Showing papers by "Polytechnic University of Milan published in 2013"

Definition of the halogen bond (IUPAC Recommendations 2013)

Abstract: This recommendation proposes a definition for the term ``halogen bond'', which designates a specific subset of the inter- and intramolecular interactions involving a halogen atom in a molecular entity.

Ion acceleration by superintense laser-plasma interaction

Abstract: Ion acceleration driven by superintense laser pulses is attracting an impressive and steadily increasing effort. Motivations can be found in the applicative potential and in the perspective to investigate novel regimes as available laser intensities will be increasing. Experiments have demonstrated, over a wide range of laser and target parameters, the generation of multi-MeV proton and ion beams with unique properties such as ultrashort duration, high brilliance, and low emittance. An overview is given of the state of the art of ion acceleration by laser pulses as well as an outlook on its future development and perspectives. The main features observed in the experiments, the observed scaling with laser and plasma parameters, and the main models used both to interpret experimental data and to suggest new research directions are described.

Position paper: Characterising performance of environmental models

Abstract: In order to use environmental models effectively for management and decision-making, it is vital to establish an appropriate level of confidence in their performance. This paper reviews techniques available across various fields for characterising the performance of environmental models with focus on numerical, graphical and qualitative methods. General classes of direct value comparison, coupling real and modelled values, preserving data patterns, indirect metrics based on parameter values, and data transformations are discussed. In practice environmental modelling requires the use and implementation of workflows that combine several methods, tailored to the model purpose and dependent upon the data and information available. A five-step procedure for performance evaluation of models is suggested, with the key elements including: (i) (re)assessment of the model's aim, scale and scope; (ii) characterisation of the data for calibration and testing; (iii) visual and other analysis to detect under- or non-modelled behaviour and to gain an overview of overall performance; (iv) selection of basic performance criteria; and (v) consideration of more advanced methods to handle problems such as systematic divergence between modelled and observed values.

Organic light detectors: photodiodes and phototransistors.

Abstract: While organic electronics is mostly dominated by light-emitting diodes, photovoltaic cells and transistors, optoelectronics properties peculiar to organic semiconductors make them interesting candidates for the development of innovative and disruptive applications also in the field of light signal detection. In fact, organic-based photoactive media combine effective light absorption in the region of the spectrum from ultraviolet to near-infrared with good photogeneration yield and low-temperature processability over large areas and on virtually every substrate, which might enable innovative optoelectronic systems to be targeted for instance in the field of imaging, optical communications or biomedical sensing. In this review, after a brief resume of photogeneration basics and of devices operation mechanisms, we offer a broad overview of recent progress in the field, focusing on photodiodes and phototransistors. As to the former device category, very interesting values for figures of merit such as photoconversion efficiency, speed and minimum detectable signal level have been attained, and even though the simultaneous optimization of all these relevant parameters is demonstrated in a limited number of papers, real applications are within reach for this technology, as it is testified by the increasing number of realizations going beyond the single-device level and tackling more complex optoelectronic systems. As to phototransistors, a more recent subject of study in the framework of organic electronics, despite a broad distribution in the reported performances, best photoresponsivities outperform amorphous silicon-based devices. This suggests that organic phototransistors have a large potential to be used in a variety of optoelectronic peculiar applications, such as a photo-sensor, opto-isolator, image sensor, optically controlled phase shifter, and opto-electronic switch and memory.

Software Engineering for Self-Adaptive Systems : A Second Research Roadmap

Abstract: The goal of this roadmap paper is to summarize the state-of-the-art and identify research challenges when developing, deploying and managing self-adaptive software systems. Instead of dealing with a wide range of topics associated with the field, we focus on four essential topics of self-adaptation: design space for self-adaptive solutions, software engineering processes for self-adaptive systems, from centralized to decentralized control, and practical run-time verification & validation for self-adaptive systems. For each topic, we present an overview, suggest future directions, and focus on selected challenges. This paper complements and extends a previous roadmap on software engineering for self-adaptive systems published in 2009 covering a different set of topics, and reflecting in part on the previous paper. This roadmap is one of the many results of the Dagstuhl Seminar 10431 on Software Engineering for Self-Adaptive Systems, which took place in October 2010.

