Showing papers by "Polytechnic University of Valencia published in 2007"
TL;DR: Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481 4.2.1.
Abstract: 3.2.3. Hydroformylation 2467 3.2.4. Dimerization 2468 3.2.5. Oxidative Cleavage and Ozonolysis 2469 3.2.6. Metathesis 2470 4. Terpenes 2472 4.1. Pinene 2472 4.1.1. Isomerization: R-Pinene 2472 4.1.2. Epoxidation of R-Pinene 2475 4.1.3. Isomerization of R-Pinene Oxide 2477 4.1.4. Hydration of R-Pinene: R-Terpineol 2478 4.1.5. Dehydroisomerization 2479 4.2. Limonene 2480 4.2.1. Isomerization 2480 4.2.2. Epoxidation: Limonene Oxide 2480 4.2.3. Isomerization of Limonene Oxide 2481 4.2.4. Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481
5,127 citations
TL;DR: Microwave photonics has attracted great interest from both the research community and the commercial sector over the past 30 years and is set to have a bright future as mentioned in this paper, which makes it possible to have functions in microwave systems that are complex or even not directly possible in the radiofrequency domain and also creates new opportunities for telecommunication networks.
Abstract: Microwave photonics, which brings together the worlds of radiofrequency engineering and optoelectronics, has attracted great interest from both the research community and the commercial sector over the past 30 years and is set to have a bright future. The technology makes it possible to have functions in microwave systems that are complex or even not directly possible in the radiofrequency domain and also creates new opportunities for telecommunication networks. Here we introduce the technology to the photonics community and summarize recent research and important applications.
2,354 citations
TL;DR: This work presents a new iterated greedy algorithm that applies two phases iteratively, named destruction, were some jobs are eliminated from the incumbent solution, and construction, where the eliminated jobs are reinserted into the sequence using the well known NEH construction heuristic.
923 citations
TL;DR: A number of alternatives for preservation of fresh-cut vegetables have been proposed, such as antioxidants, irradiation, ozone, organics acids, modified atmosphere packaging, whey permeate, etc as discussed by the authors.
Abstract: The market sales of ready-to-use fresh vegetables have grown rapidly in recent decades as a result of changes in consumer attitudes, especially consumption of fresh-cut lettuce and carrot due to their use in prepared salads. Chlorine solutions have been widely used to sanitise fruit and vegetables in the fresh-cut industry. However, the association of chlorine with the possible formation of carcinogenic chlorinated compounds in water has called into question the use of chlorine in food processing. There is a real need to find alternatives for preservation of fresh-cut fruit and vegetables in order to improve the efficacy of washing treatments. Alternatives or modified methods have been proposed, as antioxidants, irradiation, ozone, organics acids, modified atmosphere packaging, whey permeate, etc.; however, none have yet gained widespread acceptance by the industry. For this reason the development of alternatives and markers in order to measure the efficacy of these alternatives are needed.
894 citations
TL;DR: The results confirmed the efficacy of VR as affective medium and showed a circular interaction between presence and emotions: the interaction with "anxious" and "relaxing" virtual environments produced anxiety and relaxation.
Abstract: Many studies showed the ability of movies and imagery techniques to elicit emotions. Nevertheless, it is less clear how to manipulate the content of interactive media to induce specific emotional responses. In particular, this is true for the emerging medium virtual reality (VR), whose main feature is the ability to induce a feeling of "presence" in the computer-generated world experienced by the user. The main goal of this study was to analyze the possible use of VR as an affective medium. Within this general goal, the study also analyzed the relationship between presence and emotions. The results confirmed the efficacy of VR as affective medium: the interaction with "anxious" and "relaxing" virtual environments produced anxiety and relaxation. The data also showed a circular interaction between presence and emotions: on one side, the feeling of presence was greater in the "emotional" environments; on the other side, the emotional state was influenced by the level of presence. The significance of these r...
