Showing papers by "Paul Scherrer Institute published in 2018"

Structure of the µ-opioid receptor–G i protein complex

Abstract: The μ-opioid receptor (μOR) is a G-protein-coupled receptor (GPCR) and the target of most clinically and recreationally used opioids. The induced positive effects of analgesia and euphoria are mediated by μOR signalling through the adenylyl cyclase-inhibiting heterotrimeric G protein Gi. Here we present the 3.5 A resolution cryo-electron microscopy structure of the μOR bound to the agonist peptide DAMGO and nucleotide-free Gi. DAMGO occupies the morphinan ligand pocket, with its N terminus interacting with conserved receptor residues and its C terminus engaging regions important for opioid-ligand selectivity. Comparison of the μOR-Gi complex to previously determined structures of other GPCRs bound to the stimulatory G protein Gs reveals differences in the position of transmembrane receptor helix 6 and in the interactions between the G protein α-subunit and the receptor core. Together, these results shed light on the structural features that contribute to the Gi protein-coupling specificity of the µOR.

Identification of heavy-flavour jets with the CMS detector in pp collisions at 13 TeV

Abstract: Many measurements and searches for physics beyond the standard model at the LHC rely on the efficient identification of heavy-flavour jets, i.e. jets originating from bottom or charm quarks. In this paper, the discriminating variables and the algorithms used for heavy-flavour jet identification during the first years of operation of the CMS experiment in proton-proton collisions at a centre-of-mass energy of 13 TeV, are presented. Heavy-flavour jet identification algorithms have been improved compared to those used previously at centre-of-mass energies of 7 and 8 TeV. For jets with transverse momenta in the range expected in simulated events, these new developments result in an efficiency of 68% for the correct identification of a b jet for a probability of 1% of misidentifying a light-flavour jet. The improvement in relative efficiency at this misidentification probability is about 15%, compared to previous CMS algorithms. In addition, for the first time algorithms have been developed to identify jets containing two b hadrons in Lorentz-boosted event topologies, as well as to tag c jets. The large data sample recorded in 2016 at a centre-of-mass energy of 13 TeV has also allowed the development of new methods to measure the efficiency and misidentification probability of heavy-flavour jet identification algorithms. The b jet identification efficiency is measured with a precision of a few per cent at moderate jet transverse momenta (between 30 and 300 GeV) and about 5% at the highest jet transverse momenta (between 500 and 1000 GeV).

Patterns of New Physics in b → sℓ+ℓ− transitions in the light of recent data

Abstract: In the Standard Model (SM), the rare transitions where a bottom quark decays into a strange quark and a pair of light leptons exhibit a potential sensitivity to physics beyond the SM. In addition, the SM embeds Lepton Flavour Universality (LFU), leading to almost identical probabilities for muon and electron modes. The LHCb collaboration discovered a set of deviations from the SM expectations in decays to muons and also in ratios assessing LFU. Other experiments (Belle, ATLAS, CMS) found consistent measurements, albeit with large error bars. We perform a global fit to all available b → sl+l− data (l = e, μ) in a model-independent way allowing for different patterns of New Physics. For the first time, the NP hypothesis is preferred over the SM by 5 σ in a general case when NP can enter SM-like operators and their chirally-flipped partners. LFU violation is favoured with respect to LFU at the 3-4 σ level. We discuss the impact of LFU-violating New Physics on the observable P 5 ′ from B → K∗μ+μ− and we compare our estimate for long-distance charm contributions with an empirical model recently proposed by a group of LHCb experimentalists. Finally, we discuss NP models able to describe this consistent pattern of deviations.

Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2

Abstract: The search for improved energy-storage materials has revealed Li- and Na-rich intercalation compounds as promising high-capacity cathodes. They exhibit capacities in excess of what would be expected from alkali-ion removal/reinsertion and charge compensation by transition-metal (TM) ions. The additional capacity is provided through charge compensation by oxygen redox chemistry and some oxygen loss. It has been reported previously that oxygen redox occurs in O 2p orbitals that interact with alkali ions in the TM and alkali-ion layers (that is, oxygen redox occurs in compounds containing Li+-O(2p)-Li+ interactions). Na2/3[Mg0.28Mn0.72]O2 exhibits an excess capacity and here we show that this is caused by oxygen redox, even though Mg2+ resides in the TM layers rather than alkali-metal (AM) ions, which demonstrates that excess AM ions are not required to activate oxygen redox. We also show that, unlike the alkali-rich compounds, Na2/3[Mg0.28Mn0.72]O2 does not lose oxygen. The extraction of alkali ions from the alkali and TM layers in the alkali-rich compounds results in severely underbonded oxygen, which promotes oxygen loss, whereas Mg2+ remains in Na2/3[Mg0.28Mn0.72]O2, which stabilizes oxygen.

Unravelling structure sensitivity in CO 2 hydrogenation over nickel

Abstract: Continuous efforts in the field of materials science have allowed us to generate smaller and smaller metal nanoparticles, creating new opportunities to understand catalytic properties that depend on the metal particle size. Structure sensitivity is the phenomenon where not all surface atoms in a supported metal catalyst have the same activity. Understanding structure sensitivity can assist in the rational design of catalysts, allowing control over mechanisms, activity and selectivity, and thus even the viability of a catalytic reaction. Here, using a unique set of well-defined silica-supported Ni nanoclusters (1–7 nm) and advanced characterization methods, we prove how structure sensitivity influences the mechanism of catalytic CO2 reduction, the nature of which has been long debated. These findings bring fundamental new understanding of CO2 hydrogenation over Ni and allow us to control both activity and selectivity, which can be a means for CO2 emission abatement through its valorization as a low- or even negative-cost feedstock on a low-cost transition-metal catalyst.

B Meson Anomalies in a Pati-Salam Model within the Randall-Sundrum Background.

Abstract: Lepton number as a fourth color is the intriguing theoretical idea of the famous Pati-Salam (PS) model. While in conventional PS models, the symmetry breaking scale and the mass of the resulting vector leptoquark are stringently constrained by K_{L}→μe and K→πμe, the scale can be lowered to a few TeV by adding vectorlike fermions. Furthermore, in this case, the intriguing hints for lepton flavor universality violation in b→sμ^{+}μ^{-} and b→cτν processes can be addressed. Such a setup is naturally achieved by implementing the PS gauge group in the five-dimensional Randall-Sundrum background. The PS symmetry is broken by boundary conditions on the fifth dimension, and the resulting massive vector leptoquark automatically has the same mass scale as the vectorlike fermions and all other resonances. We consider the phenomenology of this model in the context of the hints for lepton flavor universality violation in semileptonic B decays. Assuming flavor alignment in the down sector, we find that in b→sl^{+}l^{-} transitions, the observed deviations from the standard model predictions [including R(K) and R(K^{*})] can be explained with natural values for the free parameters of the model. Even though we find sizable effects in R(D), R(D^{*}), and R(J/Ψ), one cannot account for the current central values in the constrained setup of our minimal model due to the stringent constraints from D-D[over ¯] mixing and τ→3μ.

Performance of the CMS muon detector and muon reconstruction with proton-proton collisions at s=13 TeV

Abstract: The CMS muon detector system, muon reconstruction software, and high-level trigger underwent significant changes in 2013–2014 in preparation for running at higher LHC collision energy and instantaneous luminosity. The performance of the modified system is studied using proton-proton collision data at center-of-mass energy √s=13 TeV, collected at the LHC in 2015 and 2016. The measured performance parameters, including spatial resolution, efficiency, and timing, are found to meet all design specifications and are well reproduced by simulation. Despite the more challenging running conditions, the modified muon system is found to perform as well as, and in many aspects better than, previously. We dedicate this paper to the memory of Prof. Alberto Benvenuti, whose work was fundamental for the CMS muon detector.

Current-driven dynamics and inhibition of the skyrmion Hall effect of ferrimagnetic skyrmions in GdFeCo films.

