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Institution

Paul Scherrer Institute

FacilityVilligen, Switzerland
About: Paul Scherrer Institute is a facility organization based out in Villigen, Switzerland. It is known for research contribution in the topics: Neutron & Large Hadron Collider. The organization has 9248 authors who have published 23984 publications receiving 890129 citations. The organization is also known as: PSI.


Papers
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Journal ArticleDOI
TL;DR: Stealth liposomes comprising self-assembled superparamagnetic iron oxide nanoparticles individually stabilized with palmityl-nitroDOPA incorporated in the lipid membrane are demonstrated to be able to control timing and dose of repeatedly released cargo from such vesicles.
Abstract: The ideal nanoscale drug delivery vehicle allows control over the released dose in space and time. We demonstrate that this can be achieved by stealth liposomes comprising self-assembled superparamagnetic iron oxide nanoparticles (NPs) individually stabilized with palmityl-nitroDOPA incorporated in the lipid membrane. Alternating magnetic fields were used to control timing and dose of repeatedly released cargo from such vesicles by locally heating the membrane, which changed its permeability without major effects on the environment.

352 citations

Journal ArticleDOI
29 Jun 2017-Nature
TL;DR: An angle-resolved photoemission spectroscopy is used to demonstrate the existence of a triply degenerate point in the electronic structure of crystalline molybdenum phosphide, which opens up a way of exploring the new physics of unconventional fermions in condensed-matter systems.
Abstract: In quantum field theory, Lorentz invariance leads to three types of fermion-Dirac, Weyl and Majorana. Although the existence of Weyl and Majorana fermions as elementary particles in high-energy physics is debated, all three types of fermion have been proposed to exist as low-energy, long-wavelength quasiparticle excitations in condensed-matter systems. The existence of Dirac and Weyl fermions in condensed-matter systems has been confirmed experimentally, and that of Majorana fermions is supported by various experiments. However, in condensed-matter systems, fermions in crystals are constrained by the symmetries of the 230 crystal space groups rather than by Lorentz invariance, giving rise to the possibility of finding other types of fermionic excitation that have no counterparts in high-energy physics. Here we use angle-resolved photoemission spectroscopy to demonstrate the existence of a triply degenerate point in the electronic structure of crystalline molybdenum phosphide. Quasiparticle excitations near a triply degenerate point are three-component fermions, beyond the conventional Dirac-Weyl-Majorana classification, which attributes Dirac and Weyl fermions to four- and two-fold degenerate points, respectively. We also observe pairs of Weyl points in the bulk electronic structure of the crystal that coexist with the three-component fermions. This material thus represents a platform for studying the interplay between different types of fermions. Our experimental discovery opens up a way of exploring the new physics of unconventional fermions in condensed-matter systems.

352 citations

Journal ArticleDOI
TL;DR: The concentration, size, and composition of non-refractory submicron aerosol (NR-PM1) was measured over Mexico City and central Mexico with a HR-ToF-AMS onboard the NSF/NCAR C-130 aircraft as part of the MILAGRO field campaign as discussed by the authors.
Abstract: The concentration, size, and composition of non-refractory submicron aerosol (NR-PM1) was measured over Mexico City and central Mexico with a High-Resolution Time-of-Flight Aerosol Mass Spectrometer (HR-ToF-AMS) onboard the NSF/NCAR C-130 aircraft as part of the MILAGRO field campaign. This was the first aircraft deployment of the HR-ToF-AMS. During the campaign the instrument performed very well, and provided 12 s data. The aerosol mass from the AMS correlates strongly with other aerosol measurements on board the aircraft. Organic aerosol (OA) species dominate the NR-PM1 mass. OA correlates strongly with CO and HCN indicating that pollution (mostly secondary OA, SOA) and biomass burning (BB) are the main OA sources. The OA to CO ratio indicates a typical value for aged air of around 80 μg m−3 (STP) ppm−1. This is within the range observed in outflow from the Northeastern US, which could be due to a compensating effect between higher BB but lower biogenic VOC emissions during this study. The O/C atomic ratio for OA is calculated from the HR mass spectra and shows a clear increase with photochemical age, as SOA forms rapidly and quickly overwhelms primary urban OA, consistent with Volkamer et al. (2006) and Kleinman et al. (2008). The stability of the OA/CO while O/C increases with photochemical age implies a net loss of carbon from the OA. BB OA is marked by signals at m/z 60 and 73, and also by a signal enhancement at large m/z indicative of larger molecules or more resistance to fragmentation. The main inorganic components show different spatial patterns and size distributions. Sulfate is regional in nature with clear volcanic and petrochemical/power plant sources, while the urban area is not a major regional source for this species. Nitrate is enhanced significantly in the urban area and immediate outflow, and is strongly correlated with CO indicating a strong urban source. The importance of nitrate decreases with distance from the city likely due to evaporation. BB does not appear to be a strong source of nitrate despite its high emissions of nitrogen oxides, presumably due to low ammonia emissions. NR-chloride often correlates with HCN indicating a fire source, although other sources likely contribute as well. This is the first aircraft study of the regional evolution of aerosol chemistry from a tropical megacity.

