Showing papers by "Pierre-and-Marie-Curie University published in 2002"

Chemical strategies to design textured materials: from microporous and mesoporous oxides to nanonetworks and hierarchical structures.

Abstract: 3.

Global sea-air CO2 flux based on climatological surface ocean pCO2, and seasonal biological and temperature effects

Abstract: Based on about 940,000 measurements of surface-water pCO2 obtained since the International Geophysical Year of 1956–59, the climatological, monthly distribution of pCO2 in the global surface waters representing mean non-El Nino conditions has been obtained with a spatial resolution of 4°×5° for a reference year 1995. The monthly and annual net sea–air CO2 flux has been computed using the NCEP/NCAR 41-year mean monthly wind speeds. An annual net uptake flux of CO2 by the global oceans has been estimated to be 2.2 (+22% or ?19%) Pg C yr?1 using the (wind speed)2 dependence of the CO2 gas transfer velocity of Wanninkhof (J. Geophys. Res. 97 (1992) 7373). The errors associated with the wind-speed variation have been estimated using one standard deviation (about±2 m s?1) from the mean monthly wind speed observed over each 4°×5° pixel area of the global oceans. The new global uptake flux obtained with the Wanninkhof (wind speed)2 dependence is compared with those obtained previously using a smaller number of measurements, about 250,000 and 550,000, respectively, and are found to be consistent within±0.2 Pg C yr?1. This estimate for the global ocean uptake flux is consistent with the values of 2.0±0.6 Pg C yr?1 estimated on the basis of the observed changes in the atmospheric CO2 and oxygen concentrations during the 1990s (Nature 381 (1996) 218; Science 287 (2000) 2467). However, if the (wind speed)3 dependence of Wanninkhof and McGillis (Res. Lett. 26 (1999) 1889) is used instead, the annual ocean uptake as well as the sensitivity to wind-speed variability is increased by about 70%. A zone between 40° and 60° latitudes in both the northern and southern hemispheres is found to be a major sink for atmospheric CO2. In these areas, poleward-flowing warm waters meet and mix with the cold subpolar waters rich in nutrients. The pCO2 in the surface water is decreased by the cooling effect on warm waters and by the biological drawdown of pCO2 in subpolar waters. High wind speeds over these low pCO2 waters increase the CO2 uptake rate by the ocean waters. The pCO2 in surface waters of the global oceans varies seasonally over a wide range of about 60% above and below the current atmospheric pCO2 level of about 360 ?atm. A global map showing the seasonal amplitude of surface-water pCO2 is presented. The effect of biological utilization of CO2 is differentiated from that of seasonal temperature changes using seasonal temperature data. The seasonal amplitude of surface-water pCO2 in high-latitude waters located poleward of about 40° latitude and in the equatorial zone is dominated by the biology effect, whereas that in the temperate gyre regions is dominated by the temperature effect. These effects are about 6 months out of phase. Accordingly, along the boundaries between these two regimes, they tend to cancel each other, forming a zone of small pCO2 amplitude. In the oligotrophic waters of the northern and southern temperate gyres, the biology effect is about 35 ?atm on average. This is consistent with the biological export flux estimated by Laws et al. (Glob. Biogeochem. Cycles 14 (2000) 1231). Small areas such as the northwestern Arabian Sea and the eastern equatorial Pacific, where seasonal upwelling occurs, exhibit intense seasonal changes in pCO2 due to the biological drawdown of CO2.

Strength or toughness? A criterion for crack onset at a notch

Abstract: Both energy and stress criteria are necessary conditions for fracture but neither one nor the other are sufficient. Experiments by Parvizi et al. on transverse cracking in cross-ply laminates corroborate this assumption. Thanks to the singularity at the tip of the notch, the incremental form of the energy criterion gives a lower bound of admissible crack lengths. On the contrary, the stress criterion leads to an upper bound. The consistency between these two conditions provides a general form of a criterion for crack nucleation. It enjoys the desirable property of coinciding with the usual Griffith criterion to study the crack growth and with the stress criterion for the uniform traction along a straight edge. Comparisons with experiments carried out on homogeneous notched materials and on bimaterial structures show a good agreement.