Abstract: Magnetic skyrmions are swirling magnetic textures with novel characteristics suitable for future spintronic and topological applications. Recent studies confirmed the room-temperature stabilization of skyrmions in ultrathin ferromagnets. However, such ferromagnetic skyrmions show an undesirable topological effect, the skyrmion Hall effect, which leads to their current-driven motion towards device edges, where skyrmions could easily be annihilated by topographic defects. Recent theoretical studies have predicted enhanced current-driven behavior for antiferromagnetically exchange-coupled skyrmions. Here we present the stabilization of these skyrmions and their current-driven dynamics in ferrimagnetic GdFeCo films. By utilizing element-specific X-ray imaging, we find that the skyrmions in the Gd and FeCo sublayers are antiferromagnetically exchange-coupled. We further confirm that ferrimagnetic skyrmions can move at a velocity of ~50 m s−1 with reduced skyrmion Hall angle, |θSkHE| ~ 20°. Our findings open the door to ferrimagnetic and antiferromagnetic skyrmionics while providing key experimental evidences of recent theoretical studies. Non-zero topological charge prevents the straight motion of ferromagnetic skyrmions and hinders their applications. Here, the authors report the stabilization and current-driven dynamics of skyrmions in GdFeCo films in which the ferrimagnetic skyrmions can move with high velocity and reduced skyrmion Hall angle.

Surface distortion as a unifying concept and descriptor in oxygen reduction reaction electrocatalysis

Abstract: Tuning the surface structure at the atomic level is of primary importance to simultaneously meet the electrocatalytic performance and stability criteria required for the development of low-temperature proton-exchange membrane fuel cells (PEMFCs). However, transposing the knowledge acquired on extended, model surfaces to practical nanomaterials remains highly challenging. Here, we propose ‘surface distortion’ as a novel structural descriptor, which is able to reconciliate and unify seemingly opposing notions and contradictory experimental observations in regards to the electrocatalytic oxygen reduction reaction (ORR) reactivity. Beyond its unifying character, we show that surface distortion is pivotal to rationalize the electrocatalytic properties of state-of-the-art of PtNi/C nanocatalysts with distinct atomic composition, size, shape and degree of surface defectiveness under a simulated PEMFC cathode environment. Our study brings fundamental and practical insights into the role of surface defects in electrocatalysis and highlights strategies to design more durable ORR nanocatalysts. Tuning surface structure is key for electrocatalytic performance and stability of proton-exchange membrane fuel cells. Surface distortion as a structural descriptor can help to clarify the role of surface defects and to design enhanced nanocatalysts.

Combined explanations of (g -2 )μ ,e and implications for a large muon EDM

Abstract: With the long-standing tension between experiment and standard-model (SM) prediction in the anomalous magnetic moment of the muon, ${a}_{\ensuremath{\mu}}=(g\ensuremath{-}2{)}_{\ensuremath{\mu}}/2$, at the level of $3--4\ensuremath{\sigma}$, it is natural to ask if there could be a sizable effect in the electric dipole moment (EDM) ${d}_{\ensuremath{\mu}}$ as well. In this context it has often been argued that in UV complete models the electron EDM, which is very precisely measured, excludes a large effect in ${d}_{\ensuremath{\mu}}$. However, the recently observed $2.5\ensuremath{\sigma}$ tension in ${a}_{e}=(g\ensuremath{-}2{)}_{e}/2$, if confirmed, requires that the muon and electron sectors effectively decouple to avoid constraints from $\ensuremath{\mu}\ensuremath{\rightarrow}e\ensuremath{\gamma}$. We briefly discuss UV complete models that possess such a decoupling, which can be enforced by an Abelian flavor symmetry ${L}_{\ensuremath{\mu}}\ensuremath{-}{L}_{\ensuremath{\tau}}$. We show that, in such scenarios, there is no reason to expect a correlation between the electron and muon EDM, so that the latter can be sizable. New limits on ${d}_{\ensuremath{\mu}}$ improved by up to two orders of magnitude are expected from the upcoming $(g\ensuremath{-}2{)}_{\ensuremath{\mu}}$ experiments at Fermilab and J-PARC. Beyond, a proposed dedicated muon EDM experiment at PSI could further advance the limit. In this way, future improved measurements of ${a}_{e}$, ${a}_{\ensuremath{\mu}}$, as well as the fine-structure constant $\ensuremath{\alpha}$ are not only set to provide exciting precision tests of the SM, but, in combination with EDMs, to reveal crucial insights into the flavor structure of physics beyond the SM.