771 citations
TL;DR: Upon light excitation MOF-5 behaves as a semiconductor and undergoes charge separation (electrons and holes) decaying in the microsecond time scale, and photoinduced electron transfer processes to viologen generates the corresponding viologens radical cation.
Abstract: Upon light excitation MOF-5 behaves as a semiconductor and undergoes charge separation (electrons and holes) decaying in the microsecond time scale. The actual conduction band energy value was estimated to be 0.2 V versus NHE with a band gap of 3.4 eV. Photoinduced electron transfer processes to viologen generates the corresponding viologen radical cation, while holes of MOF-5 oxidizes N,N,N',N'-tetramethyl-p-phenylenediamine. One application investigated for MOF-5 as a semiconductor has been the shape-selective photocatalyzed degradation of phenol in aqueous solutions.
757 citations
TL;DR: The result provides a set of progressively less conservative sufficient conditions for proving positivity of fuzzy summations of Polya's theorems on positive forms on the standard simplex.
582 citations
TL;DR: In this article, the catalytic cracking of glycerol and sorbitol, as representative of biomass-derived oxygenates, was studied at 500-700°C with six different catalysts, including a fresh fluid catalytic cracker, an equilibrium FCC catalyst with metal impurities (ECat), a mesoporous Al2O3, a USY zeolite (Y), a ZSM5-based FCC additive (ZSM5), and an inert silicon carbide (SiC).
517 citations
TL;DR: A palladium-containing metal-organic framework (Pd-MOF) was found to be an active catalyst for alcohol oxidation, Suzuki C C coupling, and olefin hydrogenation.
500 citations
TL;DR: Recent developments to attain molecular systems with increased logic capabilities is described, including bioinspired systems based on DNA and enzymes, as well as chemical molecular logic gates.
Abstract: Molecular and supramolecular logic gates are candidates for computation at the nanoscale level. Nowadays all common logic operations can be mimicked with molecular devices based on chemical approaches. One step further towards molecular systems with increased logic capabilities is the addition or subtraction of binary digits. This Minireview describes recent developments to attain this goal, including bioinspired systems based on DNA and enzymes. Furthermore, chemical molecular logic gates are discussed and compared critically with regard to alternative concepts.
435 citations
TL;DR: The high chemoselectiviy of the Au/TiO2 catalyst can be attributed to a cooperation between the gold nanoparticle and the support that preferentially activates the nitro group.
Abstract: Nanoparticles of gold on TiO2 are highly chemoselective for the reduction of substituted nitroaromatics, such as nitrostyrene. By combining kinetics and in situ IR spectroscopy, it has been found that there is a preferential adsorption of the reactant on the catalyst through the nitro group. IR studies of nitrobenzene, styrene, and nitrostyrene adsorption, together with quantum chemical calculations, show that the nitro and the olefinic groups adsorb weakly on the Au(111) and Au(001) surfaces, and that although a stronger adsorption occurs on low-coordinated atoms in gold nanoparticles, this adsorption is not selective. On the other hand, an energetically and geometrically favored adsorption through the nitro group occurs on the TiO2 support and in the interface between the gold nanoparticle and the TiO2 support. Such preferential adsorption is not observed with nanoparticles of gold on silica which, contrary to the Au/TiO2 catalyst, is not chemoselective for the reduction of substituted nitroaromatic com...
TL;DR: This paper presents a numerical analysis for flow and heat transfer in a viscous fluid over a nonlinear stretching sheet by employing a novel numerical procedure that converts governing partial differential equations into highly nonlinear ordinary differential equations by a similarity transformation.
TL;DR: An experimental demonstration of an integrated biochemical sensor based on a slot-waveguide microring resonator that detects a minimal refractive index variation of 2x10(-4) RIU.
