Siberian Federal University

About: Siberian Federal University is a education organization based out in Krasnoyarsk, Russia. It is known for research contribution in the topics: Magnetization & Heat capacity. The organization has 4440 authors who have published 6005 publications receiving 44558 citations. The organization is also known as: Sibirskiĭ federalʹnyĭ universitet & SibFU.

Large Scale Growth and Characterization of Atomic Hexagonal Boron Nitride Layers

Abstract: Hexagonal boron nitride (h-BN), a layered material similar to graphite, is a promising dielectric. Monolayer h-BN, so-called "white graphene", has been isolated from bulk BN and could be useful as a complementary two-dimensional dielectric substrate for graphene electronics. Here we report the large area synthesis of h-BN films consisting of two to five atomic layers, using chemical vapor deposition. These atomic films show a large optical energy band gap of 5.5 eV and are highly transparent over a broad wavelength range. The mechanical properties of the h-BN films, measured by nanoindentation, show 2D elastic modulus in the range of 200-500 N/m, which is corroborated by corresponding theoretical calculations.

Cooling and societal change during the Late Antique Little Ice Age from 536 to around 660 AD

Abstract: Societal upheaval occurred across Eurasia in the sixth and seventh centuries. Tree-ring reconstructions suggest a period of pronounced cooling during this time associated with several volcanic eruptions. Climatic changes during the first half of the Common Era have been suggested to play a role in societal reorganizations in Europe1,2 and Asia3,4. In particular, the sixth century coincides with rising and falling civilizations1,2,3,4,5,6, pandemics7,8, human migration and political turmoil8,9,10,11,12,13. Our understanding of the magnitude and spatial extent as well as the possible causes and concurrences of climate change during this period is, however, still limited. Here we use tree-ring chronologies from the Russian Altai and European Alps to reconstruct summer temperatures over the past two millennia. We find an unprecedented, long-lasting and spatially synchronized cooling following a cluster of large volcanic eruptions in 536, 540 and 547 AD (ref. 14), which was probably sustained by ocean and sea-ice feedbacks15,16, as well as a solar minimum17. We thus identify the interval from 536 to about 660 AD as the Late Antique Little Ice Age. Spanning most of the Northern Hemisphere, we suggest that this cold phase be considered as an additional environmental factor contributing to the establishment of the Justinian plague7,8, transformation of the eastern Roman Empire and collapse of the Sasanian Empire1,2,5, movements out of the Asian steppe and Arabian Peninsula8,11,12, spread of Slavic-speaking peoples9,10 and political upheavals in China13.

Eu2+ Site Preferences in the Mixed Cation K2BaCa(PO4)2 and Thermally Stable Luminescence.

Abstract: Site preferences of dopant Eu2+ on the locations of K+, Ba2+, and Ca2+ in the mixed cation phosphate K2BaCa(PO4)2 (KBCP) are quantitatively analyzed via a combined experimental and theoretical method to develop a blue-emitting phosphor with thermally stable luminescence. Eu2+ ions are located at K2 (M2) and K3 (M3) sites of KBCP, with the latter occupation relatively more stable than the former, corresponding to emissions at 438 and 465 nm, respectively. KBCP:Eu2+ phosphor exhibits highly thermal stable luminescence even up to 200 °C, which is interpreted as due to a balance between thermal ionization and recombination of Eu2+ 5d excited-state centers with the involvement of electrons trapped at crystal defect levels. Our results can initiate more exploration of activator site engineering in phosphors and therefore allow predictive control of photoluminescence tuning and thermally stable luminescence for emerging applications in white LEDs.

Theory and Calculation of the Phosphorescence Phenomenon

Abstract: Phosphorescence is a phenomenon of delayed luminescence that corresponds to the radiative decay of the molecular triplet state. As a general property of molecules, phosphorescence represents a cornerstone problem of chemical physics due to the spin prohibition of the underlying triplet-singlet emission and because its analysis embraces a deep knowledge of electronic molecular structure. Phosphorescence is the simplest physical process which provides an example of spin-forbidden transformation with a characteristic spin selectivity and magnetic field dependence, being the model also for more complicated chemical reactions and for spin catalysis applications. The bridging of the spin prohibition in phosphorescence is commonly analyzed by perturbation theory, which considers the intensity borrowing from spin-allowed electronic transitions. In this review, we highlight the basic theoretical principles and computational aspects for the estimation of various phosphorescence parameters, like intensity, radiative...

Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition.

Abstract: Phosphor-converted white LEDs rely on combining a blue-emitting InGaN chip with yellow and red-emitting luminescent materials. The discovery of cyan-emitting (470–500 nm) phosphors is a challenge to compensate for the spectral gap and produce full-spectrum white light. Na0.5K0.5Li3SiO4:Eu2+ (NKLSO:Eu2+) phosphor was developed with impressive properties, providing cyan emission at 486 nm with a narrow full width at half maximum (FWHM) of only 20.7 nm, and good thermal stability with an integrated emission loss of only 7% at 150 °C. The ultra-narrow-band cyan emission results from the high-symmetry cation sites, leading to almost ideal cubic coordination for UCr4C4-type compounds. NKLSO:Eu2+ phosphor allows the valley between the blue and yellow emission peaks in the white LED device to be filled, and the color-rendering index can be enhanced from 86 to 95.2, suggesting great applications in full-spectrum white LEDs. Luminescent crystals that efficiently emit light in the narrow cyan color wavelength range, from 470 to 500 nanometers, could be used to fill a gap or “valley” in light-emitting diodes (LEDs) intended to mimic the full spectrum of daylight. There is great interest in developing more efficient and cost-effective full daylight spectrum LED lighting sources. These can create more natural indoor lighting conditions that are also believed to be more beneficial for health. Researchers in China and Russia, led by Zhiguo Xia at the University of Science and Technology Beijing, developed a suitable inorganic crystalline compound showing narrow cyan emission, with the formula Na0.5K0.5Li3SiO4:Eu2+. The many possible applications include LEDs for daylight spectrum lamps used to treat the low mood and depression associated with Seasonal Affective Disorder (SAD).