Model of vector leptoquarks in view of the B -physics anomalies

Abstract: Lepton number as a fourth color is an intriguing theoretical idea which is combined with a possible left-right symmetry within the famous Pati-Salam (PS) model. In the conventional PS model, a spontaneous breaking of the PS gauge group down to the SM, one can only take place at very high scales (above the PeV scale) due to the stringent bounds from ${K}_{L}\ensuremath{\rightarrow}\ensuremath{\mu}e$ and $K\ensuremath{\rightarrow}\ensuremath{\pi}\ensuremath{\mu}e$ induced by the resulting vector leptoquarks. In this paper, we show that these constraints can be avoided once additional vectorlike fermions are introduced and, thus, a breaking at the TeV scale is possible. We consider the flavor phenomenology of this model in the context of the intriguing hints for new physics in semileptonic $B$ decays. The necessary violation of lepton flavor universality is induced by mixing SM and vectorlike fermions. Concerning $R(D)$ and $R({D}^{*})$, we find that sizable effects are possible while respecting the bounds from other flavor observables but predicting a large enhancement of ${B}_{s}\ensuremath{\rightarrow}{\ensuremath{\tau}}^{+}{\ensuremath{\tau}}^{\ensuremath{-}}$. Furthermore, also in $b\ensuremath{\rightarrow}s{\ensuremath{\ell}}^{+}{\ensuremath{\ell}}^{\ensuremath{-}}$ transitions, the observed deviations from the SM predictions [including $R(K)$ and $R({K}^{*})$] can be explained with natural values for the free parameters of the model without any fine-tuning, predicting sizable decay rates for $b\ensuremath{\rightarrow}s\ensuremath{\tau}\ensuremath{\mu}$. Finally, the anomaly in the anomalous magnetic moment of the muon can be accounted for by a loop contribution involving the vector leptoquark and vectorlike leptons.

The design of the MEG II experiment

Abstract: The MEG experiment, designed to search for the $${\mu ^+ \rightarrow \hbox {e}^+ \gamma }$$ decay, completed data-taking in 2013 reaching a sensitivity level of $${5.3\times 10^{-13}}$$ for the branching ratio. In order to increase the sensitivity reach of the experiment by an order of magnitude to the level of $$6\times 10^{-14}$$ , a total upgrade, involving substantial changes to the experiment, has been undertaken, known as MEG II. We present both the motivation for the upgrade and a detailed overview of the design of the experiment and of the expected detector performance.

Retinal isomerization in bacteriorhodopsin captured by a femtosecond x-ray laser

Abstract: Ultrafast isomerization of retinal is the primary step in photoresponsive biological functions including vision in humans and ion transport across bacterial membranes. We used an x-ray laser to study the subpicosecond structural dynamics of retinal isomerization in the light-driven proton pump bacteriorhodopsin. A series of structural snapshots with near-atomic spatial resolution and temporal resolution in the femtosecond regime show how the excited all-trans retinal samples conformational states within the protein binding pocket before passing through a twisted geometry and emerging in the 13-cis conformation. Our findings suggest ultrafast collective motions of aspartic acid residues and functional water molecules in the proximity of the retinal Schiff base as a key facet of this stereoselective and efficient photochemical reaction.

Search for Heavy Neutral Leptons in Events with Three Charged Leptons in Proton-Proton Collisions at √s = 13 TeV

Abstract: A search for a heavy neutral lepton N of Majorana nature decaying into a W boson and a charged lepton is performed using the CMS detector at the LHC. The targeted signature consists of three prompt charged leptons in any flavor combination of electrons and muons. The data were collected in proton-proton collisions at a center-of-mass energy of 13 TeV, with an integrated luminosity of 35.9 fb^(−1). The search is performed in the N mass range between 1 GeV and 1.2 TeV. The data are found to be consistent with the expected standard model background. Upper limits are set on the values of |V_(eN)|^2and |V_(μN)|^2, where V_(lN) is the matrix element describing the mixing of N with the standard model neutrino of flavor l. These are the first direct limits for N masses above 500 GeV and the first limits obtained at a hadron collider for N masses below 40 GeV.