Abstract: We report an experimental demonstration of an integrated biochemical sensor based on a slot-waveguide microring resonator. The microresonator is fabricated on a Si3N4-SiO2 platform and operates at a wavelength of 1.3 μm. The transmission spectrum of the sensor is measured with different ambient refractive indices ranging from n=1.33 to 1.42. A linear shift of the resonant wavelength with increasing ambient refractive index of 212 nm/refractive index units (RIU) is observed. The sensor detects a minimal refractive index variation of 2×10−4 RIU.
TL;DR: The third or fifth order of convergence of these variants of Newton's method for dimension one, and the second or third order in several variables, depending on the behaviour of the second derivative are proved.
TL;DR: The structure of MOF-5 is considered as being constructed of discrete semiconductor Zn4O13 quantum dots stabilized and interconnected by terephthalate linkers.
Abstract: The structure of MOF-5 is considered as being constructed of discrete semiconductor Zn4O13 quantum dots stabilized and interconnected by terephthalate linkers. Terephthalate can absorb light and se...
TL;DR: Several ECG applications are reviewed where PCA techniques have been successfully employed, including data compression, ST-T segment analysis for the detection of myocardial ischemia and abnormalities in ventricular repolarization, extraction of atrial fibrillatory waves for detailed characterization of atrium fibrillation, and analysis of body surface potential maps.
Abstract: This paper reviews the current status of principal component analysis in the area of ECG signal processing. The fundamentals of PCA are briefly described and the relationship between PCA and Karhunen-Loeve transform is explained. Aspects on PCA related to data with temporal and spatial correlations are considered as adaptive estimation of principal components is. Several ECG applications are reviewed where PCA techniques have been successfully employed, including data compression, ST-T segment analysis for the detection of myocardial ischemia and abnormalities in ventricular repolarization, extraction of atrial fibrillatory waves for detailed characterization of atrial fibrillation, and analysis of body surface potential maps.
TL;DR: In this article, the authors proposed a dehydroisomerization of R-Pinene and terpenes to produce Cymene, which was shown to be more efficient than the traditional dehydration.
Abstract: 3.2.3. Hydroformylation 2467 3.2.4. Dimerization 2468 3.2.5. Oxidative Cleavage and Ozonolysis 2469 3.2.6. Metathesis 2470 4. Terpenes 2472 4.1. Pinene 2472 4.1.1. Isomerization: R-Pinene 2472 4.1.2. Epoxidation of R-Pinene 2475 4.1.3. Isomerization of R-Pinene Oxide 2477 4.1.4. Hydration of R-Pinene: R-Terpineol 2478 4.1.5. Dehydroisomerization 2479 4.2. Limonene 2480 4.2.1. Isomerization 2480 4.2.2. Epoxidation: Limonene Oxide 2480 4.2.3. Isomerization of Limonene Oxide 2481 4.2.4. Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481
TL;DR: The use of the interoperability frameworks and of the enterprise architectures within the e-government initiatives is surveyed and all trends in interoperability policy fall within the scope of the survey.
TL;DR: In this article, the elastic properties of cylinders are taken into account and a gradient index lens for airborne sound is proposed, whose functionality is demonstrated by multiple scattering simulations, and it is shown that metamaterials with perfect matching of impedance with air are possible by using aerogel and rigid cylinders equally distributed in a square lattice.
Abstract: It has been shown that two-dimensional arrays of rigid or fluidlike cylinders in a fluid or a gas define, in the limit of large wavelengths, a class of acoustic metamaterials whose effective parameters (sound velocity and density) can be tailored up to a certain limit. This work goes a step further by considering arrays of solid cylinders in which the elastic properties of cylinders are taken into account. We have also treated mixtures of two different elastic cylinders. It is shown that both effects broaden the range of acoustic parameters available for designing metamaterials. For example, it is predicted that metamaterials with perfect matching of impedance with air are now possible by using aerogel and rigid cylinders equally distributed in a square lattice. As a potential application of the proposed metamaterial, we present a gradient index lens for airborne sound (i.e. a sonic Wood lens) whose functionality is demonstrated by multiple scattering simulations.