What is — and what is not — an optical isolator

Abstract: The quest for on-chip optical isolators has recently spawned many new isolator structures. However, there has been some confusion about the requirement of nonreciprocity. Here, we review the essential characteristics of an isolator.

The halogen bond in the design of functional supramolecular materials: recent advances.

Abstract: Halogen bonding is an emerging noncovalent interaction for constructing supramolecular assemblies. Though similar to the more familiar hydrogen bonding, four primary differences between these two interactions make halogen bonding a unique tool for molecular recognition and the design of functional materials. First, halogen bonds tend to be much more directional than (single) hydrogen bonds. Second, the interaction strength scales with the polarizability of the bond-donor atom, a feature that researchers can tune through single-atom mutation. In addition, halogen bonds are hydrophobic whereas hydrogen bonds are hydrophilic. Lastly, the size of the bond-donor atom (halogen) is significantly larger than hydrogen. As a result, halogen bonding provides supramolecular chemists with design tools that cannot be easily met with other types of noncovalent interactions and opens up unprecedented possibilities in the design of smart functional materials.This Account highlights the recent advances in the design of hal...

Integrated multimode interferometers with arbitrary designs for photonic boson sampling

Abstract: The boson-sampling problem was demonstrated by studying three-photon interference in a five-mode integrated interferometer containing three-dimensional S-bent waveguides. Three single photons were input into the interferometer and the probability ratios of all events were measured. The results agree with quantum mechanical predictions for three-photon interference.

Hot exciton dissociation in polymer solar cells

Abstract: The standard picture of photovoltaic conversion in all-organic bulk heterojunction solar cells predicts that the initial excitation dissociates at the donor/acceptor interface after thermalization. Accordingly, on above-gap excitation, the excess photon energy is quickly lost by internal dissipation. Here we directly target the interfacial physics of an efficient low-bandgap polymer/PC(60)BM system. Exciton splitting occurs within the first 50 fs, creating both interfacial charge transfer states (CTSs) and polaron species. On high-energy excitation, higher-lying singlet states convert into hot interfacial CTSs that effectively contribute to free-polaron generation. We rationalize these findings in terms of a higher degree of delocalization of the hot CTSs with respect to the relaxed ones, which enhances the probability of charge dissociation in the first 200 fs. Thus, the hot CTS dissociation produces an overall increase in the charge generation yield.

Global land and water grabbing

Abstract: Societal pressure on the global land and freshwater resources is increasing as a result of the rising food demand by the growing human population, dietary changes, and the enhancement of biofuel production induced by the rising oil prices and recent changes in United States and European Union bioethanol policies. Many countries and corporations have started to acquire relatively inexpensive and productive agricultural land located in foreign countries, as evidenced by the dramatic increase in the number of transnational land deals between 2005 and 2009. Often known as “land grabbing,” this phenomenon is associated with an appropriation of freshwater resources that has never been assessed before. Here we gather land-grabbing data from multiple sources and use a hydrological model to determine the associated rates of freshwater grabbing. We find that land and water grabbing are occurring at alarming rates in all continents except Antarctica. The per capita volume of grabbed water often exceeds the water requirements for a balanced diet and would be sufficient to improve food security and abate malnourishment in the grabbed countries. It is found that about 0.31 × 1012 m3⋅y−1 of green water (i.e., rainwater) and up to 0.14 × 1012 m3⋅y−1 of blue water (i.e., irrigation water) are appropriated globally for crop and livestock production in 47 × 106 ha of grabbed land worldwide (i.e., in 90% of the reported global grabbed land).

Research on Technological Innovation in Family Firms: Present Debates and Future Directions

Abstract: The purpose of this article is to review and systematize prior work on technological innovation in family firms and to open up an agenda to guide future research into this promising area. The study shows that family involvement has direct effects on innovation inputs (e.g., R&D expenditures), activities (e.g., leadership in new product development projects), and outputs (e.g., number of new products), as well as moderating effects on the relationships between these steps of technological innovation. The article uses theories applied in family business research (e.g., agency theory) to discuss opportunities for extending technological innovation frameworks by considering family involvement.

