Showing papers by "South China University of Technology published in 2009"

High-detectivity polymer photodetectors with spectral response from 300 nm to 1450 nm.

Abstract: Sensing from the ultraviolet-visible to the infrared is critical for a variety of industrial and scientific applications. Today, gallium nitride-, silicon-, and indium gallium arsenide--based detectors are used for different sub-bands within the ultraviolet to near-infrared wavelength range. We demonstrate polymer photodetectors with broad spectral response (300 to 1450 nanometers) fabricated by using a small-band-gap semiconducting polymer blended with a fullerene derivative. Operating at room temperature, the polymer photodetectors exhibit detectivities greater than 10(12) cm Hz(1/2)/W and a linear dynamic range over 100 decibels. The self-assembled nanomorphology and device architecture result in high photodetectivity over this wide spectral range and reduce the dark current (and noise) to values well below dark currents obtained in narrow-band photodetectors made with inorganic semiconductors.

Development of novel conjugated donor polymers for high-efficiency bulk-heterojunction photovoltaic devices.

Abstract: Solar cells are one attractive method for harnessing inexhaustible clean energy from the sun. Organic photovoltaic technology is emerging as a potential competitor to silicon-based photovoltaic cells (PVCs), and their power conversion efficiencies (PCE) can now exceed 6%. Polymeric bulk-heterojunction (BHJ) PVCs, whose photoactive layer is composed of a blend of bicontinuous and interpenetrating donors and acceptors, can maximize interfacial area between the donor and the acceptor. Classic polymer donors, such as dialkoxy-substituted poly(para-phenylene vinylene)s (PPVs) and poly(3-hexylthiophene) (P3HT), have been widely investigated. However, advances in synthetic methodology provide new avenues for the development of novel conjugated polymer donors with improved power conversion efficiencies. Recently, researchers have achieved great advances in this area. This Account primarily focuses on novel donor polymers that have shown power conversion efficiencies greater than 1%. 2,1,3-Benzothiadiazole, thioph...

The genome of the cucumber, Cucumis sativus L.

Abstract: Cucumber is an economically important crop as well as a model system for sex determination studies and plant vascular biology. Here we report the draft genome sequence of Cucumis sativus var. sativus L., assembled using a novel combination of traditional Sanger and next-generation Illumina GA sequencing technologies to obtain 72.2-fold genome coverage. The absence of recent whole-genome duplication, along with the presence of few tandem duplications, explains the small number of genes in the cucumber. Our study establishes that five of the cucumber's seven chromosomes arose from fusions of ten ancestral chromosomes after divergence from Cucumis melo. The sequenced cucumber genome affords insight into traits such as its sex expression, disease resistance, biosynthesis of cucurbitacin and 'fresh green' odor. We also identify 686 gene clusters related to phloem function. The cucumber genome provides a valuable resource for developing elite cultivars and for studying the evolution and function of the plant vascular system.

A facile and efficient preparation of pillararenes and a pillarquinone.

Abstract: Calixarenes 1 and their derivatives have attracted considerable attention over the past two decades. This attention can be attributed to their applications in areas as diverse as gas adsorption, nanotubes, catalysis, DNA recognition and fullerene chemistry. Recently, many calixarene analogues have been developed in supramolecular chemistry, such as calixpyrroles, thiacalixarenes, and homooxacalixarenes. In contrast to the vast literature about the meta-bridged cyclooligomers 1, very little is known about their para-bridged analogues 2, called pillar[n]arenes (Scheme 1). Recently, the

DE-Based Reversible Data Hiding With Improved Overflow Location Map

Abstract: For difference-expansion (DE)-based reversible data hiding, the embedded bit-stream mainly consists of two parts: one part that conveys the secret message and the other part that contains embedding information, including the 2-D binary (overflow) location map and the header file. The first part is the payload while the second part is the auxiliary information package for blind detection. To increase embedding capacity, we have to make the size of the second part as small as possible. Tian's classical DE method has a large auxiliary information package. Thodi mitigated the problem by using a payload-independent overflow location map. However, the compressibility of the overflow location map is still undesirable in some image types. In this paper, we focus on improving the overflow location map. We design a new embedding scheme that helps us construct an efficient payload-dependent overflow location map. Such an overflow location map has good compressibility. Our accurate capacity control capability also reduces unnecessary alteration to the image. Under the same image quality, the proposed algorithm often has larger embedding capacity. It performs well in different types of images, including those where other algorithms often have difficulty in acquiring good embedding capacity and high image quality.

