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Showing papers by "Southwest University published in 2017"


Journal ArticleDOI
TL;DR: The simulation results show that the proposed path-planning approach is effective for many driving scenarios, and the MMPC-based path-tracking controller provides dynamic tracking performance and maintains good maneuverability.
Abstract: A path planning and tracking framework is presented to maintain a collision-free path for autonomous vehicles. For path-planning approaches, a 3-D virtual dangerous potential field is constructed as a superposition of trigonometric functions of the road and the exponential function of obstacles, which can generate a desired trajectory for collision avoidance when a vehicle collision with obstacles is likely to happen. Next, to track the planned trajectory for collision avoidance maneuvers, the path-tracking controller formulated the tracking task as a multiconstrained model predictive control (MMPC) problem and calculated the front steering angle to prevent the vehicle from colliding with a moving obstacle vehicle. Simulink and CarSim simulations are conducted in the case where moving obstacles exist. The simulation results show that the proposed path-planning approach is effective for many driving scenarios, and the MMPC-based path-tracking controller provides dynamic tracking performance and maintains good maneuverability.

675 citations


Journal ArticleDOI
TL;DR: Improvement of citrus canker resistance through CRISPR/Cas9‐targeted modification of the susceptibility gene CsLOB1 promoter in citrus is reported and is demonstrated to be an efficient strategy for generation of canker‐resistant citrus cultivars.
Abstract: Citrus canker, caused by Xanthomonas citri subsp. citri (Xcc), is severely damaging to the global citrus industry. Targeted editing of host disease-susceptibility genes represents an interesting and potentially durable alternative in plant breeding for resistance. Here, we report improvement of citrus canker resistance through CRISPR/Cas9-targeted modification of the susceptibility gene CsLOB1 promoter in citrus. Wanjincheng orange (Citrus sinensis Osbeck) harbours at least three copies of the CsLOB1G allele and one copy of the CsLOB1- allele. The promoter of both alleles contains the effector binding element (EBEPthA4 ), which is recognized by the main effector PthA4 of Xcc to activate CsLOB1 expression to promote citrus canker development. Five pCas9/CsLOB1sgRNA constructs were designed to modify the EBEPthA4 of the CsLOB1 promoter in Wanjincheng orange. Among these constructs, mutation rates were 11.5%-64.7%. Homozygous mutants were generated directly from citrus explants. Sixteen lines that harboured EBEPthA4 modifications were identified from 38 mutant plants. Four mutation lines (S2-5, S2-6, S2-12 and S5-13), in which promoter editing disrupted CsLOB1 induction in response to Xcc infection, showed enhanced resistance to citrus canker compared with the wild type. No canker symptoms were observed in the S2-6 and S5-13 lines. Promoter editing of CsLOB1G alone was sufficient to enhance citrus canker resistance in Wanjincheng orange. Deletion of the entire EBEPthA4 sequence from both CsLOB1 alleles conferred a high degree of resistance to citrus canker. The results demonstrate that CRISPR/Cas9-mediated promoter editing of CsLOB1 is an efficient strategy for generation of canker-resistant citrus cultivars.

457 citations


Journal ArticleDOI
21 Sep 2017-Polymer
TL;DR: The development of nanocellulose composites and materials has attracted significant interest in recent decades because they show unique and potentially useful features, including abundance, renewability, high strength and stiffness, eco-friendliness, and low weight as mentioned in this paper.

430 citations


Posted Content
TL;DR: In this paper, the authors jointly optimize the wake-up schedule and UAV's trajectory to minimize the maximum energy consumption of all ground sensor nodes, while ensuring that the required amount of data is collected reliably from each SN.
Abstract: In wireless sensor networks (WSNs), utilizing the unmanned aerial vehicle (UAV) as a mobile data collector for the ground sensor nodes (SNs) is an energy-efficient technique to prolong the network lifetime. Specifically, since the UAV can sequentially move close to each of the SNs when collecting data from them and thus reduce the link distance for saving the SNs' transmission energy. In this letter, considering a general fading channel model for the SN-UAV links, we jointly optimize the SNs' wake-up schedule and UAV's trajectory to minimize the maximum energy consumption of all SNs, while ensuring that the required amount of data is collected reliably from each SN. We formulate our design as a mixed-integer non-convex optimization problem. By applying the successive convex optimization technique, an efficient iterative algorithm is proposed to find a sub-optimal solution. Numerical results show that the proposed scheme achieves significant network energy saving as compared to benchmark schemes.

