Sungkyunkwan University

About: Sungkyunkwan University is a education organization based out in Seoul, South Korea. It is known for research contribution in the topics: Graphene & Thin film. The organization has 28229 authors who have published 56428 publications receiving 1352733 citations. The organization is also known as: 성균관대학교.

Fundamentals of Wireless Information and Power Transfer: From RF Energy Harvester Models to Signal and System Designs

Abstract: Radio waves carry both energy and information simultaneously. Nevertheless, radio-frequency (RF) transmissions of these quantities have traditionally been treated separately. Currently, the community is experiencing a paradigm shift in wireless network design, namely, unifying wireless transmission of information and power so as to make the best use of the RF spectrum and radiation as well as the network infrastructure for the dual purpose of communicating and energizing. In this paper, we review and discuss recent progress in laying the foundations of the envisioned dual purpose networks by establishing a signal theory and design for wireless information and power transmission (WIPT) and identifying the fundamental tradeoff between conveying information and power wirelessly. We start with an overview of WIPT challenges and technologies, namely, simultaneous WIPT (SWIPT), wirelessly powered communication networks (WPCNs), and wirelessly powered backscatter communication (WPBC). We then characterize energy harvesters and show how WIPT signal and system designs crucially revolve around the underlying energy harvester model. To that end, we highlight three different energy harvester models, namely, one linear model and two nonlinear models, and show how WIPT designs differ for each of them in single-user and multi-user deployments. Topics discussed include rate-energy region characterization, transmitter and receiver architectures, waveform design, modulation, beamforming and input distribution optimizations, resource allocation, and RF spectrum use. We discuss and check the validity of the different energy harvester models and the resulting signal theory and design based on circuit simulations, prototyping, and experimentation. We also point out numerous directions that are promising for future research.

Shape-Controlled Synthesis of Pd Nanocrystals and Their Catalytic Applications

Abstract: Palladium is a marvelous catalyst for a rich variety of reactions in industrial processes and commercial devices. Most Pd-catalyzed reactions exhibit structure sensitivity, meaning that the activity or selectivity depends on the arrangement of atoms on the surface. Previously, such reactions could only be studied in ultrahigh vacuum using Pd single crystals cut with a specific crystallographic plane. However, these model catalysts are far different from real catalytic systems owing to the absence of atoms at corners and edges and the extremely small specific surface areas for the model systems. Indeed, enhancing the performance of a Pd-based catalyst, in part to reduce the amount needed of this precious and rare metal for a given reaction, requires the use of Pd with the highest possible specific surface area. Recent advances in nanocrystal synthesis are offering a great opportunity to investigate and quantify the structural sensitivity of catalysts based on Pd and other metals. For a structure-sensitive reaction, the catalytic properties of Pd nanocrystals are strongly dependent on both the size and shape. The shape plays a more significant role in controlling activity and selectivity, because the shape controls not only the facets but also the proportions of surface atoms at corners, edges, and planes, which affect the outcomes of possible reactions. We expect catalysts based on Pd nanocrystals with optimized shapes to meet the increasing demands of industrial applications at reduced loadings and costs. In this Account, we discuss recent advances in the synthesis of Pd nanocrystals with controlled shapes and their resulting performance as catalysts for a large number of reactions. First, we review various synthetic strategies based on oxidative etching, surface capping, and kinetic control that have been used to direct the shapes of nanocrystals. When crystal growth is under thermodynamic control, the capping agent plays a pivotal role in determining the shape of a product by altering the order of surface energies for different facets through selective adsorption; the resulting product has the lowest possible total surface energy. In contrast, the product of a kinetically controlled synthesis often deviates from the thermodynamically favored structure, with notable examples including nanocrystals enclosed by high-index facets or concave surfaces. We then discuss the key parameters that control the nucleation and growth of Pd nanocrystals to decipher potential growth mechanisms and build a connection between the experimental conditions and the pathways to different shapes. Finally, we present a number of examples to highlight the use of these Pd nanocrystals as catalysts or electrocatalysts for various applications with structure-sensitive properties. We believe that a deep understanding of the shape-dependent catalytic properties, together with an ability to experimentally maneuver the shape of metal nanocrystals, will eventually lead to rational design of advanced catalysts with substantially enhanced performance.