Technical University of Berlin

About: Technical University of Berlin is a education organization based out in Berlin, Germany. It is known for research contribution in the topics: Quantum dot & Laser. The organization has 27292 authors who have published 59342 publications receiving 1414623 citations. The organization is also known as: Technische Universität Berlin & TU Berlin.

Diacetylene Functionalized Covalent Organic Framework (COF) for Photocatalytic Hydrogen Generation

Abstract: Covalent organic frameworks (COFs) are crystalline, highly porous, two- or three-dimensional polymers with tunable topology and functionalities. Because of their higher chemical stabilities in comparison to their boron-linked counterparts, imine or β-ketoenamine linked COFs have been utilized for a broad range of applications, including gas storage, heterogeneous catalysis, energy storage devices, or proton-conductive membranes. Herein, we report the synthesis of highly porous and chemically stable acetylene (−C≡C−) and diacetylene (−C≡C–C≡C−) functionalized β-ketoenamine COFs, which have been applied as photocatalyst for hydrogen generation from water. It is shown that the diacetylene moieties have a profound effect as the diacetylene-based COF largely outperforms the acetylene-based COF in terms of photocatalytic activity. As a combined effect of high porosity, easily accessible diacetylene (−C≡C–C≡C−) functionalities and considerable chemical stability, an efficient and recyclable heterogeneous photoca...

Three-phase four-wire shunt active filter control strategies

Abstract: This paper describes a three-phase four-wire shunt active power filter using a conventional three-leg converter, without the need of power supply at DC bus Two approaches have been developed to control the active filter Both control strategies consider harmonics and zero sequence components in the voltage and current simultaneously The first one provides constant power and the second one sinusoidal current to the source, even under unbalanced voltage conditions Simulation results from a complete model of shunt active filter are presented to validate and compare the control strategies