426 citations


Journal ArticleDOI
TL;DR: In this article, a comprehensive review of power management strategy (PMS) utilized in hybrid electric vehicles (HEVs) with an emphasis on model predictive control (MPC) based strategies for the first time is presented.

384 citations


Journal ArticleDOI
TL;DR: Drought-induced osmolyte accumulation and strong enzymatic and non-enzymatic defense systems prevented the severe damage in Dong Dan 80; nevertheless, negative effects of drought stress were more prominent in Run Nong 35.
Abstract: Consequences of drought stress in crop production systems are perhaps more deleterious than other abiotic stresses under changing climatic scenarios. Regulations of physio-biochemical responses of plants under drought stress can be used as markers for drought stress tolerance in selection and breeding. The present study was conducted to appraise the performance of three different maize hybrids (Dong Dan 80, Wan Dan 13, and Run Nong 35) under well-watered, low, moderate and SD conditions maintained at 100, 80, 60, and 40% of field capacity, respectively. Compared with well-watered conditions, drought stress caused oxidative stress by excessive production of reactive oxygen species (ROS) which led to reduced growth and yield formation in all maize hybrids; nevertheless, negative effects of drought stress were more prominent in Run Nong 35. Drought-induced osmolyte accumulation and strong enzymatic and non-enzymatic defense systems prevented the severe damage in Dong Dan 80. Overall performance of all maize hybrids under drought stress was recorded as: Dong Dan 80 > Wan Dan 13 > Run Nong 35 with 6.39, 7.35, and 16.55% yield reductions. Consequently, these biochemical traits and differential physiological responses might be helpful to develop drought tolerance genotypes that can withstand water-deficit conditions with minimum yield losses.

361 citations


Journal ArticleDOI
TL;DR: In this article, electrical conductivity and the electromagnetic interference (EMI) shielding effectiveness of poly(L-lactide)/multi-walled carbon nanotube (PLLA/MWCNT) nanocomposites without sacrificing their mechanical properties via simply choosing two different PLLA polymers with different viscosities and crystallinities.
Abstract: Electrically conductive segregated networks were built in poly(L-lactide)/multi-walled carbon nanotube (PLLA/MWCNT) nanocomposites without sacrificing their mechanical properties via simply choosing two different PLLA polymers with different viscosities and crystallinities. First, the MWCNTs were dispersed in PLLA with low viscosity and crystallinity (L-PLLA) to obtain the L-PLANT phase. Second, the PLLA particles with high viscosity and crystallinity (H-PLLA) were well coated with the L-PLANT phase at 140 °C which was below the melting temperature of H-PLLA. Finally, the coated H-PLLA particles were compressed above the melting temperature of H-PLLA to form the PLLA/MWCNT nanocomposites with segregated structures. The morphological observation showed the successful location of MWCNTs in the continuous L-PLLA phase, resulting in an ultralow percolation threshold of 0.019 vol% MWCNTs. The electrical conductivity and the electromagnetic interference (EMI) shielding effectiveness (SE) of the composites with the segregated structure are 25 S m−1 and ∼30 dB, showing three orders and 36% higher than that of the samples with a random distribution of MWCNTs with 0.8 vol% of MWCNT loading, respectively. High-performance electromagnetic interference (EMI) shielding was also observed mainly dependent on the highly efficient absorption shielding, which can be achieved by the densely continuous MWCNT networks and the abundant interfaces induced by the segregated structures. Furthermore, the composites with segregated structures not only showed higher Young's modulus and tensile strength than the corresponding conventional composites, but also maintained high elongation at break because of the continuous and dense MWCNT networks induced by the segregated structures and the high interfacial interaction between H-PLLA and L-PLLA.