The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review

Abstract: Predicting the formation of ice in the atmosphere presents one of the great challenges in physical sciences with important implications for the chemistry and composition of the Earth’s atmosphere, the hydrological cycle, and climate. Among atmospheric ice formation processes, heterogeneous ice nucleation proceeds on aerosol particles ranging from a few nanometers to micrometers in size, commonly referred to as ice nucleating particles (INPs). Research over the last two decades has demonstrated that organic matter (OM) is ubiquitous in the atmosphere, present as organic aerosol (OA) particles or as coatings on other particle types. The physicochemical properties of OM make predicting how OM can contribute to the INP population challenging. This review focuses on the role of OM in INPs, summarizing and highlighting recent advances in our understanding of the ice nucleation process gained from theoretical, laboratory, and field studies. Examination of ice residuals and INPs with analytical techniques demonst...

Rapid Structure Determination of Microcrystalline Molecular Compounds Using Electron Diffraction.

Abstract: Chemists of all fields currently publish about 50 000 crystal structures per year, the vast majority of which are X-ray structures. We determined two molecular structures by employing electron rather than X-ray diffraction. For this purpose, an EIGER hybrid pixel detector was fitted to a transmission electron microscope, yielding an electron diffractometer. The structure of a new methylene blue derivative was determined at 0.9 A resolution from a crystal smaller than 1×2 μm2 . Several thousand active pharmaceutical ingredients (APIs) are only available as submicrocrystalline powders. To illustrate the potential of electron crystallography for the pharmaceutical industry, we also determined the structure of an API from its pill. We demonstrate that electron crystallography complements X-ray crystallography and is the technique of choice for all unsolved cases in which submicrometer-sized crystals were the limiting factor.

Search for narrow and broad dijet resonances in proton-proton collisions at √s=13 TeV and constraints on dark matter mediators and other new particles

Abstract: Searches for resonances decaying into pairs of jets are performed using proton-proton collision data collected at s√=13 TeV corresponding to an integrated luminosity of up to 36 fb−1. A low-mass search, for resonances with masses between 0.6 and 1.6 TeV, is performed based on events with dijets reconstructed at the trigger level from calorimeter information. A high-mass search, for resonances with masses above 1.6 TeV, is performed using dijets reconstructed offline with a particle-flow algorithm. The dijet mass spectrum is well described by a smooth parameterization and no evidence for the production of new particles is observed. Upper limits at 95% confidence level are reported on the production cross section for narrow resonances with masses above 0.6 TeV. In the context of specific models, the limits exclude string resonances with masses below 7.7 TeV, scalar diquarks below 7.2 TeV, axigluons and colorons below 6.1 TeV, excited quarks below 6.0 TeV, color-octet scalars below 3.4 TeV, W′ bosons below 3.3 TeV, Z′ bosons below 2.7 TeV, Randall-Sundrum gravitons below 1.8 TeV and in the range 1.9 to 2.5 TeV, and dark matter mediators below 2.6 TeV. The limits on both vector and axial-vector mediators, in a simplified model of interactions between quarks and dark matter particles, are presented as functions of dark matter particle mass and coupling to quarks. Searches are also presented for broad resonances, including for the first time spin-1 resonances with intrinsic widths as large as 30% of the resonance mass. The broad resonance search improves and extends the exclusions of a dark matter mediator to larger values of its mass and coupling to quarks.

