Romanian Academy

About: Romanian Academy is a archive organization based out in Bucharest, Romania. It is known for research contribution in the topics: Population & Nonlinear system. The organization has 3662 authors who have published 10491 publications receiving 146447 citations. The organization is also known as: Academia Română & Societatea Literară Română.

Advances and opportunities in the exciting world of azobenzenes

Abstract: Azobenzenes are archetypal molecules that have a central role in fundamental and applied research. Over the course of almost two centuries, the area of azobenzenes has witnessed great achievements; azobenzenes have evolved from simple dyes to ‘little engines’ and have become ubiquitous in many aspects of our lives, ranging from textiles, cosmetics, food and medicine to energy and photonics. Despite their long history, azobenzenes continue to arouse academic interest, while being intensively produced for industrial purposes, owing to their rich chemistry, versatile and straightforward design, robust photoswitching process and biodegradability. The development of azobenzenes has stimulated the production of new coloured and light-responsive materials with various applications, and their use continues to expand towards new high-tech applications. In this Review, we highlight the latest achievements in the synthesis of red-light-responsive azobenzenes and the emerging application areas of photopharmacology, photoswitchable adhesives and biodegradable materials for drug delivery. We show how the synthetic versatility and adaptive properties of azobenzenes continue to inspire new research directions, with limits imposed only by one’s imagination. Over the past decade, advances in azobenzenes have revolutionized their application potential, going beyond traditional uses as dyes and ultraviolet photoswitches. This Review describes breakthroughs in the development of red-light-photoswitchable azobenzenes and emerging applications in photopharmacology, photoswitchable adhesives and biodegradable systems for drug delivery.

P Systems Running on a Cluster of Computers

Abstract: The paper presents a parallel implementation of the membrane systems. We implement the simplest variant of P systems, which however defines the essential features of the membrane systems, and acts as a framework for other variants of P systems with advanced functionalities. The mechanisms used in this implementation could be easily adapted to other versions of P systems with minor changes. The implementation is designed for a cluster of computers; it is written in C++ and it makes use of Message Passing Interface as its communication mechanism.

Synthesis of Schiff Base-Ruthenium Complexes and Their Applications in Catalytic Processes

Abstract: The synthesis of various Schiff base mononuclear and binuclear ruthenium complexes, whose additional ligands around the metal core have been selected from an array of motifs, is described. These types of ruthenium complexes, conveniently prepared from commonly available ruthenium sources, are rather stable, display good tolerance towards diverse organic functionalities and also to air and moisture. Remarkably, they exhibit a high activity and chemoselectivity in a variety of catalytic processes such as ring-closing metathesis (RCM), Kharasch addition, alkyne dimerization, enol ester synthesis, ring-opening metathesis polymerization (ROMP) and atom-transfer radical polymerization (ATRP). This review covers both homogeneous and heterogeneous hybrid Schiff base-ruthenium complexes.