317 citations


Journal ArticleDOI
TL;DR: In this article, the nanoporous carbons (NPC) derived from a one-step carbonization of zeolitic imidazolate framework-8 (ZIF-8) were synthesized and used for ciprofloxacin (CIP) removal from water.

311 citations


Journal ArticleDOI
TL;DR: It is suggested that in collectivistic cultural settings, individual differences in expressive suppression do not alter fear-related neural activation during suppression-irrelevant context, as reflected by the priming-specific decrease of emotional subcortical activations with more use of expressive suppression.
Abstract: Though the spontaneous emotion regulation has received long discussions, few studies have explored the regulatory effects of spontaneous expressive suppression at the neural level. The functional magnetic resonance imaging (fMRI) study aimed to examine whether individual differences in the tendency to use suppression manifests in decreased amygdala responses when individuals are spontaneously confronted with negative situations in Chinese culture valuing emotion suppression. Twenty-three heathy Chinese undergraduates completed a fMRI paradigm involving fear processing, and a synonym matching task was added to prime participants with the unconscious (automatic) expressive suppression goal. Participants completed measures of typical emotion regulation use (reappraisal and suppression), trait anxiety, and neuroticism. Results indicated that only in emotion suppression prime condition, greater use of suppression in everyday life was related to decreased amygdala activity. These associations were not attributable to variation in trait anxiety, neuroticism, or the habitual use of reappraisal. These findings suggest that 1) though Chinese cultures value emotion suppression, the regulatory effects of spontaneous suppression depends on the situational factors; 2) like spontaneous reappraisal, individual differences in suppression use are associated with decreased activation in ventral emotion generative regions in response to negative stimuli.

287 citations


Journal ArticleDOI
TL;DR: This study de novo sequenced and comprehensively studied the genomes of four representative citrus species and found a miniature inverted-repeat transposable element insertion in the promoter region of CitRWP that cosegregated with polyembryony.
Abstract: Qiang Xu and colleagues sequence four citrus species de novo, along with 100 accessions, including primitive, wild and cultivated citrus. Their genomic analyses associate the CitRWP gene with polyembryony and suggest that regions harboring energy- and reproduction-associated genes are probably under selection in cultivated citrus. The emergence of apomixis—the transition from sexual to asexual reproduction—is a prominent feature of modern citrus. Here we de novo sequenced and comprehensively studied the genomes of four representative citrus species. Additionally, we sequenced 100 accessions of primitive, wild and cultivated citrus. Comparative population analysis suggested that genomic regions harboring energy- and reproduction-associated genes are probably under selection in cultivated citrus. We also narrowed the genetic locus responsible for citrus polyembryony, a form of apomixis, to an 80-kb region containing 11 candidate genes. One of these, CitRWP, is expressed at higher levels in ovules of polyembryonic cultivars. We found a miniature inverted-repeat transposable element insertion in the promoter region of CitRWP that cosegregated with polyembryony. This study provides new insights into citrus apomixis and constitutes a promising resource for the mining of agriculturally important genes.

269 citations


Journal ArticleDOI
TL;DR: The gene families encoding receptors for bitter or toxic substances and detoxification enzymes, such as cytochrome P450, carboxylesterase and glutathione-S-transferase were massively expanded in this polyphagous species, enabling its extraordinary ability to detect and detoxify many plant secondary compounds.
Abstract: The tobacco cutworm, Spodoptera litura, is among the most widespread and destructive agricultural pests, feeding on over 100 crops throughout tropical and subtropical Asia. By genome sequencing, physical mapping and transcriptome analysis, we found that the gene families encoding receptors for bitter or toxic substances and detoxification enzymes, such as cytochrome P450, carboxylesterase and glutathione-S-transferase, were massively expanded in this polyphagous species, enabling its extraordinary ability to detect and detoxify many plant secondary compounds. Larval exposure to insecticidal toxins induced expression of detoxification genes, and knockdown of representative genes using short interfering RNA (siRNA) reduced larval survival, consistent with their contribution to the insect’s natural pesticide tolerance. A population genetics study indicated that this species expanded throughout southeast Asia by migrating along a South India–South China–Japan axis, adapting to wide-ranging ecological conditions with diverse host plants and insecticides, surviving and adapting with the aid of its expanded detoxification systems. The findings of this study will enable the development of new pest management strategies for the control of major agricultural pests such as S. litura. Genome of the tobacco cutworm, Spodoptera litura, which is one of the most widespread and destructive agricultural pests in tropical and subtropical Asia.