Ultrafast collinear scattering and carrier multiplication in graphene

Abstract: Graphene is emerging as a viable alternative to conventional optoelectronic, plasmonic and nanophotonic materials. The interaction of light with charge carriers creates an out-of-equilibrium distribution, which relaxes on an ultrafast timescale to a hot Fermi-Dirac distribution, that subsequently cools emitting phonons. Although the slower relaxation mechanisms have been extensively investigated, the initial stages still pose a challenge. Experimentally, they defy the resolution of most pump-probe setups, due to the extremely fast sub-100 fs carrier dynamics. Theoretically, massless Dirac fermions represent a novel many-body problem, fundamentally different from Schrodinger fermions. Here we combine pump-probe spectroscopy with a microscopic theory to investigate electron-electron interactions during the early stages of relaxation. We identify the mechanisms controlling the ultrafast dynamics, in particular the role of collinear scattering. This gives rise to Auger processes, including charge multiplication, which is key in photovoltage generation and photodetectors.

Anderson localization of entangled photons in an integrated quantum walk

Abstract: Researchers observe Anderson localization for pairs of polarization-entangled photons in a discrete quantum walk affected by position-dependent disorder. By exploiting polarization entanglement of photons to simulate different quantum statistics, they experimentally investigate the interplay between the Anderson localization mechanism and the bosonic/fermionic symmetry of the wave function.

Stereoelectroencephalography: surgical methodology, safety, and stereotactic application accuracy in 500 procedures.

Abstract: BACKGROUND Stereoelectroencephalography (SEEG) methodology, originally developed by Talairach and Bancaud, is progressively gaining popularity for the presurgical invasive evaluation of drug-resistant epilepsies. OBJECTIVE To describe recent SEEG methodological implementations carried out in our center, to evaluate safety, and to analyze in vivo application accuracy in a consecutive series of 500 procedures with a total of 6496 implanted electrodes. METHODS Four hundred nineteen procedures were performed with the traditional 2-step surgical workflow, which was modified for the subsequent 81 procedures. The new workflow entailed acquisition of brain 3-dimensional angiography and magnetic resonance imaging in frameless and markerless conditions, advanced multimodal planning, and robot-assisted implantation. Quantitative analysis for in vivo entry point and target point localization error was performed on a sub--data set of 118 procedures (1567 electrodes). RESULTS The methodology allowed successful implantation in all cases. Major complication rate was 12 of 500 (2.4%), including 1 death for indirect morbidity. Median entry point localization error was 1.43 mm (interquartile range, 0.91-2.21 mm) with the traditional workflow and 0.78 mm (interquartile range, 0.49-1.08 mm) with the new one (P < 2.2 × 10). Median target point localization errors were 2.69 mm (interquartile range, 1.89-3.67 mm) and 1.77 mm (interquartile range, 1.25-2.51 mm; P < 2.2 × 10), respectively. CONCLUSION SEEG is a safe and accurate procedure for the invasive assessment of the epileptogenic zone. Traditional Talairach methodology, implemented by multimodal planning and robot-assisted surgery, allows direct electrical recording from superficial and deep-seated brain structures, providing essential information in the most complex cases of drug-resistant epilepsy.

Analysis of enhanced light emission from highly strained germanium microbridges

Abstract: Highly strained germanium on silicon samples with up to 3.1% uniaxial strain are fabricated and then investigated by Raman spectroscopy. During optical pumping, changes in both the emission wavelength and output power are observed, indicating that bandgap modification and optical gain are occurring.