TL;DR: In this article, the influence of ultrasound and conventional heating under different processing conditions on the inactivation and potential subsequent growth of micro-organisms in orange juice was investigated, and no ultrasound-related detrimental effects on the quality attributes of juice (limonin content, brown pigments and colour) were found.
TL;DR: It is concluded that pollination mediates fruit set by activating GA biosynthesis mainly through up-regulation of GA20ox, the hypothesis that GA1 is the active GA for tomato fruit growth.
Abstract: The role of gibberellins (GAs) in tomato (Solanum lycopersicum) fruit development was investigated. Two different inhibitors of GA biosynthesis (LAB 198999 and paclobutrazol) decreased fruit growth and fruit set, an effect reversed by GA3 application. LAB 198999 reduced GA1 and GA8 content, but increased that of their precursors GA53, GA44, GA19, and GA20 in pollinated fruits. This supports the hypothesis that GA1 is the active GA for tomato fruit growth. Unpollinated ovaries developed parthenocarpically in response to GA3 > GA1 = GA4 > GA20, but not to GA19, suggesting that GA 20-oxidase activity was limiting in unpollinated ovaries. This was confirmed by analyzing the effect of pollination on transcript levels of SlCPS, SlGA20ox1, -2, and -3, and SlGA3ox1 and -2, encoding enzymes of GA biosynthesis. Pollination increased transcript content of SlGA20ox1, -2, and -3, and SlCPS, but not of SlGA3ox1 and -2. To investigate whether pollination also altered GA inactivation, full-length cDNA clones of genes encoding enzymes catalyzing GA 2-oxidases (SlGA2ox1, -2, -3, -4, and -5) were isolated and characterized. Transcript levels of these genes did not decrease early after pollination (5-d-old fruits), but transcript content reduction of all of them, mainly of SlGA2ox2, was found later (from 10 d after anthesis). We conclude that pollination mediates fruit set by activating GA biosynthesis mainly through up-regulation of GA20ox. Finally, the phylogenetic reconstruction of the GA2ox family clearly showed the existence of three gene subfamilies, and the phylogenetic position of SlGA2ox1, -2, -3, -4, and -5 was established.
TL;DR: An important reduction in spray volume could be followed by an equivalent reduction of plant protection products but further research work is needed to guarantee biological efficacy of a reduced dose.
TL;DR: The aim of this paper is to propose tools in order to implicitly consider different preventive maintenance policies on machines regarding flowshop problems by proposing a simple criterion to schedule preventive maintenance operations to the production sequence.
TL;DR: Interestingly, the depletion of SlDELLA in tomato was sufficient to overcome the growth arrest normally imposed on the ovary at anthesis, resulting in parthenocarpic fruits in the absence of pollination, indicating that fertilization-associated SlDEllA-independent signals are operational in ovary-fruit transitions.
Abstract: DELLA proteins are plant nuclear factors that restrain growth and proliferation in response to hormonal signals. The effects of the manipulation of the DELLA pathway in the making of a berry-like fruit were investigated. The expression of the Arabidopsis thaliana gain-of-function DELLA allele Atgai (del) in tomato (Solanum lycopersicum L.) produced partially sterile dwarf plants and compacted influorescences, as expected for a constitutively activated growth repressor. In contrast, antisense silencing of the single endogenous tomato DELLA gene homologue (SlDELLA) produced slender-like plants with elongated flower trusses. Interestingly, the depletion of SlDELLA in tomato was sufficient to overcome the growth arrest normally imposed on the ovary at anthesis, resulting in parthenocarpic fruits in the absence of pollination. Antisense SlDELLA-engineered fruits were smaller in size and elongated in shape compared with wild type. Cell number estimations showed that fruit set, resulting from reduced SlDELLA expression, arose from activated cell elongation at the longitudinal and lateral axes of the fruit pericarp, bypassing phase-II (post-pollination) cell divisions. Parthenocarpy caused by SlDELLA depletion is facultative, as hand pollination restored wild-type fruit phenotype. This indicates that fertilization-associated SlDELLA-independent signals are operational in ovary-fruit transitions. SlDELLA was also found to restrain growth in other reproductive structures, affecting style elongation, stylar hair primordial growth and stigma development.