Journal ArticleDOI
TL;DR: The long-wavelength and multicolor emission properties of CDs and ways to achieve these goals including surface state and size controlled by synthesis strategies, proper precursors, chemical doping and modification, solvatochromic effects and energy transfer are reviewed in detail.
Abstract: Herein, we summarize recent research developments and progress of carbon dots (CDs), which have been attracting considerable attention as a new type of photoluminescent material. Raw materials, from single carbonaceous compounds to colorful natural substances, for the synthesis of CDs are discussed. A range of diverse synthetic methodologies to achieve better photoluminescence performance and more advanced functions are summarized, and these are basically divided into two classes: top-down and bottom-up. The inspiring properties, mainly including composites, optical properties and cytotoxicity, are listed. In particular, the luminescence mechanism and surface functionalization of the CDs are briefly discussed. Moreover, on the basis of the above, the long-wavelength and multicolor emission properties of CDs and ways to achieve these goals including surface state and size controlled by synthesis strategies, proper precursors, chemical doping and modification, solvatochromic effects and energy transfer are reviewed in detail.

Journal ArticleDOI
TL;DR: Simulation results and performance analyses verify the effectiveness of the proposed encryption algorithm, which can achieve the image data security and image appearance security simultaneously, and the size of the cipher image and original image is equal, it does not require additional transmission bandwidth and storage space.

Journal ArticleDOI
TL;DR: This review focuses on how ROS/RNS are produced and mediate signaling in CNS and how Trx and GSH systems regulate redox signaling by catalyzing reversible thiol modifications, and the effects of certain small molecules that target thiol-based signaling pathways in the CNS.
Abstract: Significance: The thioredoxin (Trx) and glutathione (GSH) systems play important roles in maintaining the redox balance in the brain, a tissue that is prone to oxidative stress due to its high-energy demand. These two disulfide reductase systems are active in various areas of the brain and are considered to be critical antioxidant systems in the central nervous system (CNS). Various neuronal disorders have been characterized to have imbalanced redox homeostasis. Recent Advances: In addition to their detrimental effects, recent studies have highlighted that reactive oxygen species/reactive nitrogen species (ROS/RNS) act as critical signaling molecules by modifying thiols in proteins. The Trx and GSH systems, which reversibly regulate thiol modifications, regulate redox signaling involved in various biological events in the CNS. Critical Issues: In this review, we focus on the following: (i) how ROS/RNS are produced and mediate signaling in CNS; (ii) how Trx and GSH systems regulate redox signaling...

Journal ArticleDOI
TL;DR: Novel K3V2(PO4)3 and three-dimensional conductive network K3M3/C nanocomposites are successfully fabricated and further evaluated as cathode materials for potassium-ion batteries for the first time.