A survey on service quality description

Abstract: Quality of service (QoS) can be a critical element for achieving the business goals of a service provider, for the acceptance of a service by the user, or for guaranteeing service characteristics in a composition of services, where a service is defined as either a software or a software-support (i.e., infrastructural) service which is available on any type of network or electronic channel. The goal of this article is to compare the approaches to QoS description in the literature, where several models and metamodels are included. consider a large spectrum of models and metamodels to describe service quality, ranging from ontological approaches to define quality measures, metrics, and dimensions, to metamodels enabling the specification of quality-based service requirements and capabilities as well as of SLAs (Service-Level Agreements) and SLA templates for service provisioning. Our survey is performed by inspecting the characteristics of the available approaches to reveal which are the consolidated ones and which are the ones specific to given aspects and to analyze where the need for further research and investigation lies. The approaches here illustrated have been selected based on a systematic review of conference proceedings and journals spanning various research areas in computer science and engineering, including: distributed, information, and telecommunication systems, networks and security, and service-oriented and grid computing.

Molecular mechanics of mineralized collagen fibrils in bone.

Abstract: Bone is a natural composite of collagen protein and the mineral hydroxyapatite. The structure of bone is known to be important to its load-bearing characteristics, but relatively little is known about this structure or the mechanism that govern deformation at the molecular scale. Here we perform full-atomistic calculations of the three-dimensional molecular structure of a mineralized collagen protein matrix to try to better understand its mechanical characteristics under tensile loading at various mineral densities. We find that as the mineral density increases, the tensile modulus of the network increases monotonically and well beyond that of pure collagen fibrils. Our results suggest that the mineral crystals within this network bears up to four times the stress of the collagen fibrils, whereas the collagen is predominantly responsible for the material’s deformation response. These findings reveal the mechanism by which bone is able to achieve superior energy dissipation and fracture resistance characteristics beyond its individual constituents.

Real-time observation of ultrafast Rabi oscillations between excitons and plasmons in metal nanostructures with J-aggregates

Abstract: Researchers observe Rabi oscillations in a metal structure with a J-aggregate nonlinear medium and coherent energy transfer between excitonic quantum emitters and surface plasmons. The coupling energy is controlled on the 10 fs timescale by varying the exciton density. This work demonstrates the potential of nonlinear ultrafast plasmonics.

Halogen-bonding-triggered supramolecular gel formation

Abstract: Supramolecular gels are topical soft materials involving the reversible formation of fibrous aggregates using non-covalent interactions. There is significant interest in controlling the properties of such materials by the formation of multicomponent systems, which exhibit non-additive properties emerging from interaction of the components. The use of hydrogen bonding to assemble supramolecular gels in organic solvents is well established. In contrast, the use of halogen bonding to trigger supramolecular gel formation in a two-component gel ('co-gel') is essentially unexplored, and forms the basis for this study. Here, we show that halogen bonding between a pyridyl substituent in a bis(pyridyl urea) and 1,4-diiodotetrafluorobenzene brings about gelation, even in polar media such as aqueous methanol and aqueous dimethylsulfoxide. This demonstrates that halogen bonding is sufficiently strong to interfere with competing gel-inhibitory interactions and create a 'tipping point' in gel assembly. Using this concept, we have prepared a halogen bond donor bis(urea) gelator that forms co-gels with halogen bond acceptors.

An Introduction to Information Retrieval

Abstract: Information retrieval is a discipline that deals with the representation, storage, organization, and access to information items. The goal of information retrieval is to obtain information that might be useful or relevant to the user: library card cabinets are a “traditional” information retrieval system, and, in some sense, even searching for a visiting card in your pocket to find out a colleague’s contact details might be considered as an information retrieval task. In this chapter we introduce information retrieval as a scientific discipline, providing a formal characterization centered on the notion of relevance. We touch on some of its challenges and classic applications and then dedicate a section to its main evaluation criteria: precision and recall.

