Showing papers by "Tokyo Institute of Technology published in 2003"
TL;DR: The fabrication of transparent field-effect transistors using a single-crystalline thin-film transparent oxide semiconductor, InGaO3(ZnO)5, as an electron channel and amorphous hafnium oxide as a gate insulator provides a step toward the realization of transparent electronics for next-generation optoelectronics.
Abstract: We report the fabrication of transparent field-effect transistors using a single-crystalline thin-film transparent oxide semiconductor, InGaO 3 (ZnO) 5 , as an electron channel and amorphous hafnium oxide as a gate insulator. The device exhibits an on-to-off current ratio of ∼10 6 and a field-effect mobility of ∼80 square centimeters per volt per second at room temperature, with operation insensitive to visible light irradiation. The result provides a step toward the realization of transparent electronics for next-generation optoelectronics.
2,724 citations
TL;DR: Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property and a significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs.
Abstract: Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property. The temperature ranges in which the behavior was observed were far higher than that of the transition-metal-cluster single-molecule magnets (SMMs). The significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs. The effective energy barrier for reversal of the magnetic moment is determined by the ligand field around a lanthanide ion, which gives the lowest degenerate substate a large |Jz| value and large energy separations from the rest of the substates in the ground-state multiplets.
2,124 citations
TL;DR: It is shown that a single film of a liquid-crystal network containing an azobenzene chromophore can be repeatedly and precisely bent along any chosen direction by using linearly polarized light.
Abstract: Miniaturizing a simple photomechanical system could expand its range of applications. Polymer solutions and solids that contain light-sensitive molecules can undergo photo-contraction, whereby light energy is converted into mechanical energy1,2,3,4,5,6,7,8. Here we show that a single film of a liquid-crystal network containing an azobenzene chromophore can be repeatedly and precisely bent along any chosen direction by using linearly polarized light. This striking photomechanical effect results from a photoselective volume contraction and may be useful in the development of high-speed actuators for microscale or nanoscale applications, for example in microrobots in medicine or optical microtweezers.
1,887 citations
TL;DR: In this article, a narrow charmonium-like state produced in the exclusive decay process B+/--->K+/-pi(+)pi(-)J/psi has been observed, which has a mass of 3872.0+/-0.6(stat)+/- 0.5(syst) MeV.
Abstract: We report the observation of a narrow charmoniumlike state produced in the exclusive decay process B+/--->K+/-pi(+)pi(-)J/psi. This state, which decays into pi(+)pi(-)J/psi, has a mass of 3872.0+/-0.6(stat)+/-0.5(syst) MeV, a value that is very near the M(D0)+M(D(*0)) mass threshold. The results are based on an analysis of 152M B-Bmacr; events collected at the Upsilon(4S) resonance in the Belle detector at the KEKB collider. The signal has a statistical significance that is in excess of 10sigma.
1,294 citations
TL;DR: The complete nucleotide sequence of the linear chromosome of Streptomyces avermitilis is determined and it is revealed that an internal 6.5-Mb region in the S. avermitILis genome was highly conserved with respect to gene order and content, and contained all known essential genes but showed perfectly asymmetric structure at the oriC center.
Abstract: Species of the genus Streptomyces are of major pharmaceutical interest because they synthesize a variety of bioactive secondary metabolites. We have determined the complete nucleotide sequence of the linear chromosome of Streptomyces avermitilis. S. avermitilis produces avermectins, a group of antiparasitic agents used in human and veterinary medicine. The genome contains 9,025,608 bases (average GC content, 70.7%) and encodes at least 7,574 potential open reading frames (ORFs). Thirty-five percent of the ORFs (2,664) constitute 721 paralogous families. Thirty gene clusters related to secondary metabolite biosynthesis were identified, corresponding to 6.6% of the genome. Comparison with Streptomyces coelicolor A3(2) revealed that an internal 6.5-Mb region in the S. avermitilis genome was highly conserved with respect to gene order and content, and contained all known essential genes but showed perfectly asymmetric structure at the oriC center. In contrast, the terminal regions were not conserved and preferentially contained nonessential genes.
1,182 citations
TL;DR: In this article, the conduction and valence band edges for electronic band gaps and Fermi levels are determined for Ta2O5, TaON, and Ta3N5 by ultraviolet photoelectron spectroscopy (UPS) and electrochemical analyses.