Journal ArticleDOI
TL;DR: The integrated BAC-to-BAC and whole-genome shotgun sequencing strategies were effective in the assembly of repetitive regions (especially young long terminal repeats) and resulted in a high-quality genome assembly of B. napus 'ZS11', and certain genetic differences were also detected in two morphotypes.
Abstract: Allotetraploid oilseed rape (Brassica napus L.) is an agriculturally important crop. Cultivation and breeding of B. napus by humans has resulted in numerous genetically diverse morphotypes with optimized agronomic traits and ecophysiological adaptation. To further understand the genetic basis of diversification and adaptation, we report a draft genome of an Asian semi-winter oilseed rape cultivar 'ZS11' and its comprehensive genomic comparison with the genomes of the winter-type cultivar 'Darmor-bzh' as well as two progenitors. The integrated BAC-to-BAC and whole-genome shotgun sequencing strategies were effective in the assembly of repetitive regions (especially young long terminal repeats) and resulted in a high-quality genome assembly of B. napus 'ZS11'. Within a short evolutionary period (~6700 years ago), semi-winter-type 'ZS11' and the winter-type 'Darmor-bzh' maintained highly genomic collinearity. Even so, certain genetic differences were also detected in two morphotypes. Relative to 'Darmor-bzh', both two subgenomes of 'ZS11' are closely related to its progenitors, and the 'ZS11' genome harbored several specific segmental homoeologous exchanges (HEs). Furthermore, the semi-winter-type 'ZS11' underwent potential genomic introgressions with B. rapa (Ar ). Some of these genetic differences were associated with key agronomic traits. A key gene of A03.FLC3 regulating vernalization-responsive flowering time in 'ZS11' was first experienced HE, and then underwent genomic introgression event with Ar , which potentially has led to genetic differences in controlling vernalization in the semi-winter types. Our observations improved our understanding of the genetic diversity of different B. napus morphotypes and the cultivation history of semi-winter oilseed rape in Asia.

Journal ArticleDOI
TL;DR: Enhanced properties were attributed to the construction of 3D self-segregated structures, concentrated distribution of MWCNTs, and strong interfacial interaction between the segregated phase and the continuous phase with chemical bonds formed during the second curing process.
Abstract: Formation of highly conductive networks is essential for achieving flexible conductive polymer composites (CPCs) with high force sensitivity and high electrical conductivity In this study, self-segregated structures were constructed in polydimethylsiloxane/multi-wall carbon nanotube (PDMS/MWCNT) nanocomposites, which then exhibited high piezoresistive sensitivity and low percolation threshold without sacrificing their mechanical properties First, PDMS was cured and pulverized into 40–60 mesh-sized particles (with the size range of 250–425 μm) as an optimum self-segregated phase to improve the subsequent electrical conductivity Then, the uncured PDMS/MWCNT base together with the curing agent was mixed with the abovementioned PDMS particles, serving as the segregated phase Finally, the mixture was cured again to form the PDMS/MWCNT nanocomposites with self-segregated structures The morphological evaluation indicated that MWCNTs were located in the second cured three-dimensional (3D) continuous PDMS phase, resulting in an ultralow percolation threshold of 0003 vol% MWCNTs The nanocomposites with self-segregated structures with 02 vol% MWCNTs achieved a high electrical conductivity of 0003 S m−1, whereas only 487 × 10−10 S m−1 was achieved for the conventional samples with 02 vol% MWCNTs The gauge factor GF of the self-segregated samples was 74-fold that of the conventional samples at 30% compression strain Furthermore, the self-segregated samples also showed higher compression modulus and strength as compared to the conventional samples These enhanced properties were attributed to the construction of 3D self-segregated structures, concentrated distribution of MWCNTs, and strong interfacial interaction between the segregated phase and the continuous phase with chemical bonds formed during the second curing process These self-segregated structures provide a new insight into the fabrication of elastomers with high electrical conductivity and piezoresistive sensitivity for flexible force-sensitive materials

Journal ArticleDOI
TL;DR: In this article, water-soluble and blue fluorescent carbon dots (C-dots) were synthesized using one-pot hydrothermal method with malonic acid and urea, and were then used as a label-free fluorescent probe for selective, sensitive, and rapid determination of picric acid (PA).
Abstract: In this work, novel water-soluble and blue fluorescent carbon dots (C-dots) were synthesized using one-pot hydrothermal method with malonic acid and urea, and were then used as a label-free fluorescent probe for selective, sensitive, and rapid determination of picric acid (PA). The sizes of the as-prepared C-dots were mainly distributed in the range of 1.5–3.0 nm with an average diameter of 2.5 nm. Moreover, the C-dots displayed blue fluorescence with an emission peak at 395 nm (320 nm excitation), which also showed good stability and anti-photobleaching ability. Interestingly, the fluorescence of C-dots could be selectively quenched by PA within 10 s. Based on this phenomenon, a label-free fluorescence assay was proposed for specific determination of PA. The fluorescence intensity of probe showed a linear response to PA in the concentration range of 0.1 to 26.5 μM with a low detection limit of 51 nM (S/N = 3). Finally, the resultant fluorescent probe was successfully applied to the detection of PA in real water samples.