Progress and perspective of polymer white light-emitting devices and materials

Abstract: Within organic optoelectronics, polymer light-emitting devices (PLEDs) are regarded as an important class of devices which can convert electricity into light as a result of radiative decay taking place in semiconducting polymers. Recently, much effort has been devoted to developing efficient white emitting PLEDs for their potential applications in next-generation flat-panel displays and solid-state lighting sources. In this tutorial review, we will summarize the advances in white emitting polymers and devices published up till April 2009 by major prestigious institutions in this field. Special attention is paid to the recent progress in highly efficient devices realized by doping an electrophosphorescent guest into a polymer host and other approaches. Also we will summarize the new strategies to realize white emission with simultaneous fluorescent and/or phosphorescent emission from a single polymer in which singlet and/or triplet chromophores are incorporated into the polymer side or main chain through a covalent bond.

Comparative study of hemicelluloses obtained by graded ethanol precipitation from sugarcane bagasse.

Abstract: The sequential treatment of dewaxed sugarcane bagasse with H(2)O and 1 and 3% NaOH at a solid to liquid ratio of 1:25 (g mL(-1)) at 50 degrees C for 3 h yielded 74.9% of the original hemicelluloses. Each of the hemicellulosic fractions was successively subfractionated by graded precipitation at ethanol concentrations of 15, 30, and 60% (v/v). Chemical composition, physicochemical properties, and structures of eight precipitated hemicellulosic fractions were elucidated by a combination of sugar analysis, nitrobenzene oxidation of bound lignin, molecular determination, Fourier transform infrared (FT-IR), (1)H and (13)C nuclear magnetic spectroscopies, and thermal analysis. The results showed that the sequential treatments and graded precipitations were very effective on the fractionation of hemicelluloses from bagasse. Comparison of these hemicelluloses indicated that the smaller sized and more branched hemicelluloses were extracted by the hot water treatment; they are rich in glucose, probably originating from alpha-glucan and pectic polysaccharides. The larger molecular size and more linear hemicelluloses were dissolved by the alkali treatment; they are rich in xylose, principally resulting from l-arabino-(4-O-methylglucurono)-d-xylans. In addition, noticeable differences in the chemical composition and molecular weights were observed among the graded hemicellulosic subfractions from the water-soluble and alkali-soluble hemicelluloses. The Ara/Xyl ratio increased with the increment of ethanol concentration from 15 to 60%, and the arabinoxylans with higher Ara/Xyl ratios had higher molecular weights. There were no significant differences in the structural features of the precipitated hemicellulosic subfractions, which are mainly constituted of l-arabino-(4-O-methyl-d-glucurono)xylan, whereas the difference may occur in the distribution of branches along the xylan backbone.

Development of New Conjugated Polymers with Donor−π-Bridge−Acceptor Side Chains for High Performance Solar Cells

Abstract: Two new conjugated polymers have been designed and synthesized for polymer solar cells. Both of them exhibit excellent photovoltaic properties with a power conversion efficiency as high as 4.74%. Different from the traditional linear donor-acceptor (D-A) type conjugated polymers, these newly designed polymers have a two-dimensional conjugated structure with their tunable acceptors located at the end of D-A side chains and connected with the donors on the main chain through an efficient pi-bridge. This approach provides great flexibility in fine-tuning the absorption spectra and energy levels of the resultant polymers for achieving high device performance.

Complete Resequencing of 40 Genomes Reveals Domestication Events and Genes in Silkworm (Bombyx)

Abstract: A single-base pair resolution silkworm genetic variation map was constructed from 40 domesticated and wild silkworms, each sequenced to approximately threefold coverage, representing 99.88% of the genome. We identified ∼16 million single-nucleotide polymorphisms, many indels, and structural variations. We find that the domesticated silkworms are clearly genetically differentiated from the wild ones, but they have maintained large levels of genetic variability, suggesting a short domestication event involving a large number of individuals. We also identified signals of selection at 354 candidate genes that may have been important during domestication, some of which have enriched expression in the silk gland, midgut, and testis. These data add to our understanding of the domestication processes and may have applications in devising pest control strategies and advancing the use of silkworms as efficient bioreactors.

An Aggregation Approach to Short-Term Traffic Flow Prediction

Abstract: In this paper, an aggregation approach is proposed for traffic flow prediction that is based on the moving average (MA), exponential smoothing (ES), autoregressive MA (ARIMA), and neural network (NN) models. The aggregation approach assembles information from relevant time series. The source time series is the traffic flow volume that is collected 24 h/day over several years. The three relevant time series are a weekly similarity time series, a daily similarity time series, and an hourly time series, which can be directly generated from the source time series. The MA, ES, and ARIMA models are selected to give predictions of the three relevant time series. The predictions that result from the different models are used as the basis of the NN in the aggregation stage. The output of the trained NN serves as the final prediction. To assess the performance of the different models, the naive, ARIMA, nonparametric regression, NN, and data aggregation (DA) models are applied to the prediction of a real vehicle traffic flow, from which data have been collected at a data-collection point that is located on National Highway 107, Guangzhou, Guangdong, China. The outcome suggests that the DA model obtains a more accurate forecast than any individual model alone. The aggregation strategy can offer substantial benefits in terms of improving operational forecasting.