Time-resolved copper speciation during selective catalytic reduction of NO on Cu-SSZ-13

Abstract: Practical catalysts often operate under dynamic conditions of temperature variations and sudden changes of feed composition that call for understanding of operation and catalyst structure under analogous experimental conditions. For instance, the copper-exchanged small-pore SSZ-13 catalyst used currently in the selective catalytic reduction of harmful nitrogen oxides from the exhaust gas of diesel-fuelled vehicles operates under recurrent ammonia dosage. Here, we report the design of unsteady state experiments that mimic such a dynamic environment to obtain key mechanistic information on this reaction. Through the combination of time-resolved X-ray absorption spectroscopy and transient experimentation, we were able to capture an ammonia inhibition effect on the rate-limiting copper re-oxidation at low temperature. The practical relevance of this observation was demonstrated by optimization of the ammonia dosage on a catalyst washcoat on cordierite honeycomb, resulting in lower ammonia consumption and an increase in nitrogen oxide conversion at low temperature. Selective catalytic reduction is employed at the exhaust of diesel vehicles to abate nitrogen oxide emissions. Now, guided by time-resolved X-ray absorption spectroscopy and transient experiments using Cu-SSZ-13 as the catalyst, the authors unravel important features of the reaction mechanism that allow the performance of the catalyst to be improved.

Stable complete methane oxidation over palladium based zeolite catalysts.

Abstract: Increasing the use of natural gas engines is an important step to reduce the carbon footprint of mobility and power generation sectors. To avoid emissions of unburnt methane and the associated severe greenhouse effect of lean-burn engines, the stability of methane oxidation catalysts against steam-induced sintering at low temperatures (<500 °C) needs to be improved. Here we demonstrate how the combination of catalyst development and improved process control yields a highly efficient solution for complete methane oxidation. We design a material based on palladium and hierarchical zeolite with fully sodium-exchanged acid sites, which improves the support stability and prevents steam-induced palladium sintering under reaction conditions by confining the metal within the zeolite. Repeated short reducing pulses enable the use of a highly active transient state of the catalyst, which in combination with its high stability provides excellent performance without deactivation for over 90 h in the presence of steam.

Combined search for electroweak production of charginos and neutralinos in proton-proton collisions at √s=13 TeV

Abstract: A statistical combination of several searches for the electroweak production of charginos and neutralinos is presented. All searches use proton-proton collision data at $ \sqrt{s}=13 $ TeV, recorded with the CMS detector at the LHC in 2016 and corresponding to an integrated luminosity of 35.9 fb$^{−1}$. In addition to the combination of previous searches, a targeted analysis requiring three or more charged leptons (electrons or muons) is presented, focusing on the challenging scenario in which the difference in mass between the two least massive neutralinos is approximately equal to the mass of the Z boson. The results are interpreted in simplified models of chargino-neutralino or neutralino pair production. For chargino-neutralino production, in the case when the lightest neutralino is massless, the combination yields an observed (expected) limit at the 95% confidence level on the chargino mass of up to 650 (570) GeV, improving upon the individual analysis limits by up to 40 GeV. If the mass difference between the two least massive neutralinos is approximately equal to the mass of the Z boson in the chargino-neutralino model, the targeted search requiring three or more leptons obtains observed and expected exclusion limits of around 225 GeV on the second neutralino mass and 125 GeV on the lightest neutralino mass, improving the observed limit by about 60 GeV in both masses compared to the previous CMS result. In the neutralino pair production model, the combined observed (expected) exclusion limit on the neutralino mass extends up to 650–750 (550–750) GeV, depending on the branching fraction assumed. This extends the observed exclusion achieved in the individual analyses by up to 200 GeV. The combined result additionally excludes some intermediate gaps in the mass coverage of the individual analyses.

Multicomponent new particle formation from sulfuric acid, ammonia, and biogenic vapors

Abstract: A major fraction of atmospheric aerosol particles, which affect both air quality and climate, form from gaseous precursors in the atmosphere. Highly oxygenated organic molecules (HOMs), formed by oxidation of biogenic volatile organic compounds, are known to participate in particle formation and growth. However, it is not well understood how they interact with atmospheric pollutants, such as nitrogen oxides (NOx) and sulfur oxides (SOx) from fossil fuel combustion, as well as ammonia (NH3) from livestock and fertilizers. Here, we show how NOx suppresses particle formation, while HOMs, sulfuric acid, and NH3 have a synergistic enhancing effect on particle formation. We postulate a novel mechanism, involving HOMs, sulfuric acid, and ammonia, which is able to closely reproduce observations of particle formation and growth in daytime boreal forest and similar environments. The findings elucidate the complex interactions between biogenic and anthropogenic vapors in the atmospheric aerosol system.