Journal ArticleDOI
TL;DR: This review summarizes the status of knowledge on geographical distribution, diversity, and host range of Ralstonia spp.
Abstract: Bacterial wilt caused by plant pathogenic Ralstonia spp. is one of the most important diseases affecting the production of many important crops worldwide. In China, a large scientific community has been dedicated to studying bacterial wilt and its causative agent, R. pseudosolanacearum and R. solanacearum. Most of their work was published in Chinese, which has hindered international communication and collaboration in this field. In this review, we summarize the status of knowledge on geographical distribution, diversity, and host range of Ralstonia spp., as well as, the impact of bacterial wilt on important crops and disease control approaches, in China. We present areas of research and publications by Chinese scientists and propose the promotion of collaborative research within China and with the international community.

Journal ArticleDOI
TL;DR: In this paper, a new method called D-DEMATEL which combines D number theory and decision-making trial and evaluation laboratory (DEMATel) to identify the critical success factors (CSFs) in emergency management is proposed.

Journal ArticleDOI
TL;DR: Through modulation in T‐cell responses, melatonin exerts beneficial effects in various inflammatory diseases, such as type 1 diabetes, systemic lupus erythematosus, and multiple sclerosis, and these findings highlight the importance of melatonin signaling in T •cell fate determination, and T cell‐based immune pathologies.
Abstract: Melatonin affects a variety of physiological processes including circadian rhythms, cellular redox status, and immune function. Importantly, melatonin significantly influences T-cell-mediated immune responses, which are crucial to protect mammals against cancers and infections, but are associated with pathogenesis of many autoimmune diseases. This review focuses on our current understanding of the significance of melatonin in T-cell biology and the beneficial effects of melatonin in T-cell response-based diseases. In addition to expressing both membrane and nuclear receptors for melatonin, T cells have the four enzymes required for the synthesis of melatonin and produce high levels of melatonin. Meanwhile, melatonin is highly effective in modulating T-cell activation and differentiation, especially for Th17 and Treg cells, and also memory T cells. Mechanistically, the influence of melatonin in T-cell biology is associated with membrane and nuclear receptors as well as receptor-independent pathways, for example, via calcineurin. Several cell signaling pathways, including ERK1/2-C/EBPα, are involved in the regulatory roles of melatonin in T-cell biology. Through modulation in T-cell responses, melatonin exerts beneficial effects in various inflammatory diseases, such as type 1 diabetes, systemic lupus erythematosus, and multiple sclerosis. These findings highlight the importance of melatonin signaling in T-cell fate determination, and T cell-based immune pathologies.

Journal ArticleDOI
TL;DR: In this paper, the authors reviewed progress in toughening poly(lactic acid) with renewable polymers and briefly introduced the tougheting theories and compatibilization strategies.
Abstract: Poly(lactic acid) (PLA) is regarded as one of the most promising biobased and biodegradable polymers due its various advantages including high mechanical strength, easy processability, high melting temperature, renewability, biodegradability, and biocompatibility. However, the inherent brittleness significantly restricts its wide application. Therefore, toughening PLA has attracted more and more attention and various materials have been used to blend with PLA for toughening. Considering the fact that the use of petroleum-based species to toughen PLA would partially sacrifice the sustainability, various renewable polymers have recently been employed to toughen PLA. A series of important achievements have been obtained but not reviewed. This article aims to review progress in toughening PLA with renewable polymers. The toughening theories and compatibilization strategies are also briefly introduced.