Viewpoint Invariant Texture Description Using Fractal Analysis

Abstract: Image texture provides a rich visual description of the surfaces in the scene. Many texture signatures based on various statistical descriptions and various local measurements have been developed. Existing signatures, in general, are not invariant to 3D geometric transformations, which is a serious limitation for many applications. In this paper we introduce a new texture signature, called the multifractal spectrum (MFS). The MFS is invariant under the bi-Lipschitz map, which includes view-point changes and non-rigid deformations of the texture surface, as well as local affine illumination changes. It provides an efficient framework combining global spatial invariance and local robust measurements. Intuitively, the MFS could be viewed as a "better histogram" with greater robustness to various environmental changes and the advantage of capturing some geometrical distribution information encoded in the texture. Experiments demonstrate that the MFS codes the essential structure of textures with very low dimension, and thus represents an useful tool for texture classification.

Adsorption and Diffusion of Carbon Dioxide on Metal−Organic Framework (MOF-5)

Abstract: Adsorption equilibrium and diffusion of CO2 on microporous metal−organic frameworks (MOF-5, or IRMOF-1) crystals were experimentally studied by the gravimetric method in the pressure range up to 1 atm. The MOF-5 crystal cubes of about 40−60 μm in sizes were synthesized by the solvothermal method. Freundlich adsorption isotherm equation can fit well CO2 adsorption isotherms on MOF-5, with isosteric heat of adsorption of about 34 kJ/mol. Diffusion coefficient of CO2 in the MOF-5 is in the range of 8.1−11.5 × 10−9 cm2/s in 295−331K with activation energy of 7.61 kJ/mol. MOF-5 offers attractive adsorption properties as an adsorbent for separation of CO2 from flue gas.

Activity recognition from acceleration data based on discrete consine transform and SVM

Abstract: This paper developed a high-accuracy human activity recognition system based on single tri-axis accelerometer for use in a naturalistic environment. This system exploits the discrete cosine transform (DCT), the Principal Component Analysis (PCA) and Support Vector Machine (SVM) for classification human different activity. First, the effective features are extracted from accelerometer data using DCT. Next, feature dimension is reduced by PCA in DCT domain. After implementing the PCA, the most invariant and discriminating information for recognition is maintained. As a consequence, Multi-class Support Vector Machines is adopted to distinguish different human activities. Experiment results show that the proposed system achieves the best accuracy is 97.51%, which is better than other approaches.

Experimental Investigation of Heat Conduction Mechanisms in Nanofluids. Clue on Clustering

Abstract: Heat conduction mechanisms in nanofluids, fluids seeded with nanoparticles, have been extensively scrutinized in the past decades to explain some experimental observations of their enhanced thermal conductivity beyond the effective medium theory. Although many mechanisms such as Brownian motion, clustering, ballistic transport, and internanoparticle potential are speculated, experimental proof of any of the mechanisms has been difficult. Here, we investigate the mechanisms experimentally by thermal conductivity measurements and structural analysis for the same materials in both liquid and solid states. These studies strongly suggest that clustering holds the key to the thermal conductivity enhancement of nanofluids.

Effect of degree of hydrolysis on the antioxidant activity of loach (Misgurnus anguillicaudatus) protein hydrolysates.

Abstract: Loach ( Misgurnus anguillicaudatus ) proteins were hydrolysed by papain and Protamex, the antioxidant activity of loach protein hydrolysates (LPH) was investigated. The results demonstrated that extensive hydrolysis by papain and Protamex led to the browning of the hydrolysates. When the degree of hydrolysis (DH) was 23%, hydrolysates prepared by papain (HA) exhibited the strongest antioxidant activity. The maximum values of the hydroxyl, 1,1-diphenyl-2-picrylhydrazyl (DPPH), 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) diammonium salt (ABTS) radical scavenging activities and the reducing power were 56.1%, 95.5%, 2.80 mM and 1.46, respectively. The hydrolysates prepared by Protamex (HB) showed the strongest hydroxyl radical scavenging activity (55.0%) at DH 28%, DPPH radical scavenging activity (92.2%) and ABTS radical scavenging activity (2.81 mM) at DH 23%, and the reducing power (1.17) at DH 33%. At the same DH value, there were significant ( p Industrial relevance Loach has long been employed as a traditional Chinese medicine for the treatment of many kinds of diseases. From our previous work, loach was determined to be a good source of protein (accounts for approximately 17% (w/w) of the body weight). In this work, loach proteins were hydrolyzed by papain and Protamex to specific extent. The effect of DH on the antioxidant activities of hydrolysates was investigated. The results indicated that loach protein hydrolysates were potent antioxidants which were significantly affected by DH. This research is helpful for extensive development of loach product.