Alternative Methods for the Preparation of Gold Nanoparticles Supported on TiO2

Abstract: The best current way to prepare Au/TiO2 catalysts is the method of deposition−precipitation with NaOH (DP NaOH) developed by Haruta and co-workers. With this method, it is possible to obtain small gold metal particles (2−3 nm), but the corresponding gold loading remains rather low (∼3 wt %). The main goal of this work is to investigate other methods of preparation of Au/TiO2 catalysts to obtain small gold metal particles (2−3 nm) and a higher Au loading. It is shown that anion adsorption with AuCl4- (AA) does not produce Au loading higher than 1.5 wt % and the average particle size is not very small (∼4 nm). Cation adsorption with Au(en)23+ (CA) leads to small particles (2 nm) when the solution/support contact time is moderate (1 h), but the Au loading does not exceed 2 wt %. The most promising method of preparation appears to be deposition−precipitation with urea (DP urea). Indeed, samples with gold particles as small as those obtained with DP NaOH (∼2 nm) can be prepared, and all gold in solution is dep...

The honesty of bird song: multiple constraints for multiple traits

Abstract: The function of bird song is closely linked to sexual selection. A fundamental question regarding the evolution of sexually selected male signals is how their honesty is maintained. The neural space required for storing a large song repertoire size has traditionally been identified as a key constraint. However, it is often forgotten that bird song is a multifaceted behaviour, and that the different characters that comprise it have specific costs. Recent research has revealed the existence of new constraints, such as social aggression or learning opportunities, which limit the expression of several song characteristics. We review the existing evidence for each of these constraints, revealing some major gaps in our knowledge of this fascinating biological system.

Childhood absence epilepsy: genes, channels, neurons and networks.

Abstract: Childhood absence epilepsy is an idiopathic, generalized non-convulsive epilepsy with a multifactorial genetic aetiology. Molecular-genetic analyses of affected human families and experimental models, together with neurobiological investigations, have led to important breakthroughs in the identification of candidate genes and loci, and potential pathophysiological mechanisms for this type of epilepsy. Here, we review these results, and compare the human and experimental phenotypes that have been investigated. Continuing efforts and comparisons of this type will help us to elucidate the multigenetic traits and pathophysiology of this form of generalized epilepsy.

Reliable Real-Time Solution of Parametrized Partial Differential Equations: Reduced-Basis Output Bound Methods

Abstract: We present a technique for the rapid and reliable prediction of linear-functional outputs of elliptic (and parabolic) partial differential equations with affine parameter dependence. The essential components are (i) (provably) rapidly convergent global reduced basis approximations, Galerkin projection onto a space W(sub N) spanned by solutions of the governing partial differential equation at N selected points in parameter space; (ii) a posteriori error estimation, relaxations of the error-residual equation that provide inexpensive yet sharp and rigorous bounds for the error in the outputs of interest; and (iii) off-line/on-line computational procedures, methods which decouple the generation and projection stages of the approximation process. The operation count for the on-line stage, in which, given a new parameter value, we calculate the output of interest and associated error bound, depends only on N (typically very small) and the parametric complexity of the problem; the method is thus ideally suited for the repeated and rapid evaluations required in the context of parameter estimation, design, optimization, and real-time control.

