Tokyo University of Science

About: Tokyo University of Science is a education organization based out in Tokyo, Japan. It is known for research contribution in the topics: Thin film & Enantioselective synthesis. The organization has 15800 authors who have published 24147 publications receiving 438081 citations. The organization is also known as: Tōkyō Rika Daigaku & Science University of Tokyo.

Polyanionic Compounds for Potassium-Ion Batteries.

Abstract: Lithium-ion batteries have the highest energy density among practical secondary batteries and are widely used for electronic devices, electric vehicles, and even stationary energy-storage systems. Along with the expansion of demand and applications, the concern about resources of lithium and cobalt is growing. Therefore, secondary batteries composed of abundant elements are required to complement lithium-ion batteries. In recent years, the development of potassium-ion batteries has attracted much attention, especially for large-scale energy storage. In order to realize potassium-ion batteries, various compounds are proposed and investigated as positive electrode materials, including layered transition-metal oxides, Prussian blue analogues, and polyanionic compounds. This article offers a review of polyanionic compounds which are typically composed of abundant elements and expected high operating potential. Furthermore, we deliver our new results to partially compensate for lack of studies and provide a future perspective.

Performance analysis of atmospheric optical PPM CDMA systems

Abstract: We propose atmospheric optical code-division multiple-access (CDMA) systems. We analyze the bit-error rate of the proposed system using pulse-position modulation (PPM) with considering the effects of the scintillation, avalanche photodiode noise, thermal noise, and multi-user interference. We show that the atmospheric optical CDMA systems can realize high-speed communications when the logarithm variance of the scintillation is small. When /spl sigma//sub s//sup 2/ is large, we need to use forward-error correction codes.

Pinwheel valence-bond solid and triplet excitations in the two-dimensional deformed kagome lattice

Abstract: Single crystals of a two-dimensional quantum spin system with geometric frustration lead to the observation of a ‘pinwheel’ valence-bond ground state. In this case, the distortion of the ideal kagome lattice structure helps to stabilize the quantum spin state. Determining ground states of correlated electron systems is fundamental to understanding unusual phenomena in condensed-matter physics. A difficulty, however, arises in a geometrically frustrated system in which the incompatibility between the global topology of an underlying lattice and local spin interactions gives rise to macroscopically degenerate ground states1, potentially prompting the emergence of quantum spin states, such as resonating valence bond2,3,4,5,6,7 and valence-bond solid8,9,10,11 (VBS). Although theoretically proposed to exist in a kagome lattice—one of the most highly frustrated lattices in two dimensions being comprised of corner-sharing triangles—such quantum-fluctuation-induced states have not been observed experimentally. Here we report the first realization of the ‘pinwheel’ VBS ground state in the S=1/2 deformed kagome lattice antiferromagnet Rb2Cu3SnF12 (refs 12, 13). In this system, a lattice distortion breaks the translational symmetry of the ideal kagome lattice and stabilizes the VBS state.

Surfactant-free emulsions

Abstract: Recent aspects and advances on surfactant-free emulsions are reviewed: preparation methods (e.g., acoustic emulsification, removal of dissolved gas from water and oil mixtures, utilization of solid particles, near- and super-critical carbon dioxide), colloidal stabilization (e.g., the addition of hydrophobic polymers into oil droplets, utilization of megasonic irradiation), and characterization techniques (single-droplet detection technique) of surfactant-free emulsions.