Tokyo Institute of Technology

About: Tokyo Institute of Technology is a education organization based out in Tokyo, Tôkyô, Japan. It is known for research contribution in the topics: Thin film & Catalysis. The organization has 46775 authors who have published 101656 publications receiving 2357893 citations. The organization is also known as: Tokyo Tech & Tokodai.

Dimensionality-controlled insulator-metal transition and correlated metallic state in 5d transition metal oxides Sr n+1Ir nO3n+1 (n=1, 2, and infinity)

Abstract: We investigated the electronic structures of the 5d Ruddlesden-Popper series Sr n+1Ir nO3n+1 (n=1, 2, and infinity) using optical spectroscopy and first-principles calculations. As 5d orbitals are spatially more extended than 3d or 4d orbitals, it has been widely accepted that correlation effects are minimal in 5d compounds. However, we observed a Mott insulator-metal transition with a change of bandwidth as we increased n. In addition, the artificially synthesized perovskite SrIrO3 showed a very large mass enhancement of about 6, indicating that it was in a correlated metallic state.

Comprehensive survey of proteins targeted by chloroplast thioredoxin.

Abstract: Possible target proteins of chloroplast thioredoxin (Trx) have been investigated in the stroma lysate of spinach chloroplasts. For that purpose, we immobilized a mutant of m-type Trx in which an internal cysteine at the active site was substituted with serine, on cyanogen bromide-activated resin. By using this resin, the target proteins in chloroplast were efficiently acquired when they formed the mixed-disulfide intermediates with the immobilized Trxs. We could acquire Rubisco activase (45 kDa) and 2-Cys-type peroxiredoxin (Prx), which were recently identified as targets of chloroplast Trxs. Glyceraldehyde-3-phosphate dehydrogenase and sedoheputulose 1,7-bisphosphatase, well-known thiol enzymes in the Calvin cycle, also were recognized among the collected proteins, suggesting the method is applicable for our purpose. Furthermore, four proteins were identified from a homology search of the NH2-terminal sequence of the acquired proteins: glutamine synthetase, a protein homologous to chloroplast cyclophilin, a homolog of Prx-Q, and the Rubisco small subunit. The Trx susceptibilities of the recombinant cyclophilin and Prx-Q of Arabidopsis thaliana were then examined. The method developed in the present study is thus applicable to investigate the various redox networks via Trxs and the related enzymes in the cell.

A Study of Design and Control of a Quadruped Walking Vehicle

Abstract: The paper addresses some of the fundamental problems of energy efficiency, design, and adaptive gait control of quadru ped walking vehicles. The design principle of a leg called a gravitationally decoupled actuator (GDA) is shown to be indispensable for realizing energetically efficient walking mo tion. A novel mechanism, the three-dimensional Cartesian- coordinate pantograph (PANTOMEC), which follows the GDA principle and has a lightweight structure, is introduced. A constructed quadruped walking vehicle model is then de scribed : the walking vehicle has the PANTOMEC leg mecha nisms, eight tactile sensors and a posture detector, and is hierarchically controlled by a microcomputer. Comparatively high energy efficiency and a certain degree of terrain adapt ability is demonstrated. It is thus shown that a practical walking vehicle can be designed using the proposed method.The adaptive gait control problem is formalized, and an algorithm for terrain-adaptive gait control is presented. By computer simulation,...