Traffic matrix estimation: existing techniques and new directions

Abstract: Very few techniques have been proposed for estimating traffic matrices in the context of Internet traffic. Our work on POP-to-POP traffic matrices (TM) makes two contributions. The primary contribution is the outcome of a detailed comparative evaluation of the three existing techniques. We evaluate these methods with respect to the estimation errors yielded, sensitivity to prior information required and sensitivity to the statistical assumptions they make. We study the impact of characteristics such as path length and the amount of link sharing on the estimation errors. Using actual data from a Tier-1 backbone, we assess the validity of the typical assumptions needed by the TM estimation techniques. The secondary contribution of our work is the proposal of a new direction for TM estimation based on using choice models to model POP fanouts. These models allow us to overcome some of the problems of existing methods because they can incorporate additional data and information about POPs and they enable us to make a fundamentally different kind of modeling assumption. We validate this approach by illustrating that our modeling assumption matches actual Internet data well. Using two initial simple models we provide a proof of concept showing that the incorporation of knowledge of POP features (such as total incoming bytes, number of customers, etc.) can reduce estimation errors. Our proposed approach can be used in conjunction with existing or future methods in that it can be used to generate good priors that serve as inputs to statistical inference techniques.

Observed Impact of Atlantic SST Anomalies on the North Atlantic Oscillation

Abstract: The large-scale patterns of covariability between monthly sea surface temperature (SST) and 500-mb height anomalies (Z500) in the Atlantic sector are investigated as a function of time lag in the NCEP‐NCAR reanalysis (1958‐97). In agreement with previous studies, the dominant signal is the atmospheric forcing of SST anomalies, but statistically significant covariances are also found when SST leads Z500 by several months. In winter, a PanAtlantic SST pattern precedes the North Atlantic oscillation (NAO) by up to 6 months. Such long lead time covariance is interpreted in the framework of the stochastic climate model, reflecting the forcing of the NAO by persistent Atlantic SST anomalies. A separate analysis of midlatitudes (208‐708N) and tropical (208S‐208N) SST anomalies reveals that the bulk of the NAO signal comes from the midlatitudes. A dipolar anomaly, with warm SST southeast of Newfoundland and cold SST to the northeast and southeast, precedes a positive phase of the NAO, and it should provide a prediction of up to 15% of its monthly variance several months in advance. Since the ‘‘forcing’’ SST pattern projects significantly onto the tripole pattern generated by the NAO, these results indicate a positive feedback between the SST tripole and the NAO, with a strength of up to . 25 mK 21 at 500 mb or 2‐3 mb K21 at sea level. Additionally, a warming of the tropical Atlantic (208S‐208N), roughly symmetric about the equator, induces a negative NAO phase in early winter. This tropical forcing of the NAO is nearly uncorrelated with and weaker than that resulting from the midlatitudes, and is associated with shorter lead times and reduced predictive skill.

Public Information and Breeding Habitat Selection in a Wild Bird Population

Abstract: According to the “public information” hypothesis, some animal species may monitor the current reproductive success of conspecifics to assess local habitat quality and to choose their own subsequent breeding site. To test this hypothesis experimentally, we manipulated two components of public information, the mean number of offspring raised locally (“quantity”) and their condition (“quality”), in the collared flycatcher Ficedula albicollis. Immigration rate decreased with local offspring quantity but did not depend on local offspring quality, suggesting that immigrants are deprived of information regarding local quality. Conversely, emigration rate increased both when local offspring quantity or quality decreased, suggesting that residents can use both components of public information.

Nitrogen retention in rivers: model development and application to watersheds in the northeastern U.S.A.

Abstract: A regression model (RivR-N) was developed that predicts the proportion of N removed from streams and reservoirs as an inverse function of the water displacement time of the water body (ratio of water body depth to water time of travel). When applied to 16 drainage networks in the eastern U.S., the RivR-N model predicted that 37% to 76% of N input to these rivers is removed during transport through the river networks. Approximately half of that is removed in 1st through 4th order streams which account for 90% of the total stream length. The other half is removed in 5th order and higher rivers which account for only about 10% of the total stream length. Most N removed in these higher orders is predicted to originate from watershed loading to small and intermediate sized streams. The proportion of N removed from all streams in the watersheds (37-76%) is considerably higher than the proportion of N input to an individual reach that is removed in that reach (generally <20%) because of the cumulative effect of continued nitrogen removal along the entire flow path in downstream reaches. This generally has not been recognized in previous studies, but is critical to an evaluation of the total amount of N removed within a river network. At the river network scale, reservoirs were predicted to have a minimal effect on N removal. A fairly modest decrease (<10 percentage points) in the N removed at the river network scale was predicted when a third of the direct watershed loading was to the two highest orders compared to a uniform loading.

