Institution
Polytechnic University of Valencia
Education•Valencia, Spain•
About: Polytechnic University of Valencia is a education organization based out in Valencia, Spain. It is known for research contribution in the topics: Catalysis & Population. The organization has 16282 authors who have published 40162 publications receiving 850234 citations.
Papers published on a yearly basis
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TL;DR: An overview of VHO techniques, along with the main algorithms, protocols and tools proposed in the literature are presented, and the most appropriate V HO techniques to efficiently communicate in VN environments are suggested considering the particular characteristics of this type of networks.
229 citations
TL;DR: In this paper, the authors examined the various methods through which firms benefit from interactions with universities, arguing that such benefits are instrumental in nurturing the multiple facets of a firm's absorptive capacity.
229 citations
TL;DR: In this paper, it has been found that the activity of Cu changes with the organic linker in the MOF, being those containing CuN 4 more active than CuO 4 centers.
228 citations
TL;DR: It is proposed that the photo enhancement should be a general phenomenon in gold catalysis for those reaction mechanisms involving positive and/or negative gold species.
Abstract: Laser flash photolysis of supported gold nanopar-ticles exciting at the surface plasmon band (532 nm) has allowed in the case of Au/CeO2 and Au/OH-npD (OH-npD: Fenton-treated diamond nanoparticles) detection of transients decaying in the microsecond time scale that have been attributed as indicating photoinduced electron ejection from gold based on N2O quenching and the observation of the generation of methyl viologen radical cations. This photochemical behavior has led us to hypothesize that there could be assistance to the catalytic activity of these materials by irradiation in those cases wherein the mechanism involves electron transfer to or from a substrate to the gold. This hypothesis has been confirmed by observing that the catalytic activity of Au/OH-npD for the Fenton degradation of phenol with hydrogen peroxide can be increased over 1 order of magnitude by irradiation at 532 nm. Moreover, there is a linear relationship between the initial reaction rate and the incident photon flux. This photoenh...
228 citations
TL;DR: This paper will show how the different active sites in the framework can act in a synergistic or in a consecutive way following a similar functionality model to biological multisite catalysts.
Abstract: Organic–inorganic hybrid materials with different levels of structuration and porous hierarchy and one or several types of active sites in the framework can catalyze multistep chemical processes in a one-pot reactor system following a cascade of reaction events. It will show how the different active sites can act in a synergistic or in a consecutive way following a similar functionality model to biological multisite catalysts. Research on this subject for heterogeneous catalysts is still in the beginning stage and very interesting results can be expected if we are able to successfully combine the properties of organic and inorganic catalysts.
228 citations
Authors
Showing all 16503 results
| Name | H-index | Papers | Citations |
|---|---|---|---|
| Avelino Corma | 134 | 1049 | 89095 |
| Bruce D. Hammock | 111 | 1409 | 57401 |
| Geoffrey A. Ozin | 108 | 811 | 47504 |
| Wolfgang J. Parak | 102 | 469 | 43307 |
| Hermenegildo García | 97 | 792 | 46585 |
| María Vallet-Regí | 95 | 711 | 41641 |
| Albert Ferrando | 87 | 419 | 36793 |
| Rajendra Prasad | 86 | 945 | 29526 |
| J.J. Garcia-Luna-Aceves | 86 | 602 | 25151 |
| George W. Huber | 84 | 280 | 37964 |
| Juan J. Calvete | 81 | 458 | 22646 |
| Juan M. Feliu | 80 | 544 | 23147 |
| Amparo Chiralt | 78 | 298 | 18378 |
| Michael Tsapatsis | 77 | 375 | 20051 |
| Josep Redon | 77 | 488 | 81395 |