Rensselaer Polytechnic Institute

About: Rensselaer Polytechnic Institute is a education organization based out in Troy, New York, United States. It is known for research contribution in the topics: Terahertz radiation & Finite element method. The organization has 19024 authors who have published 39922 publications receiving 1414699 citations. The organization is also known as: RPI & Rensselaer Institute.

When does entrepreneurial self-efficacy enhance versus reduce firm performance?

Abstract: The entrepreneurial self-efficacy of lead founders has been generally considered to be a robust predictor of the performance of their firms. Few studies, however, have considered variables that might moderate this relationship. The current study attempts to fill this gap in the literature by examining two possible moderators of the effects of entrepreneurial self-efficacy on firm performance: dispositional optimism and environmental dynamism. Results indicate that these factors do indeed moderate the effects of entrepreneurial self-efficacy; in fact, a three-way interaction between self-efficacy, optimism, and environmental dynamism was observed with respect to firm performance. Consistent with predictions, in dynamic environments, the effects of high entrepreneurial self-efficacy on firm performance were positive when combined with moderate optimism, but negative when combined with high optimism. In stable environments, in contrast, the effects of self-efficacy were relatively weak, and were not moderated by optimism. Overall, results suggest that high self-efficacy is not always beneficial for entrepreneurs and may, in fact, exert negative effects under some conditions. Copyright © 2008 Strategic Management Society.

The mechanisms leading to the useful electrical properties of polymer nanodielectrics

Abstract: Polymer nanocomposites with metal oxide nanoparticle fillers exhibit enhanced electrical breakdown strength and voltage endurance compared to their unfilled or micron filled counterparts. This paper presents the following hypothesis for the mechanisms leading to improved properties. The inclusion of nanoparticles provides myriad scattering obstacles and trap sites in the charge carriers' paths, effectively reducing carrier mobility and thus carrier energy. The result is homocharge buildup at the electrodes, which increases the voltage required for further charge injection due to blocking by the homocharge. The hypothesis is supported by electroluminescence, pulsed electro acoustic analysis, thermally stimulated current measurements, a comparison of AC, DC, and impulse breakdown, as well as absorption current measurements, in silica/crosslinked polyethylene matrix composites with supporting evidence from titania/epoxy composites.

When owl: sameAs isn't the same: an analysis of identity in linked data

Abstract: In Linked Data, the use of owl:sameAs is ubiquitous in interlinking data-sets. There is however, ongoing discussion about its use, and potential misuse, particularly with regards to interactions with inference. In fact, owl:sameAs can be viewed as encoding only one point on a scale of similarity, one that is often too strong for many of its current uses. We describe how referentially opaque contexts that do not allow inference exist, and then outline some varieties of referentially-opaque alternatives to owl:sameAs. Finally, we report on an empirical experiment over randomly selected owl:sameAs statements from the Web of data. This theoretical apparatus and experiment shed light upon how owl:sameAs is being used (and misused) on the Web of data.

Characterizing hydrophobicity of interfaces by using cavity formation, solute binding, and water correlations

Abstract: Hydrophobicity is often characterized macroscopically by the droplet contact angle. Molecular signatures of hydrophobicity have, however, remained elusive. Successful theories predict a drying transition leading to a vapor-like region near large hard-sphere solutes and interfaces. Adding attractions wets the interface with local density increasing with attractions. Here we present extensive molecular simulation studies of hydration of realistic surfaces with a wide range of chemistries from hydrophobic (−CF3, −CH3) to hydrophilic (−OH, −CONH2). We show that the water density near weakly attractive hydrophobic surfaces (e.g., −CF3) can be bulk-like or larger, and provides a poor quantification of surface hydrophobicity. In contrast, the probability of cavity formation or the free energy of binding of hydrophobic solutes to interfaces correlates quantitatively with the macroscopic wetting properties and serves as an excellent signature of hydrophobicity. Specifically, the probability of cavity formation is enhanced in the vicinity of hydrophobic surfaces, and water–water correlations correspondingly display characteristics similar to those near a vapor–liquid interface. Hydrophilic surfaces suppress cavity formation and reduce the water–water correlation length. Our results suggest a potentially robust approach for characterizing hydrophobicity of more complex and heterogeneous surfaces of proteins and biomolecules, and other nanoscopic objects.

Passivity as a design tool for group coordination

Abstract: We pursue a group coordination problem where the objective is to steer the differences between output variables of the group members to a prescribed compact set via distributed feedback rules. When the information flow between neighboring members is bidirectional, we show that the closed-loop system exhibits a special interconnection structure which inherits the passivity properties of its components. By exploiting this structure we develop a passivity-based design framework, which results in a broad class of feedback rules that encompass as special cases some of the existing formation stabilization and group agreement designs in the literature. The passivity approach offers additional design flexibility compared to these special cases, and systematically constructs a Lurie-type Lyapunov function for the closed-loop system. We further study the robustness of the feedback laws in the presence of a time-varying communication topology.