Search for electroweak production of charginos and neutralinos in multilepton final states in proton-proton collisions at √s=13 TeV

Abstract: Results are presented from a search for the direct electroweak production of charginos and neutralinos in signatures with either two or more leptons (electrons or muons) of the same electric charge, or with three or more leptons, which can include up to two hadronically decaying tau leptons. The results are based on a sample of proton-proton collision data collected at $ \sqrt{s}=13 $ TeV, recorded with the CMS detector at the LHC, corresponding to an integrated luminosity of 35.9 fb$^{−1}$. The observed event yields are consistent with the expectations based on the standard model. The results are interpreted in simplified models of supersymmetry describing various scenarios for the production and decay of charginos and neutralinos. Depending on the model parameters chosen, mass values between 180 GeV and 1150 GeV are excluded at 95% CL. These results significantly extend the parameter space probed for these particles in searches at the LHC. In addition, results are presented in a form suitable for alternative theoretical interpretations.

Observation of two types of fractional excitation in the Kitaev honeycomb magnet

Abstract: Quantum spin liquid is a disordered but highly entangled magnetic state with fractional spin excitations1. The ground state of an exactly solved Kitaev honeycomb model is perhaps its clearest example2. Under a magnetic field, a spin flip in this model fractionalizes into two types of anyon, a quasiparticle with more complex exchange statistics than standard fermions or bosons: a pair of gauge fluxes and a Majorana fermion2,3. Here, we demonstrate this kind of fractionalization in the Kitaev paramagnetic state of the honeycomb magnet α-RuCl3. The spin excitation gap determined by nuclear magnetic resonance consists of the predicted Majorana fermion contribution following the cube of the applied magnetic field2,4,5, and a finite zero-field contribution matching the predicted size of the gauge flux gap2,6. The observed fractionalization into gapped anyons survives in a broad range of temperatures and magnetic fields, which establishes α-RuCl3 as a unique platform for future investigations of anyons.

Electronic structures and unusually robust bandgap in an ultrahigh-mobility layered oxide semiconductor, Bi2O2Se

Abstract: Semiconductors are essential materials that affect our everyday life in the modern world Two-dimensional semiconductors with high mobility and moderate bandgap are particularly attractive today because of their potential application in fast, low-power, and ultrasmall/thin electronic devices We investigate the electronic structures of a new layered air-stable oxide semiconductor, Bi2O2Se, with ultrahigh mobility (~28 × 105 cm2/V⋅s at 20 K) and moderate bandgap (~08 eV) Combining angle-resolved photoemission spectroscopy and scanning tunneling microscopy, we mapped out the complete band structures of Bi2O2Se with key parameters (for example, effective mass, Fermi velocity, and bandgap) The unusual spatial uniformity of the bandgap without undesired in-gap states on the sample surface with up to ~50% defects makes Bi2O2Se an ideal semiconductor for future electronic applications In addition, the structural compatibility between Bi2O2Se and interesting perovskite oxides (for example, cuprate high–transition temperature superconductors and commonly used substrate material SrTiO3) further makes heterostructures between Bi2O2Se and these oxides possible platforms for realizing novel physical phenomena, such as topological superconductivity, Josephson junction field-effect transistor, new superconducting optoelectronics, and novel lasers

Measurement of the inelastic proton-proton cross section at √s=13 TeV

Abstract: A measurement of the inelastic proton-proton cross section with the CMS detector at a center-of-mass energy of $ \sqrt{s}=13 $ TeV is presented. The analysis is based on events with energy deposits in the forward calorimeters, which cover pseudorapidities of −6.6 4.1 GeV and/or M$_{Y}$ > 13 GeV, where M$_{X}$ and M$_{Y}$ are the masses of the diffractive dissociation systems at negative and positive pseudorapidities, respectively. The results are compared with those from other experiments as well as to predictions from high-energy hadron-hadron interaction models.