TL;DR: No significant differences were found in moisture and NaCl content of samples treated under STAT conditions and AG conditions, while the influence of ultrasound on the mass transfer process during meat brining depended on the intensity applied, and at the highest level of intensity studied, the water content was significantly higher than the initial water content of meat.
TL;DR: In this article, economic and integrated economic-engineering-hydrologic modeling is discussed in the context of the evolving European Water Framework Directive (EWF Directive) for river basin management problems.
Abstract: Economic ideas and processes are becoming increasingly integrated with more traditional engineering and hydrologic models of water management problems. Combining economic management concepts and performance indicators with an engineering-level of understanding of a hydrologic system can provide results and insights more directly relevant for water management decisions and policies. When such models are developed and used with involvement of stakeholders, they can become a basis for shared understanding of water problems as a foundation for negotiated management and policy solutions. When implemented with optimization software, integrated hydro-economic models also can suggest promising innovative solutions for policy-makers to consider. Their applications to river basin management problems are reviewed. Economic and integrated economic-engineering-hydrologic modeling is then discussed in the context of the evolving European Water Framework Directive. Relevant items are cost recovery and water pricing, cost-effectiveness of water management measures, and public participation in decision processes.
TL;DR: Recently reported examples suggest that the application of chromo-fluorogenic supramolecular concepts for the chromogenic or fluorogenic sensing of nerve agents might be an area of increasing interest that would allow developing systems able to overcome some of the limitations shown by classical analytical methods.
TL;DR: The economic analysis indicates that inclusion of soybean meal in the diet reduces feeding costs and flesh quality was very little affected, albeit fish feeding on diets with partial replacement of fish meal tended to be somewhat softer.
TL;DR: Interestingly, it is shown that AGO4 works independently of other components of the RdDM pathway in mediating resistance to P.s.t. DC3000, and loss of function in other parts of the pathway operating upstream of AGO2 and DCL3, or operating downstream, such as DRD1, CMT3, DRM1, and DRM2, does not compromise resistance to this pathogen.
Abstract: Here, we report the characterization of the Arabidopsis thaliana ocp11 (for overexpressor of cationic peroxidase11) mutant, in which a β-glucuronidase reporter gene under the control of the H2O2-responsive Ep5C promoter is constitutively expressed. ocp11 plants show enhanced disease susceptibility to the virulent bacterium Pseudomonas syringae pv tomato DC3000 (P.s.t. DC3000) and also to the avirulent P.s.t. DC3000 carrying the effector avrRpm1 gene. In addition, ocp11 plants are also compromised in resistance to the nonhost pathogen P. syringae pv tabaci. Genetic and molecular analyses reveal that ocp11 plants are not affected in salicylic acid perception. We cloned OCP11 and show that it encodes ARGONAUTE4 (AGO4), a component of the pathway that mediates the transcriptional gene silencing associated with small interfering RNAs that direct DNA methylation at specific loci, a phenomenon known as RNA-directed DNA methylation (RdDM). Thus, we renamed our ocp11 mutant ago4-2, as it represents a different allele to the previously characterized recessive ago4-1. Both mutants decrease the extent of DNA cytosine methylation at CpNpG and CpHpH (asymmetric) positions present at different DNA loci and show commonalities in all of the molecular and phenotypic aspects that we have considered. Interestingly, we show that AGO4 works independently of other components of the RdDM pathway in mediating resistance to P.s.t. DC3000, and loss of function in other components of the pathway operating upstream of AGO4, such as RDR2 and DCL3, or operating downstream, such as DRD1, CMT3, DRM1, and DRM2, does not compromise resistance to this pathogen.