Tokyo Institute of Technology

About: Tokyo Institute of Technology is a education organization based out in Tokyo, Tôkyô, Japan. It is known for research contribution in the topics: Catalysis & Thin film. The organization has 46775 authors who have published 101656 publications receiving 2357893 citations. The organization is also known as: Tokyo Tech & Tokodai.

A transparent metal: Nb-doped anatase TiO2

Abstract: This Letter focuses on the discovery of a transparent conducting oxide (TCO), anatase Ti1−xNbxO2 films with x=0.002–0.2. The resistivity of films with x⩾0.03 is 2–3×10−4Ωcm at room temperature. The carrier density of Ti1−xNbxO2 can be controlled in a range of 1×1019to2×1021cm−3. The internal transmittance for films with x⩽0.03 (40nm thickness) is about 97% in the visible light region. The transport and optical parameters are comparable to those of typical TCOs, such as In2−xSnxO3 and ZnO.

Theory of Electronic States and Transport in Carbon Nanotubes

Abstract: A brief review is given of electronic and transport properties of carbon nanotubes obtained mainly in a k · p scheme. The topics include a giant Aharonov–Bohm effect on the band gap and a Landau-level formation in magnetic fields, magnetic properties, interaction effects on the band structure, optical absorption spectra, and exciton effects. Transport properties are also discussed including absence of backward scattering except for scatterers with a potential range smaller than the lattice constant, its extension to multi-channel cases, a conductance quantization in the presence of short-range and strong scatterers such as lattice vacancies, and transport across junctions between nanotubes with different diameters. A continuum model for phonons in the long-wavelength limit and the resistivity determined by phonon scattering are reviewed as well.

Homogeneous Catalysis in Supercritical Fluids.

Abstract: Supercritical fluids (SCFs), compounds heated and pressurized beyond the critical point, have many unusual properties. Homogeneous molecular catalysts, which have far greater control over selectivity than heterogeneous solid catalysts, are now being tested in SCFs, and early results show that high rates, improved selectivity, and elimination of masstransfer problems can be achieved. As industry moves away from toxic or environmentally damaging solvents, supercritical carbon dioxide may be an ideal replacement medium for nonpolar or weakly polar chemical processes. More than simply substitutes for nonpolar solvents, SCFs can radically change the observed chemistry. Supercritical carbon dioxide is also an excellent medium for its own fixation, as demonstrated by studies of its hydrogenation.

Green chemistry: biodiesel made with sugar catalyst.

Abstract: The production of diesel from vegetable oil calls for an efficient solid catalyst to make the process fully ecologically friendly. Here we describe the preparation of such a catalyst from common, inexpensive sugars. This high-performance catalyst, which consists of stable sulphonated amorphous carbon, is recyclable and its activity markedly exceeds that of other solid acid catalysts tested for 'biodiesel' production.

Recent advances in twisted intramolecular charge transfer (TICT) fluorescence and related phenomena in materials chemistry

Abstract: Twisted intramolecular charge transfer (TICT) is an electron transfer process that occurs upon photoexcitation in molecules that usually consist of a donor and acceptor part linked by a single bond. Following intramolecular twisting, the TICT state returns to the ground state either through red-shifted emission or by nonradiative relaxation. The emission properties are potentially environment-dependent, which makes TICT-based fluorophores ideal sensors for solvents, (micro)viscosity, and chemical species. Recently, several TICT-based materials have been discovered to become fluorescent upon aggregation. Furthermore, various recent studies in organic optoelectronics, non-linear optics and solar energy conversions utilised the concept of TICT to modulate the electronic-state mixing and coupling on charge transfer states. This review presents a compact overview of the latest developments in TICT research, from a materials chemistry point of view.