Romanian Academy

About: Romanian Academy is a archive organization based out in Bucharest, Romania. It is known for research contribution in the topics: Population & Nonlinear system. The organization has 3662 authors who have published 10491 publications receiving 146447 citations. The organization is also known as: Academia Română & Societatea Literară Română.

Mechanical and corrosion resistance of a new nanostructured Ti–Zr–Ta–Nb alloy

Abstract: In this work, a multi-elementary Ti–10Zr–5Nb–5Ta alloy, with non-toxic alloying elements, was used to develop an accumulative roll bonding, ARB-type procedure in order to improve its structural and mechanical properties. The alloy was obtained by cold crucible semi-levitation melting technique and then was ARB deformed following a special route. After three ARB cycles, the total deformation degree per layer is about 86%; the calculated medium layer thickness is about 13 μm. The ARB processed alloy has a low Young’s modulus of 46 GPa, a value very close to the value of the natural cortical bone (about 20 GPa). Data concerning ultimate tensile strength obtained for ARB processed alloy is rather high, suitable to be used as a material for bone substitute. Hardness of the ARB processed alloy is higher than that of the as-cast alloy, ensuring a better behaviour as a implant material. The tensile curve for the as-cast alloy shows an elastoplastic behaviour with a quite linear elastic behaviour and the tensile curve for the ARB processed alloy is quite similar with a strain-hardening elastoplastic body. Corrosion behaviour of the studied alloy revealed the improvement of the main electrochemical parameters, as a result of the positive influence of ARB processing. Lower corrosion and ion release rates for the ARB processed alloy than for the as-cast alloy, due to the favourable effect of ARB thermo-mechanical processing were obtained.

Differentiation of mesenchymal stem cells onto highly adherent radio frequency‐sputtered carbonated hydroxylapatite thin films

Abstract: In this work, an improved version of the radio frequency magnetron sputtering (RF-MS) technique was used to prepare highly adherent B-type carbonated hydroxylapatite (B-CHA) thin films. Fourier transform infrared spectroscopy (FTIR) and grazing incidence X-ray diffraction studies proved that the coatings maintained the composition and revealed the polycrystalline structure of HA. Scanning electron microscopy analysis showed that the CHA films are rough and exhibit a homogeneous microstructure. Energy-dispersive X-ray spectroscopy (EDX) mapping demonstrated a uniform distribution of the Ca and P cations while a Ca/P ratio of 1.8 was found. In addition, the FTIR experiments showed a remarkable reproducibility of the nanostructures. Human mesenchymal stem cells (hMSCs), in vitro differentiated osteoblasts, and explanted bone cells were grown over the surface of CHA coatings for periods between a few hours and 21 days. Osteoprogenitor cells maintained viability and characteristic morphology after adhesion on CHA coatings. Ki67-positive osteoblasts were the evidence of cell proliferation events. Cells showed positive staining for markers of osteoblast phenotype such as collagen type I, bone sialoprotein and osteonectin. Our data showed the formation of mineralized foci by differentiation of hMSCs to human primary osteoblasts after cultivation in osteogenic media on RF-sputtered films. The results demonstrate the capacity of B-type CHA coating to support MSCs adhesion and osteogenic differentiation ability.

Propagation indices of methane-air explosions in closed vessels

Abstract: The peak explosion pressure, the maximum rate of pressure rise and the time necessary to reach the peak explosion pressure are important flammability indices of fuel–air combustion in closed vessels, characteristic for the laminar propagation stage of the process. In the present paper, these indices were examined using methane of various concentrations within the flammability limits, at variable initial pressure between 50 and 200 kPa and ambient initial temperature. For each composition, the experimental explosion pressures were compared with the adiabatic explosion pressures, computed under the assumption that chemical equilibrium is reached in the flame. The experimental explosion pressures and the rates of pressure rise are examined in comparison with literature data, the fluctuations being attributed to differences of heat lost by the flammable gas to the explosion vessel, during flame propagation. Using the differences between the adiabatic and experimental explosion pressures, the amount of heat lost to the walls during the explosion propagation in a closed vessel and the fraction of the transferred heat from the total released heat have been determined.

Kinetic and thermodynamic studies on methylene blue biosorption using corn-husk

Abstract: A low-cost waste biomass derived from corn plant (husk) was tested as an alternative to other expensive treatment options, for the removal of methylene blue (MB), from aqueous solutions. The effects of different experimental parameters, such as biosorbent dosage, dye concentration, contact time, and temperature, on the adsorption process were investigated. An optimum value of discoloration was observed at pH 6.0 and 2 g L−1 biomass dosage. The amount of dye removed per adsorbent unit decreased with increasing adsorbent dosage, temperature, and increased with increasing contact time, and concentration. Experimental data were modeled using first-order, pseudo-second-order, Elovich, and intraparticle diffusion kinetics models. The adsorption kinetics of MB could be described by the pseudo-second order reaction model. The experimental data were fitted to: Langmuir, Freundlich, Temkin, Redlich–Peterson, Toth, and Sips isotherm models and the best fitting was obtained with the Sips model. The thermodynamic parameters (ΔH°, ΔS° and ΔG°) obtained revealed that MB adsorption is a spontaneous, exothermic and physical process. The obtained results indicated that corn husk as a low-cost biomaterial is an attractive candidate for the removal of basic dye MB from aqueous solutions.