Abstract: The conduction and valence band edges for electronic band gaps and Fermi levels are determined for Ta2O5, TaON, and Ta3N5 by ultraviolet photoelectron spectroscopy (UPS) and electrochemical analyses. Reasonable agreement between the results of the two methods is obtained at the pH at which the ζ potentials of the particles are zero. The tops of the valence bands are found to be shifted to higher potential energies on the order Ta2O5 < TaON < Ta3N5, whereas the bottoms of the conduction bands are very similar in the range −0.3 to −0.5 V (vs NHE at pH = 0). From the results, it is concluded that TaON and Ta3N5 are promixing catalysts for the reduction and oxidation of water using visible light in the ranges λ < 520 nm and λ < 600 nm, respectively. It is also demonstrated that the proposed UPS technique is a reliable alternative to electrochemical analyses for determining the absolute band gap positions for materials in aqueous solutions that would otherwise be difficult to measure using electrochemical methods.
856 citations
TL;DR: Aqueous H2O2 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogensulfate as an acidic phase-transfer catalyst in an economically, technically, and environmentally satisfying manner.
849 citations
TL;DR: The removal of clathrated oxygen ions from the crystallographic cages in a single crystal of 12CaO·7Al2O3, leading to the formation of high-density electrons highly localized in the cages, may be regarded as a thermally and chemically stable single crystalline “electride.”
Abstract: We removed approximately 100% of clathrated oxygen ions from the crystallographic cages in a single crystal of 12CaO.7Al2O3, leading to the formation of high-density (approximately 2 x 10(21) cm-3) electrons highly localized in the cages. The resulting electron forms a structure that we interpret as an F+ center and migrates throughout the crystal by hopping to a neighboring cage with conductivity approximately 100 siemens per centimeter, demonstrating that the encaged electron behaves as an anion. The electron anions couple antiferromagnetically with each other, forming a diamagnetic pair or singlet bipolaron. The resulting [Ca24Al28O64]4+(4e-) may be regarded as a thermally and chemically stable single crystalline "electride."
719 citations
01 Apr 2003-Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment
TL;DR: Super-Kamiokande is the world's largest water Cherenkov detector, with net mass 50,000 tons as discussed by the authors, which collected 1678 live-days of data, observing neutrinos from the Sun, Earth's atmosphere, and the K2K long-baseline neutrino beam with high efficiency.
Abstract: Super-Kamiokande is the world's largest water Cherenkov detector, with net mass 50,000 tons. During the period April, 1996 to July, 2001, Super-Kamiokande I collected 1678 live-days of data, observing neutrinos from the Sun, Earth's atmosphere, and the K2K long-baseline neutrino beam with high efficiency. These data provided crucial information for our current understanding of neutrino oscillations, as well as setting stringent limits on nucleon decay. In this paper, we describe the detector in detail, including its site, configuration, data acquisition equipment, online and offline software, and calibration systems which were used during Super-Kamiokande I.
708 citations
TL;DR: T4 functional genomics will aid in the interpretation of these newly sequenced T4-related genomes and in broadening the understanding of the complex evolution and ecology of phages—the most abundant and among the most ancient biological entities on Earth.
Abstract: Phage T4 has provided countless contributions to the paradigms of genetics and biochemistry. Its complete genome sequence of 168,903 bp encodes about 300 gene products. T4 biology and its genomic sequence provide the best-understood model for modern functional genomics and proteomics. Variations on gene expression, including overlapping genes, internal translation initiation, spliced genes, translational bypassing, and RNA processing, alert us to the caveats of purely computational methods. The T4 transcriptional pattern reflects its dependence on the host RNA polymerase and the use of phage-encoded proteins that sequentially modify RNA polymerase; transcriptional activator proteins, a phage sigma factor, anti-sigma, and sigma decoy proteins also act to specify early, middle, and late promoter recognition. Posttranscriptional controls by T4 provide excellent systems for the study of RNA-dependent processes, particularly at the structural level. The redundancy of DNA replication and recombination systems of T4 reveals how phage and other genomes are stably replicated and repaired in different environments, providing insight into genome evolution and adaptations to new hosts and growth environments. Moreover, genomic sequence analysis has provided new insights into tail fiber variation, lysis, gene duplications, and membrane localization of proteins, while high-resolution structural determination of the "cell-puncturing device," combined with the three-dimensional image reconstruction of the baseplate, has revealed the mechanism of penetration during infection. Despite these advances, nearly 130 potential T4 genes remain uncharacterized. Current phage-sequencing initiatives are now revealing the similarities and differences among members of the T4 family, including those that infect bacteria other than Escherichia coli. T4 functional genomics will aid in the interpretation of these newly sequenced T4-related genomes and in broadening our understanding of the complex evolution and ecology of phages-the most abundant and among the most ancient biological entities on Earth.