351 citations

Journal ArticleDOI
TL;DR: In this paper, 14C was determined in elemental carbon (EC) and different organic carbon (OC) fractions from ambient urban aerosols with aerodynamic diameter <10 μm collected in Zurich (Switzerland).
Abstract: [1] Many open questions exist about the importance of different sources of carbonaceous aerosol, which is a substantial contributor to the global aerosol budget and, therefore, to climate change and human mortality. In this work, 14C was determined in elemental carbon (EC) and different organic carbon (OC) fractions from ambient urban aerosols with aerodynamic diameter <10 μm collected in Zurich (Switzerland). This enabled a more detailed source attribution of the carbonaceous aerosol mass than is possible with other currently available methods. The three major sources, fossil fuel, wood combustion (both anthropogenic emissions), and biogenic emissions, were quantified, making specific regulatory air quality management measures possible. EC originates nearly exclusively from fossil fuel usage during summer, whereas biomass-burning emissions become substantial during winter with ∼25%, even though this source contributes only marginally to the local energy consumption. For OC, biogenic sources are dominant in summer with ∼60%, where secondary organic aerosol prevails. Wood combustion accounts for up to ∼41% of OC in winter. Fossil fuels represent ∼30% of OC throughout the year.

350 citations

Journal ArticleDOI
TL;DR: In this article, the authors used long-term δ13C tree-ring measurements across a European forest network to reconstruct the physiologically driven response of intercellular CO2 caused by atmospheric CO2 (Ca) trends.
Abstract: Considering the combined effects of CO2 fertilization and climate change drivers on plant physiology leads to a modest increase in simulated European forest transpiration in spite of the effects of CO2-induced stomatal closure. The Earth’s carbon and hydrologic cycles are intimately coupled by gas exchange through plant stomata1,2,3. However, uncertainties in the magnitude4,5,6 and consequences7,8 of the physiological responses9,10 of plants to elevated CO2 in natural environments hinders modelling of terrestrial water cycling and carbon storage11. Here we use annually resolved long-term δ13C tree-ring measurements across a European forest network to reconstruct the physiologically driven response of intercellular CO2 (Ci) caused by atmospheric CO2 (Ca) trends. When removing meteorological signals from the δ13C measurements, we find that trees across Europe regulated gas exchange so that for one ppmv atmospheric CO2 increase, Ci increased by ∼0.76 ppmv, most consistent with moderate control towards a constant Ci/Ca ratio. This response corresponds to twentieth-century intrinsic water-use efficiency (iWUE) increases of 14 ± 10 and 22 ± 6% at broadleaf and coniferous sites, respectively. An ensemble of process-based global vegetation models shows similar CO2 effects on iWUE trends. Yet, when operating these models with climate drivers reintroduced, despite decreased stomatal opening, 5% increases in European forest transpiration are calculated over the twentieth century. This counterintuitive result arises from lengthened growing seasons, enhanced evaporative demand in a warming climate, and increased leaf area, which together oppose effects of CO2-induced stomatal closure. Our study questions changes to the hydrological cycle, such as reductions in transpiration and air humidity, hypothesized to result from plant responses to anthropogenic emissions.

349 citations


Authors

Showing all 9348 results

NameH-indexPapersCitations
Andrea Bocci1722402176461
Tobin J. Marks1591621111604
Wolfgang Wagner1562342123391
David D'Enterria1501592116210
Andreas Pfeiffer1491756131080
Christoph Grab1441359144174
Maurizio Pierini1431782104406
Alexander Belyaev1421895100796
Ajit Kumar Mohanty141112493062
Felicitas Pauss1411623104493
Chiara Mariotti141142698157
Luc Pape1411441130253
Rainer Wallny1411661105387
Roland Horisberger1391471100458
Emmanuelle Perez138155099016
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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
202363
2022199
20211,299
20201,442
20191,330
20181,298