Longitudinal Study of Motor Recovery After Stroke Recruitment and Focusing of Brain Activation

Abstract: Background and Purpose— The goal of this study was to characterize cortical reorganization after stroke and its relation with the site of the stroke-induced lesion and degree of motor recovery using functional MRI (fMRI) Methods— Fourteen stroke patients with an affected upper limb were studied longitudinally Three fMRI sessions were performed over a period of 1 to 6 months after stroke Upper limb recovery, Wallerian degeneration of the pyramidal tract, and responses to transcranial magnetic stimulation were assessed Results— Two main patterns of cortical reorganization were found Pattern 1 was focusing, in which, after initial recruitment of additional ipsilateral and contralateral areas, activation gradually developed toward a pattern of activation restricted to the contralateral sensorimotor cortex in 9 patients Five patients were found to have pattern 2, persistent recruitment, in which there was an initial and sustained recruitment of ipsilateral activity Occurrence of recruitment or focusing

Phase retrieval, error reduction algorithm, and Fienup variants: a view from convex optimization.

Abstract: The phase retrieval problem is of paramount importance in various areas of applied physics and engineering. The state of the art for solving this problem in two dimensions relies heavily on the pioneering work of Gerchberg, Saxton, and Fienup. Despite the widespread use of the algorithms proposed by these three researchers, current mathematical theory cannot explain their remarkable success. Nevertheless, great insight can be gained into the behavior, the shortcomings, and the performance of these algorithms from their possible counterparts in convex optimization theory. An important step in this direction was made two decades ago when the error reduction algorithm was identified as a nonconvex alternating projection algorithm. Our purpose is to formulate the phase retrieval problem with mathematical care and to establish new connections between well-established numerical phase retrieval schemes and classical convex optimization methods. Specifically, it is shown that Fienup’s basic input–output algorithm corresponds to Dykstra’s algorithm and that Fienup’s hybrid input–output algorithm can be viewed as an instance of the Douglas–Rachford algorithm. We provide a theoretical framework to better understand and, potentially, to improve existing phase recovery algorithms.

How much variance can be explained by ecologists and evolutionary biologists

Abstract: The average amount of variance explained by the main factor of interest in ecological and evolutionary studies is an important quantity because it allows evaluation of the general strength of research findings. It also has important implications for the planning of studies. Theoretically we should be able to explain 100% of the variance in data, but randomness and noise may reduce this amount considerably in biological studies. We performed a meta-analysis using data from 43 published meta-analyses in ecology and evolution with 93 estimates of mean effect size using Pearson's r and 136 estimates using Hedges' d or g. This revealed that (depending on the exact analysis) the mean amount of variance (r 2) explained was 2.51–5.42%. The various 95% confidence intervals fell between 1.99 and 7.05%. There was a strongly positive relationship between the fail-safe number (the number of null results needed to nullify an effect) and the coefficient of determination (r 2) or effect size. Analysis at the level of individual tests of null hypotheses showed that the amount of variance key factors explained differed among fields with the largest amount in physiological ecology, lower amounts in ecology and the lowest in evolutionary studies. In all fields though, the hypothesized relationship (e.g. main effect of a fixed treatment) explained little of the variation in the trait of interest. Our finding has important implications for the interpretation of scientific studies. Across studies, the average effect size reported is between Pearson r=0.180 and 0.193 and Hedges' d=0.631 and 0.721. Thus the average sample sizes needed to conclude that a particular relationship is absent with a power of 80% and α=0.05 (two-tailed) are considerably larger than usually recorded in studies of evolution and ecology. For example, to detect r=0.193, the required sample size is 207.