Journal ArticleDOI
TL;DR: Cu2+ can be captured by the amino groups of carbon dots (CDs) to form complexes, resulting in a strong fluorescence quenching of CDs via a nonradiative electron transfer process, which offered a rapid, visual, and selective methodology for Cu2+ detection.

Journal ArticleDOI
Xiao Xi Yang1, Chun Mei Li1, Yuan Fang Li1, Jian Wang1, Cheng Zhi Huang1 
TL;DR: A β-cyclodextrin functionalized graphene oxide (GO) composite, which displayed excellent antiviral activity and could load curcumin efficiently and could prevent RSV from infecting the host cells by directly inactivating the virus and inhibiting the viral attachment.
Abstract: The diseases attributable to viruses remain a global burden. The respiratory syncytial virus (RSV), which is considered as the major viral pathogen of the lower respiratory tract of infants, has been implicated in severe lung disease. In this contribution, we developed a β-cyclodextrin (CD) functionalized graphene oxide (GO) composite, which displayed excellent antiviral activity and could load curcumin efficiently. RSV, a negative-sense single-stranded enveloped RNA virus, was employed as a model virus to investigate the antiviral activity of multifunctional GO. Proved by the tissue culture infectious dose assay and immunofluorescence assay, the curcumin loaded functional GO was confirmed with highly efficient inhibition for RSV infection and great biocompatibility to the host cells. The results showed that the composite could prevent RSV from infecting the host cells by directly inactivating the virus and inhibiting the viral attachment, and possessed prophylactic and therapeutic effects towards the virus. Our data indicate that the composite may provide new insights into antiviral therapy for RSV infection.

Journal ArticleDOI
TL;DR: It is concluded that after 7-years of fertilization, soil bacterial diversity and community structure were shaped more by changes in soil pH rather than the direct effect of nutrient addition.
Abstract: Application of chemical fertilizer or manure can affect soil microorganisms directly by supplying nutrients and indirectly by altering soil pH. However, it remains uncertain which effect mostly shapes microbial community structure. We determined soil bacterial diversity and community structure by 454 pyrosequencing the V1-V3 regions of 16S rRNA genes after 7-years (2007-2014) of applying chemical nitrogen, phosphorus and potassium (NPK) fertilizers, composted manure or their combination to acidic (pH 5.8), near-neutral (pH 6.8) or alkaline (pH 8.4) Eutric Regosol soil in a maize-vegetable rotation in southwest China. In alkaline soil, nutrient sources did not affect bacterial Operational Taxonomic Unit (OTU) richness or Shannon diversity index, despite higher available N, P, K and soil organic carbon in fertilized than in unfertilized soil. In contrast, bacterial OTU richness and Shannon diversity index were significantly lower in acidic and near-neutral soils under NPK than under manure or their combination, which corresponded with changes in soil pH. Permutational multivariate analysis of variance showed that bacterial community structure was significantly affected across these three soils, but the PCoA ordination patterns indicated the effect was less distinct among nutrient sources in alkaline than in acidic and near-neural soils. Distance-based redundancy analysis showed that bacterial community structures were significantly altered by soil pH in acidic and near-neutral soils, but not by any soil chemical properties in alkaline soil. The relative abundance (%) of most bacterial phyla was higher in near-neutral than in acidic or alkaline soils. The most dominant phyla were Proteobacteria (24.6%), Actinobacteria (19.7%), Chloroflexi (15.3%) and Acidobacteria (12.6%); the medium dominant phyla were Bacterioidetes (5.3%), Planctomycetes (4.8%), Gemmatimonadetes (4.5%), Firmicutes (3.4%), Cyanobacteria (2.1%), Nitrospirae (1.8%), and candidate division TM7 (1.0%); the least abundant phyla were Verrucomicrobia (0.7%), Armatimonadetes (0.6%), candidate division WS3 (0.4%) and Fibrobacteres (0.3%). In addition, Cyanobacteria and candidate division TM7 were more abundant in acidic soil, whereas more Gemmatimonadetes, Nitrospirae and candidate division WS3 were more abundant in alkaline soil. We conclude that after 7-years of fertilization, soil bacterial diversity and community structure were shaped more by changes in soil pH rather than the direct effect of nutrient addition.