697 citations
Osaka University1, Pusan National University2, Konan University3, Japan Atomic Energy Agency4, Academia Sinica5, Seoul National University6, Ohio University7, Kyoto University8, Tohoku University9, Yamagata University10, Chiba University11, Wakayama Medical University12, Nagoya University13, Tokyo Institute of Technology14, University of Saskatchewan15, University of Minnesota16, University of Michigan17
TL;DR: The gamman-->K(+)K(-)n reaction on 12C has been studied by measuring both K+ and K- at forward angles and a sharp baryon resonance peak was observed, consistent with an antidecuplet of baryons predicted by the chiral soliton model.
Abstract: The $\ensuremath{\gamma}n\ensuremath{\rightarrow}{K}^{+}{K}^{\ensuremath{-}}n$ reaction on $^{12}\mathrm{C}$ has been studied by measuring both ${K}^{+}$ and ${K}^{\ensuremath{-}}$ at forward angles. A sharp baryon resonance peak was observed at $1.54\ifmmode\pm\else\textpm\fi{}0.01\text{ }\text{ }\mathrm{G}\mathrm{e}\mathrm{V}/{c}^{2}$ with a width smaller than $25\text{ }\text{ }\mathrm{M}\mathrm{e}\mathrm{V}/{c}^{2}$ and a Gaussian significance of $4.6\ensuremath{\sigma}$. The strangeness quantum number ($S$) of the baryon resonance is $+1$. It can be interpreted as a molecular meson-baryon resonance or alternatively as an exotic five-quark state ($uudd\overline{s}$) that decays into a ${K}^{+}$ and a neutron. The resonance is consistent with the lowest member of an antidecuplet of baryons predicted by the chiral soliton model.
TL;DR: Two types of photomodulation of orientations of liquid crystals (LCs) are reviewed: 1) order-disorder phase transitions induced by photochemical reactions of photochromic molecules and 2) orderorder alignment change of LCs (change in LC directors) induced by photoochemical reactions or without photochemical events.
Abstract: Two types of photomodulation of orientations of liquid crystals (LCs) are reviewed: 1) order–disorder phase transitions of LCs induced by photochemical reactions of photochromic molecules and 2) order–order alignment change of LCs (change in LC directors) induced by photochemical reactions or without photochemical events. Both processes produce a large refractive-index modulation, which forms the basis of a range of photonic applications. Various modes of photomodulation of orientations of LCs with plausible mechanisms and their possible applications in photonics are described.
TL;DR: PCL networks showed faster degradation, and higher compressive modulus and compressive recovery ratios than those of PCL itself because of their low crystallinity and the modification of terminal groups, and may have considerable potential as scaffold for tissue engineering.
TL;DR: In this paper, a weak convergence theorem for a pair of a nonexpansive mapping and a strictly pseudocontractive mapping was obtained for the problem of finding a common element of the set of fixed points of a nonsmooth mapping and the solutions of a variational inequality problem for a strongly monotone mapping.
Abstract: In this paper, we introduce an iteration process of finding a common element of the set of fixed points of a nonexpansive mapping and the set of solutions of a variational inequality problem for an inverse strongly-monotone mapping, and then obtain a weak convergence theorem. Using this result, we obtain a weak convergence theorem for a pair of a nonexpansive mapping and a strictly pseudocontractive mapping. Further, we consider the problem of finding a common element of the set of fixed points of a nonexpansive mapping and the set of zeros of an inverse strongly-monotone mapping.
TL;DR: In this paper, strong convergence theorems for nonexpansive mappings and semigroups in Hilbert spaces by the hybrid method in the mathematical programming were shown for non-convex mappings.