On Patterns for Decentralized Control in Self-Adaptive Systems

Abstract: Self-adaptation is typically realized using a control loop. One prominent approach for organizing a control loop in self-adaptive systems is by means of four components that are responsible for the primary functions of self-adaptation: Monitor, Analyze, Plan, and Execute, together forming a MAPE loop. When systems are large, complex, and heterogeneous, a single MAPE loop may not be sufficient for managing all adaptation in a system, so multiple MAPE loops may be introduced. In self-adaptive systems with multiple MAPE loops, decisions about how to decentralize each of the MAPE functions must be made. These decisions involve how and whether the corresponding functions from multiple loops are to be coordinated (e.g., planning components coordinating to prepare a plan for an adaptation). To foster comprehension of self-adaptive systems with multiple MAPE loops and support reuse of known solutions, it is crucial that we document common design approaches for engineers. As such systematic knowledge is currently lacking, it is timely to reflect on these systems to: (a) consolidate the knowledge in this area, and (b) to develop a systematic approach for describing different types of control in self-adaptive systems. We contribute with a simple notation for describing interacting MAPE loops, which we believe helps in achieving (b), and we use this notation to describe a number of existing patterns of interacting MAPE loops, to begin to fulfill (a). From our study, we outline numerous remaining research challenges in this area.

Electric Control of the Giant Rashba Effect in Bulk GeTe

Abstract: Relativistic effects, including the Rashba effect, are increasingly seen as key ingredients in spintronics. A link between Rashba physics and the field of ferroelectrics is established by predicting giant Rashba spin-splitting in bulk GeTe (see the Figure showing the band-structure as well as in-plane and out- of-plane spin polarization for a constant energy cut).

A novel approach for barriers to industrial energy efficiency

Abstract: A critical review of the literature highlighted the need for a new taxonomy encompassing the most relevant barriers stemmed from previous studies, and accounting for interactions and independences of the barriers to avoid overlaps and implicit interactions. Based on an extensive literature review the paper provides a novel approach for barriers to the adoption of industrial energy-efficient technologies, coping with the issues risen by the review of the literature. We developed a taxonomy adaptable to empirical research, and able to evaluate the differences between perceived and real barriers, the effect of the barriers on decision-making processes, and the interactions among barriers. We modeled three types of interactions, i.e., causal relationship, composite effect and hidden effect, in order to start analyzing the dynamics among barriers, and tested the taxonomy in a preliminary investigation. The study proposes a useful instrument both to enterprises and policy-makers to identify critical factors to improve industrial energy efficiency and to open the research to further investigation in this topic.

Laser-Induced Magnetic Nanostructures with Tunable Topological Properties

Abstract: We report the creation and real-space observation of magnetic structures with well-defined topological properties and a lateral size as low as about 150 nm. They are generated in a thin ferrimagnetic film by ultrashort single optical laser pulses. Thanks to their topological properties, such structures can be classified as Skyrmions of a particular type that does not require an externally applied magnetic field for stabilization. Besides Skyrmions, we are able to generate magnetic features with topological characteristics that can be tuned by changing the laser fluence. The stability of such features is accounted for by an analytical model based on the interplay between the exchange and the magnetic dipole-dipole interactions. Skyrmions [1] are particlelike solutions of wave equations characterized by a topological index which is conserved in time and plays the important role of a quantum number for particle states in the corresponding field theory. One of the most interesting characteristics of such topological states of matter resides in the robustness that they hold with respect to perturbations and disorder. In magnetic materials, Skyrmions emerge as solitonlike excitations that cannot be traced back to the ground ferromagnetic state by continuous deformations of the local

A polymer optoelectronic interface restores light sensitivity in blind rat retinas

Abstract: Interfacing organic electronics with biological substrates offers new possibilities for biotechnology by taking advantage of the beneficial properties exhibited by organic conducting polymers. These polymers have been used for cellular interfaces in several applications, including cellular scaffolds, neural probes, biosensors and actuators for drug release. Recently, an organic photovoltaic blend has been used for neuronal stimulation via a photo-excitation process. Here, we document the use of a single-component organic film of poly(3-hexylthiophene) (P3HT) to trigger neuronal firing upon illumination. Moreover, we demonstrate that this bio–organic interface restores light sensitivity in explants of rat retinas with lightinduced photoreceptor degeneration. These findings suggest that all-organic devices may play an important future role in subretinal prosthetic implants.