Synthesis and Characterization of Mesostructured Titania-Based Materials through Evaporation-Induced Self-Assembly

Abstract: Mesostructured TiO2−hexadecyltrimethylammonium bromide hybrid powders, displaying a bidimensional hexagonal pattern (p6m), have been synthesized by an evaporation-induced self-assembly (EISA) method, in ethanol/HCl/H2O media. Thermal treatment of these “titaniatropic” hybrid phases leads to phosphorus-free, high surface area (280−370 m2 g-1) mesoporous titania, with 20−25 A pores. The role of the synthesis parameters (surfactant and acid concentrations and temperature) is thoroughly discussed to understand their influence on the hybrid mesostructures. It is suggested that hydrophilic Ti-oxo nanometric building blocks formed in the acidic synthesis conditions self-assembly upon solvent evaporation to produce organized structures.

Sources of nitrate in rivers draining sixteen watersheds in the northeastern U.S.: Isotopic constraints

Abstract: The feasibility of using nitrogen and oxygen isotope ratios of nitrate (NO 3 − ) for elucidating sources and transformations of riverine nitrate was evaluated in a comparative study of 16 watersheds in the northeastern U.S.A. Stream water was sampled repeatedly at the outlets of the watersheds between January and December 1999 for determining concentrations, δ 15N values, and δ 180 values of riverine nitrate.

Individual Covariation in Life‐History Traits: Seeing the Trees Despite the Forest

Abstract: We investigated the influence of age on survival and breeding rates in a long‐lived species Rissa tridactyla using models with individual random effects permitting variation and covariation in fitness components among individuals. Differences in survival or breeding probabilities among individuals are substantial, and there was positive covariation between survival and breeding probability; birds that were more likely to survive were also more likely to breed, given that they survived. The pattern of age‐related variation in these rates detected at the individual level differed from that observed at the population level. Our results provided confirmation of what has been suggested by other investigators: within‐cohort phenotypic selection can mask senescence. Although this phenomenon has been extensively studied in humans and captive animals, conclusive evidence of the discrepancy between population‐level and individual‐level patterns of age‐related variation in life‐history traits is extremely ...

Hormones, developmental plasticity and adaptation

Abstract: Phenotypic plasticity is the extent to which an organism can change its physiology, behaviour, morphology and/or development in response to environmental cues. Environmentally induced differences in the endocrine system are among the underlying causes of phenotypic plasticity. For example, maternal and other environmental influences on developing young can affect the range of physiological and behavioural responses available to them as adults. The mechanisms underlying phenotypic plasticity can be elucidated using multidisciplinary approaches, in which the dynamic interactions among developmental, hormonal and environmental factors are considered. Such studies point to the importance of considering the overall developmental trajectory of an organism when assessing the adaptive value of phenotypic variation, rather than simply evaluating the individual at a single point in time.

Heterotachy, an Important Process of Protein Evolution

Abstract: Because of functional constraints, substitution rates vary among the positions of a protein but are usually assumed to be constant at a given site during evolution. The distribution of the rates across the sequence positions generally fits a Gamma distribution. Models of sequence evolution were accordingly designed and led to improved phylogenetic reconstruction. However, it has been convincingly demonstrated that the evolutionary rate of a given position is not always constant throughout time. We called such within-site rate variations heterotachy (for "different speed" in Greek). Yet, heterotachy was found among homologous sequences of distantly related organisms, often with different functions. In such cases, the functional constraints are likely different, which would explain the different distribution of variable sites. To evaluate the importance of heterotachy, we focused on amino acid sequences of mitochondrial cytochrome b, for which the function is likely the same in all vertebrates. Using 2,038 sequences, we demonstrate that 95% of the variable positions are heterotachous, i.e., underwent dramatic variations of substitution rate among vertebrate lineages. Heterotachy even occurs at small evolutionary scale, and in these cases it is very unlikely to be related to functional changes. Since a large number of sequences are required to efficiently detect heterotachy, the extent of this phenomenon could not be estimated for all proteins yet. It could be as large as for cytochrome b, since this protein is not a peculiar case. The observations made here open several new avenues of research, such as the understanding of the evolution of functional constraints or the improvement of phylogenetic reconstruction methods.