TL;DR: In this article, the anisotropy parameter of the second harmonic of the azimuthal particle distribution has been measured with the PHENIX detector in Au+Au collisions at roots(NN)=200 GeV for identified and inclusive charged particle production at central rapidities.
Abstract: The anisotropy parameter (v(2)), the second harmonic of the azimuthal particle distribution, has been measured with the PHENIX detector in Au+Au collisions at roots(NN)=200 GeV for identified and inclusive charged particle production at central rapidities (eta 2 GeV/c, in marked contrast to the predictions of a hydrodynamical model. A quark-coalescence model is also investigated.
TL;DR: In this article, the influence of recycled aggregate on interfacial transition zone (ITZ), strength, chloride penetration, and carbonation of concrete is examined, and a double-mixing method is proposed to improve the strength, penetration depth, and resistance to carbonation.
Abstract: This study is conducted (1) to examine the influence of recycled aggregate on interfacial transition zone (ITZ), strength, chloride penetration, and carbonation of concrete, and (2) to propose a method for improving strength, chloride penetration, and carbonation resistances of concrete using recycled aggregates Five types of recycled aggregate, and four levels of water-binder ratio are used in this study The recycled aggregate concrete is evaluated according to compressive strength, tensile strength, chloride penetration depth, and carbonation depth The characteristics of ITZs in recycled aggregate concrete are also measured and used to explain the influence of recycled aggregate on the mentioned properties Additionally, the double-mixing method for improving strength, chloride penetration, and carbonation resistances of recycled aggregate concrete is evaluated in this study
TL;DR: In this paper, the authors measured the transverse momentum spectra of neutral pions in the range 1 < p_T < 10 GeV/c and showed that the pi^0 multiplicity in central reactions is significantly below the yields measured at the same squarert(s_NN) in peripheral Au+Au and p+p reactions scaled by the number of nucleon-nucleon collisions.
Abstract: Transverse momentum spectra of neutral pions in the range 1 < p_T < 10 GeV/c have been measured at mid-rapidity by the PHENIX experiment at RHIC in Au+Au collisions at sqrt(s_NN) = 200 GeV. The pi^0 multiplicity in central reactions is significantly below the yields measured at the same sqrt(s_NN) in peripheral Au+Au and p+p reactions scaled by the number of nucleon-nucleon collisions. For the most central bin, the suppression factor is ~2.5 at p_T = 2 GeV/c and increases to ~4-5 at p_T ~= 4 GeV/c. At larger p_T, the suppression remains constant within errors. The deficit is already apparent in semi-peripheral reactions and increases smoothly with centrality.
TL;DR: In this paper, the authors investigated whether a temporary structural change would induce a lasting increase in drivers' public transport use, and found that attitudes toward bus were more positive and the frequency of bus use increased, whereas the habits of using automobile decreased from before the intervention, even one month after the intervention period.
Abstract: The aim of this study was to investigate whether a temporary structural change would induce a lasting increase in drivers' public transport use. An experiment targeting 43 drivers was carried out, in which a one-month free bus ticket was given to 23 drivers in an experimental group but not to 20 drivers in a control group. Attitudes toward, habits of, and frequency of using automobile and bus were measured immediately before, immediately after, and one month after the one-month long intervention. The results showed that attitudes toward bus were more positive and that the frequency of bus use increased, whereas the habits of using automobile decreased from before the intervention, even one month after the intervention period. Furthermore, the increase in habitual bus use had the largest effect on the increase in the frequency of bus use. The results suggest that a temporary structural change, such as offering auto drivers a temporary free bus ticket, may be an important travel demand management tool for converting automotive travel demand to public-transport travel demand.
01 Mar 2003-Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment
TL;DR: The PHENIX detector as mentioned in this paper is designed to perform a broad study of A-A, p-A and p-p collisions to investigate nuclear matter under extreme conditions, and is used to study systematic variations with species and energy as well as to measure the spin structure of the nucleon.
Abstract: The PHENIX detector is designed to perform a broad study of A-A, p-A, and p-p collisions to investigate nuclear matter under extreme conditions A wide variety of probes, sensitive to all timescales, are used to study systematic variations with species and energy as well as to measure the spin structure of the nucleon Designing for the needs of the heavy-ion and polarized-proton programs has produced a detector with unparalleled capabilities PHENIX measures electron and muon pairs, photons, and hadrons with excellent energy and momentum resolution The detector consists of a large number of subsystems that are discussed in other papers in this volume The overall design parameters of the detector are presented (C) 2002 Elsevier Science BV All rights reserved
TL;DR: A novel ZnIn2S4 catalyst synthesized by hydrothermal method shows high and stable photocatalytic activity for water reduction under visible light illumination.