Journal ArticleDOI
TL;DR: In this article, a lychee-like FeS2@FeSe2 core-shell microspheres were fabricated and used as an anode material for SIBs, delivering a high discharge capacity of 350 mA h g−1 at 1 A g −1 after 2700 cycles, and even up to 301.5 m A g− 1 after 3850 cycles with over 97% coulombic efficiency.
Abstract: Sodium ion batteries (SIBs) are one promising power source with low cost, abundant resource supply and good environmental benignity, but the development of a large capacity and long cycle life anode remains a great challenge. Unique lychee-like FeS2@FeSe2 core–shell microspheres were fabricated and used as an anode material for SIBs, delivering a high discharge capacity of 350 mA h g−1 at 1 A g−1 after 2700 cycles, and even up to 301.5 mA h g−1 at 5 A g−1 after 3850 cycles with over 97% coulombic efficiency. The significant enhancement in performance is contributed by the structure and chemistry of FeS2@FeSe2 core–shell microspheres, which are stacked into a uniformly distributed porous spheres-based electrode for fast mass transport to access both the FeS2 core and the FeSe2 shell, and the more conductive shell FeSe2 encapsulates the less conductive FeS2 for fast electron transfer/transport while preventing the aggregation of active FeS2 for a large reaction surface. This model may reveal an important scientific insight that the size of microspheres of less than diffusion thickness can make the electrochemical reaction take place without a diffusion limit like a surface-controlled pseudocapacitive behavior for an extremely rapid electron transport pathway. This study vividly demonstrates the great synergistic effects of the physics and chemistry of a nano/microstructure on the performance of energy storage devices, and the approach to the design of such a core–shell structure may have universal significance for the large capacity and long cycle life of SIBs.

Journal ArticleDOI
TL;DR: Experimental analyses indicate that the water extract of Longan's seed and peel, a mixed type inhibitor, can be chemically adsorbed onto the steel surface, and its inhibition effect rises with increasing extract concentration.

Journal ArticleDOI
TL;DR: A novel complex-valued memristive recurrent neural network (CVMRNN) is established to study its stability through the existence, uniqueness, and exponential stability of the equilibrium point for CVMRNNs by means of LaTeX-matrix and Lyapunov function.
Abstract: In this brief, we establish a novel complex-valued memristive recurrent neural network (CVMRNN) to study its stability. As a generalization of real-valued memristive neural networks, CVMRNN can be separated into real and imaginary parts. By means of $M$ -matrix and Lyapunov function, the existence, uniqueness, and exponential stability of the equilibrium point for CVMRNNs are investigated, and sufficient conditions are presented. Finally, the effectiveness of obtained results is illustrated by two numerical examples.

Journal ArticleDOI
19 Jan 2017-Langmuir
TL;DR: The CDs exhibit a quenching of both down- and up-conversion PL in the presence of morin and thus serve as useful probes for morin detection, and the proposed method of determination is simple, sensitive, and cost-effective.
Abstract: Blue luminescent carbon dots (CDs) with a high photoluminescence (PL) quantum yield (48.3 ± 5.3%) were prepared by the one-pot hydrothermal reaction of citric acid with poly(ethylenimine) (PEI). The CDs display bright PL, narrow emission spectra, pH-dependent PL intensity, high photostability, and up-converted luminescence. The CDs exhibit a quenching of both down- and up-conversion PL in the presence of morin and thus serve as useful probes for morin detection. Both down- and up-conversion measurements allow the quantification of concentrations from 0 to 300 μmol/L with a detection limit of 0.6 μmol/L, and this dual-mode detection increases the reliability of the measurement. The proposed method of determination is simple, sensitive, and cost-effective, with potential applications in clinical and biochemical assays.

Journal ArticleDOI
TL;DR: In this article, a BiVO4/ferroelectric BiFeO3 composite photoanode by a surface passivation approach was used to greatly enhance photocurrent by ~44 times plus ~400mV negative shift of the onset potential.