Use of infrared thermal imaging to isolate Arabidopsis mutants defective in stomatal regulation

Abstract: In response to drought, plants synthesise the hormone abscisic acid (ABA), which triggers closure of the stomatal pores. This process is vital for plants to conserve water by reducing transpirational water loss. Moreover, recent studies have demonstrated the advantages of the Arabidopsis stomatal guard cell for combining genetic, molecular and biophysical approaches to characterise ABA action. However, genetic dissection of stomatal regulation has been limited by the difficulty of identifying a reliable phenotype for mutant screening. Leaf temperature can be used as an indicator to detect mutants with altered stomatal control, since transpiration causes leaf cooling. In this study, we optimised experimental conditions under which individual Arabidopsis plants with altered stomatal responses to drought can be identified by infrared thermography. These conditions were then used to perform a pilot screen for mutants that displayed a reduced ability to close their stomata and hence appeared colder than the wild type. Some of the mutants recovered were deficient in ABA accumulation, and corresponded to alleles of the ABA biosynthesis loci ABA1, ABA2 and ABA3. Interestingly, two of these novel aba2 alleles were able to intragenically complement the aba2-1 mutation. The remaining mutants showed reduced ABA responsiveness in guard cells. In addition to the previously known abi1-1 mutation, we isolated mutations at two novel loci designated as OST1 (OPEN STOMATA 1) and OST2. Remarkably, ost1 and ost2 represent, to our knowledge, the first Arabidopsis mutations altering ABA responsiveness in stomata and not in seeds.

Oceanic Biogeochemical Controls on Global Dynamics of Persistent Organic Pollutants

Abstract: Understanding and quantifying the global dynamics and sinks of persistent organic pollutants (POPs) is important to assess their environmental impact and fate. Air-surface exchange processes, where temperature plays a central role in controlling volatilization and deposition, are of key importance in controlling global POP dynamics. The present study is an assessment of the role of oceanic biogeochemical processes, notably phytoplankton uptake and vertical fluxes of particles, on the global dynamics of POPs. Field measurements of atmospheric polychlorinated biphenyls (PCBs), polychlorinated dibenzodioxins (PCDDs), and furans (PCDFs) are combined with remote sensing estimations of oceanic temperature, wind speed, and chlorophyll, to model the interactions between air-water exchange, phytoplankton uptake, and export of organic matter and POPs out of the mixed surface ocean layer. Deposition is enhanced in the mid-high latitudes and is driven by sinking marine particulate matter, rather than by a cold condensation effect. However, the relative contribution of the biological pump is a function of the physical-chemical properties of POPs. It is concluded that oceanic biogeochemical processes play a critical role in controlling the global dynamics and the ultimate sink of POPs.

Carotenoids and egg quality in the lesser black-backed gull Larus fuscus: a supplemental feeding study of maternal effects

Abstract: Egg quality is a phenotype of, and can profoundly influence fitness in, both mother and offspring. However, the physiological mechanisms that underlie this maternal effect are poorly understood. Carotenoids are hypothesized to enhance antioxidant activity and immune function, and are responsible for the pigmentation of egg yolk. The proximate basis and consequences of this maternal investment, however, have not previously been studied in wild birds. In this supplemental feeding study of lesser black-backed gulls, Larus fuscus, carotenoid-fed females are shown to have increased integument pigmentation, higher plasma concentrations of carotenoids and antioxidant activity, and lower plasma concentrations of immunoglobulins (Igs) in comparison with controls. In turn, carotenoid-fed females produced eggs containing high carotenoid but low Ig concentrations (i.e. passive immunity), whereas control females produced eggs containing low carotenoid but high Ig concentrations. Within-clutch patterns of these resources varied over the laying sequence in a similar manner in both carotenoid-fed and control nests. Our results suggest that carotenoids could be one resource responsible for egg quality maternal effects in birds. We discuss the possible implications of carotenoid-mediated effects on phenotype for fitness in mothers and their offspring.