TL;DR: Taking together, mutagenesis and biochemical data show that both the relative position and motion of this coiled coil are critical for chaperone function, and propose a mechanism by which an ATP-driven conformational change is coupled to a large coiled-coil motion, which is indispensable for protein disaggregation.
TL;DR: In this article, a detailed analysis is given of SQCD with gauge group deformed by a small adjoint chiral multiplet mass, which is responsible for the confinement of (nonabelian) magnetic monopoles.
TL;DR: In this paper, anionic polymerization of 2-methoxyethyl methacrylate (1), 2-(2-methyl-methylpentyllithium/lithium chloride and diphenylmethylpotassium/diethylzinc in THF at −78 °C for 2−4 h was carried out.
Abstract: Anionic polymerizations of 2-methoxyethyl methacrylate (1), 2-(2-methoxyethoxy)ethyl methacrylate (2), and 2-[2-(2-methoxyethoxy)ethoxy]ethyl methacrylate (3) were carried out with 1,1-diphenyl-3-methylpentyllithium/lithium chloride and diphenylmethylpotassium/diethylzinc in THF at −78 °C for 2−4 h. The resulting polymers possessed the predicted molecular weights based on the molar ratios between monomers to initiators and the narrow molecular weight distributions (Mw/Mn < 1.1). The stability of the propagating chain ends of poly(2) and poly(3) was confirmed by the quantitative efficiency in the reversible sequential block copolymerizations between 2 and 3. New block copolymers having well-defined chain structures, poly(2)-block-poly(3), poly(3)-block-poly(2), polystyrene-block-poly(1), polystyrene-block-poly(2), and polystyrene-block-poly(3), were anionically synthesized. Both the solubility and the cloud point of polymers strongly depended on the length of hydrophilic oligo(ethylene glycol) unit. Poly(2...
TL;DR: In this paper, a sample of 524 car owners living in a metropolitan area of Sweden answered survey questions measuring intention to perform collective proenvironmental behavior, awareness of egoistic, social-altruistic, and biospheric environmental consequences, personal norm, and ascribed responsibility.
TL;DR: In this paper, the crystal structure of sintered β-tricalcium phosphate, Ca3(PO4)2, was refined using a high-resolution neutron powder diffraction data and the Rietveld method.
TL;DR: The yield ratio does not show the suppression observed in central Au+Au collisions at RHIC, but there is a small enhancement in the yield of high momentum particles.
Abstract: Transverse momentum spectra of charged hadrons with p(T)<8 GeV/c and neutral pions with p(T)<10 GeV/c have been measured at midrapidity by the PHENIX experiment at BNL RHIC in d+Au collisions at sqrt[s(NN)]=200 GeV. The measured yields are compared to those in p+p collisions at the same sqrt[s(NN)] scaled up by the number of underlying nucleon-nucleon collisions in d+Au. The yield ratio does not show the suppression observed in central Au+Au collisions at RHIC. Instead, there is a small enhancement in the yield of high momentum particles.
TL;DR: In this article, gold nanoparticles immobilized on an amine-terminated self-assembled monolayer (SAM) on a polycrystalline Au electrode were successfully used for the selective determination of dopamine (DA) in the presence of ascorbate (AA).
TL;DR: In this article, the first observation of the B-->D over barD(sJ)(2317) and B->D>D-s*gamma decays based on 123.8x10(6) B (B) was reported.
Abstract: We report the first observation of the B-->(D) over barD(sJ)(2317) and B-->(D) over barD(sJ)(2457) decays based on 123.8x10(6) B (B) over bar events collected with the Belle detector at KEKB. We observe the D-sJ(2317) decay to D(s)pi(0) and the D-sJ(2457) decay to the D(s)(*)pi(0) and D(s)gamma final states. We also set 90% C.L. upper limits for the decays D-sJ(2317)-->D-s*gamma, D-sJ(2457)-->D-s*gamma, D-sJ(2457)-->D(s)pi(0), and D-sJ(2457)-->D(s)pi(+)pi(-).