Institution
Technical University of Berlin
Education•Berlin, Germany•
About: Technical University of Berlin is a education organization based out in Berlin, Germany. It is known for research contribution in the topics: Quantum dot & Laser. The organization has 27292 authors who have published 59342 publications receiving 1414623 citations. The organization is also known as: Technische Universität Berlin & TU Berlin.
Topics: Quantum dot, Laser, Catalysis, Population, Raman spectroscopy
Papers published on a yearly basis
Papers
More filters
••
TL;DR: In this paper, the authors investigated the effects of planning and control on the performance of new product development (NPD) projects and found that the proficiency of project planning and process management is important predictors of NPD performance.
291 citations
••
TL;DR: In this paper, the authors showed that FeNxCy moieties in a representative Fe-N-C catalyst are structurally stable but electrochemically unstable when exposed in an acidic medium to H2O2.
Abstract: For catalysing dioxygen reduction, iron–nitrogen–carbon (Fe–N–C) materials are today the best candidates to replace platinum in proton-exchange membrane fuel cell (PEMFC) cathodes. Despite tremendous progress in their activity and site-structure understanding, improved durability is critically needed but challenged by insufficient understanding of their degradation mechanisms during operation. Here, we show that FeNxCy moieties in a representative Fe–N–C catalyst are structurally stable but electrochemically unstable when exposed in an acidic medium to H2O2, the main oxygen reduction reaction (ORR) byproduct. We reveal that exposure to H2O2 leaves iron-based catalytic sites untouched but decreases their turnover frequency (TOF) via oxidation of the carbon surface, leading to weakened O2-binding on iron-based sites. Their TOF is recovered upon electrochemical reduction of the carbon surface, demonstrating the proposed deactivation mechanism. Our results reveal for the first time a hitherto unsuspected key deactivation mechanism during the ORR in an acidic medium. This study identifies the N-doped carbon surface as the Achilles' heel during ORR catalysis in PEMFCs. Observed in acidic but not in alkaline electrolytes, these insights suggest that durable Fe–N–C catalysts are within reach for PEMFCs if rational strategies minimizing the amount of H2O2 or reactive oxygen species (ROS) produced during the ORR are developed.
291 citations
••
TL;DR: Recoverable robustness combines the flexibility of stochastic programming with the tractability and performances guarantee of the classical robust approach and is exemplified in delay resistant, periodic and aperiodic timetabling problems, and train platforming.
Abstract: We present a new concept for optimization under uncertainty: recoverable robustness A solution is recovery robust if it can be recovered by limited means in all likely scenarios Specializing the general concept to linear programming we can show that recoverable robustness combines the flexibility of stochastic programming with the tractability and performances guarantee of the classical robust approach We exemplify recoverable robustness in delay resistant, periodic and aperiodic timetabling problems, and train platforming
289 citations
••
TL;DR: In this article, the feasibility of using silica aerogels as oral drug delivery systems was investigated and it was demonstrated that for all three drugs investigated here, high loading of the aerogel could be achieved.
Abstract: The feasibility of silica aerogels as oral drug delivery systems was investigated. Silica aerogels were loaded with several drugs by adsorption from their solutions in supercritical CO2. It was demonstrated that for all three drugs investigated here, high loading of the aerogel could be achieved. The loaded aerogels were characterized by IR- and UV spectroscopy and X-ray diffraction in order to show that no degradation of the drugs occurred during the loading procedure. The release profiles of two drugs (ketoprofen and griseofulvin) from loaded aerogels were measured. It was found that the drugs adsorbed on hydrophilic silica aerogels dissolve faster than the corresponding crystalline drugs. This fact can be explained by both an increase in the specific surface area of the drug adsorbed on the aerogel and its non-crystallinity in this state. The influence of density and hydrophobicity of aerogels on both the adsorption and release of drugs were studied.
289 citations
••
Helmholtz Centre for Environmental Research - UFZ1, Humboldt University of Berlin2, Stockholm Resilience Centre3, Autonomous University of Barcelona4, Technical University of Berlin5, Erasmus University Rotterdam6, University of Pennsylvania7, University of Łódź8, Leibniz Association9, Technische Universität München10, Dresden University of Technology11
TL;DR: In this article, the authors reflect on the current debate of the social effects of greening using selected examples and discuss what trade-offs between social and ecological developments in cities mean for the future debate on greening cities and a socially balanced and inclusive way of developing our cities for various groups of urban dwellers.
288 citations
Authors
Showing all 27602 results
Name | H-index | Papers | Citations |
---|---|---|---|
Markus Antonietti | 176 | 1068 | 127235 |
Jian Li | 133 | 2863 | 87131 |
Klaus-Robert Müller | 129 | 764 | 79391 |
Michael Wagner | 124 | 351 | 54251 |
Shi Xue Dou | 122 | 2028 | 74031 |
Xinchen Wang | 120 | 349 | 65072 |
Michael S. Feld | 119 | 552 | 51968 |
Jian Liu | 117 | 2090 | 73156 |
Ary A. Hoffmann | 113 | 907 | 55354 |
Stefan Grimme | 113 | 680 | 105087 |
David M. Karl | 112 | 461 | 48702 |
Lester Packer | 112 | 751 | 63116 |
Andreas Heinz | 108 | 1078 | 45002 |
Horst Weller | 105 | 451 | 44273 |
G. Hughes | 103 | 957 | 46632 |