attractive trails that support the exploitation of initially unknown food sources in almost the minimum possible time. However, can this strategy cope with bottleneck situations, when interactions cause delays that reduce the overall flow? Here, we present an experimental study of ants confronted with two alternative routes. We find that pheromone-based attraction generates one trail at low densities, whereas at a high level of crowding, another trail is established before traffic volume is affected, which guarantees that an optimal rate of food return is maintained. This bifurcation phenomenon is explained by a nonlinear modelling approach. Surprisingly, the underlying mechanism is based on inhibitory interactions. It points to capacity reserves, a limitation of the density-induced speed reduction, and a sufficient pheromone concentration for reliable trail perception. The balancing mechanism between cohesive and dispersive forces appears to be generic in natural, urban and transportation systems.