Tokyo Institute of Technology

About: Tokyo Institute of Technology is a education organization based out in Tokyo, Tôkyô, Japan. It is known for research contribution in the topics: Thin film & Catalysis. The organization has 46775 authors who have published 101656 publications receiving 2357893 citations. The organization is also known as: Tokyo Tech & Tokodai.

Homogeneous climate variability across East Antarctica over the past three glacial cycles

Abstract: Recent ice core studies have raised the disturbing possibility that glacial–interglacial climate changes may be non-uniform across Antarctica1,2. These findings have been confined to records from the Ross Sea sector of the continent, but significant deviations in other areas would call into question the widely assumed validity of the climate record obtained from Vostok, East Antarctica, on large spatial scales3. Here we present an isotopic profile from a core drilled at Dome Fuji4,5, situated 1,500 km from Vostok in a different sector of East Antarctica. The two records show remarkable similarities over the past three glacial cycles (the extent of the Dome Fuji record) in both large-amplitude changes, such as terminations, interglacials and interstadials and more subtle glacial events, even when the origin of precipitation is accounted for. Our results indicate that Antarctic climate is essentially homogeneous at the scale of the East Antarctic Plateau, possibly as a consequence of the symmetry of the plateau and the adjacent ocean.

Millimeter-wave polarization of protoplanetary disks due to dust scattering

Abstract: We present a new method to constrain the grain size in protoplanetary disks with polarization observations at millimeter wavelengths. If dust grains are grown to the size comparable to the wavelengths, the dust grains are expected to have a large scattering opacity, and thus the continuum emission is expected to be polarized due to self-scattering. We perform 3D radiative transfer calculations to estimate the polarization degree for the protoplanetary disks having radial Gaussian-like dust surface density distributions, which have been recently discovered. The maximum grain size is set to be and the observing wavelength to be 870 . We find that the polarization degree is as high as 2.5% with a subarcsec spatial resolution, which is likely to be detected with near-future ALMA observations. The emission is polarized due to scattering of anisotropic continuum emission. The map of the polarization degree shows a double-peaked distribution, and the polarization vectors are in the radial direction in the inner ring and in the azimuthal direction in the outer ring. We also find the wavelength dependence of the polarization degree: the polarization degree is the highest if dust grains have a maximum size of , where λ is the observing wavelength. Hence, multi-wave and spatially resolved polarization observations toward protoplanetary disks enable us to put a constraint on the grain size. The constraint on the grain size from polarization observations is independent of or may be even stronger than that from the opacity index.

Photocatalytic CO2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes

Abstract: Previously undescribed supramolecules constructed with various ratios of two kinds of Ru(II) complexes—a photosensitizer and a catalyst—were synthesized. These complexes can photocatalyze the reduction of CO2 to formic acid with high selectivity and durability using a wide range of wavelengths of visible light and NADH model compounds as electron donors in a mixed solution of dimethylformamide–triethanolamine. Using a higher ratio of the photosensitizer unit to the catalyst unit led to a higher yield of formic acid. In particular, of the reported photocatalysts, a trinuclear complex with two photosensitizer units and one catalyst unit photocatalyzed CO2 reduction (ΦHCOOH = 0.061, TONHCOOH = 671) with the fastest reaction rate (TOFHCOOH = 11.6 min-1). On the other hand, photocatalyses of a mixed system containing two kinds of model mononuclear Ru(II) complexes, and supramolecules with a higher ratio of the catalyst unit were much less efficient, and black oligomers and polymers were produced from the Ru complexes during photocatalytic reactions, which reduced the yield of formic acid. The photocatalytic formation of formic acid using the supramolecules described herein proceeds via two sequential processes: the photochemical reduction of the photosensitizer unit by NADH model compounds and intramolecular electron transfer to the catalyst unit.

Rhodium(I)-catalyzed direct carboxylation of arenes with CO2 via chelation-assisted C-H bond activation.

Abstract: Rh-catalyzed direct carboxylation of unactivated aryl C−H bond under atmospheric pressure of carbon dioxide was realized via chelation-assisted C−H activation for the first time. Variously substituted and functionalized 2-arylpyridines and 1-arylpyrazoles underwent the carboxylation in the presence of the rhodium catalyst and a stoichiometric methylating reagent, AlMe2(OMe), to give carboxylated products in good yields. The catalysis is proposed to consist of methylrhodium(I) species as the key intermediate, which undergoes C−H activation to afford rhodium(III), followed by reductive elimination of methane to give nucleophilic arylrhodium(I). This approach demonstrates promising application of C−H bond activation strategy in the field of carbon dioxide fixation.