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Institution

Polytechnic University of Valencia

EducationValencia, Spain
About: Polytechnic University of Valencia is a education organization based out in Valencia, Spain. It is known for research contribution in the topics: Catalysis & Population. The organization has 16282 authors who have published 40162 publications receiving 850234 citations.


Papers
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Journal ArticleDOI
TL;DR: Six 2-quinolones, which bear a terminal alkene linked by a three- or four-membered tether to carbon atom C4 of the quinolone, were synthesized and subjected to an intramolecular [2 + 2]-photocycloaddition, finding the xanthone-based organocatalyst proved to be superior as compared to the respective benzophenone.
Abstract: Six 2-quinolones, which bear a terminal alkene linked by a three- or four-membered tether to carbon atom C4 of the quinolone, were synthesized and subjected to an intramolecular [2 + 2]-photocycloaddition. The reaction delivered the respective products in high yields (78–99%) and with good regioselectivity in favor of the straight isomer. If conducted in the presence of a chiral hydrogen-bonding template (2.5 equiv) at low temperature in toluene as the solvent, the reaction proceeded enantioselectively (83–94% ee). An organocatalytic reaction was achieved when employing a chiral hydrogen-bonding template with an attached sensitizing unit (benzophenone or xanthone). The xanthone-based organocatalyst proved to be superior as compared to the respective benzophenone. Closer inspection revealed that the reaction of 4-(pent-4-enyloxy)quinolone leading to a six-membered ring, annelated to the cyclobutane, was less enantioselective (up to 41% ee with 30 mol % catalyst) than the reaction of 4-(but-3-enyloxy)quinol...

173 citations

Journal ArticleDOI
15 Jan 2013-Wear
TL;DR: In this article, the degradation of CoCrMo alloys using existing tribocorrosion concepts was evaluated and it was shown that wear accelerated corrosion due to mechanical removal of the passive film during sliding is a major contribution to the overall degradation.

173 citations

Journal ArticleDOI
TL;DR: The minute amount of hydrogen sulfate groups introduced into the graphene oxide (GO) obtained by Hummers oxidation of graphite renders this material as a highly efficient, recyclable acid catalyst for the ring opening of epoxides with methanol and other primary alcohols as nucleophile and solvent.

173 citations

Journal ArticleDOI
TL;DR: In this article, the effect of cross-linkers (glutenin-rich fraction from commercial wheat gluten) on relevant properties of films based on a wheat gluten was studied.

173 citations

Journal ArticleDOI
TL;DR: The functional characterization of a berry-specific Ethylene Responsive Factor (ERF) is reported, VviERF045, which is induced just before véraison and peaks at ripening and affects phenolic secondary metabolism and induces a reaction resembling a plant immune response with modulation of receptor like-kinases and pathogen related genes.
Abstract: During grape ripening, numerous transcriptional and metabolic changes are required in order to obtain colored, sweet, and flavored berries. There is evidence that ethylene, together with other signals, plays an important role in triggering the onset of ripening. Here, we report the functional characterization of a berry-specific Ethylene Responsive Factor (ERF), VviERF045, which is induced just before veraison and peaks at ripening. Phylogenetic analysis revealed it is close to the SHINE clade of ERFs, factors involved in the regulation of wax biosynthesis and cuticle morphology. Transgenic grapevines lines overexpressing VviERF045 were obtained, in vitro propagated, phenotypically characterized, and analyzed for the content of specific classes of metabolites. The effect of VviERF045 was correlated with the level of transgene expression, with high-expressing lines showing stunted growth, discolored and smaller leaves, and a lower level of chlorophylls and carotenoids. One line with intermediate expression, L15, was characterized at the transcriptomic level and showed 573 differentially expressed genes compared to wild type plants. Microscopy and gene expression analyses point towards a major role of VviERF045 in epidermis patterning by acting on waxes and cuticle. They also indicate that VviERF045 affects phenolic secondary metabolism and induces a reaction resembling a plant immune response with modulation of receptor like-kinases and pathogen related genes. These results suggest also a possible role of this transcription factor in berry ripening, likely related to changes in epidermis and cuticle of the berry, cell expansion, a decrease in photosynthetic capacity, and the activation of several defense related genes as well as from the phenylpropanoid metabolism. All these processes occur in the berry during ripening.

173 citations


Authors

Showing all 16503 results

NameH-indexPapersCitations
Avelino Corma134104989095
Bruce D. Hammock111140957401
Geoffrey A. Ozin10881147504
Wolfgang J. Parak10246943307
Hermenegildo García9779246585
María Vallet-Regí9571141641
Albert Ferrando8741936793
Rajendra Prasad8694529526
J.J. Garcia-Luna-Aceves8660225151
George W. Huber8428037964
Juan J. Calvete8145822646
Juan M. Feliu8054423147
Amparo Chiralt7829818378
Michael Tsapatsis7737520051
Josep Redon7748881395
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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
20241
2023130
2022331
20212,655
20202,861
20192,762