Tokyo University of Science

About: Tokyo University of Science is a education organization based out in Tokyo, Japan. It is known for research contribution in the topics: Catalysis & Thin film. The organization has 15800 authors who have published 24147 publications receiving 438081 citations. The organization is also known as: Tōkyō Rika Daigaku & Science University of Tokyo.

Crystal Structure of Fast Lithium-ion-conducting Cubic Li7La3Zr2O12

Abstract: The detailed crystal structure of cubic Li7La3Zr2O12 has been successfully determined by single-crystal X-ray structure analysis. The three-dimensional network of the Li-ion migration pathway with ...

Postbounce Evolution of Core-Collapse Supernovae: Long-Term Effects of the Equation of State

Abstract: We study the evolution of a supernova core from the beginning of the gravitational collapse of a 15 M☉ star up to 1 s after core bounce. We present results of spherically symmetric simulations of core-collapse supernovae by solving general relativistic ν-radiation hydrodynamics in the implicit time differencing. We aim to explore the evolution of shock waves in the long term and investigate the formation of proto-neutron stars together with supernova neutrino signatures. These studies are done to examine the influence of the equation of state (EOS) on the postbounce evolution of shock waves in the late phase and the resulting thermal evolution of proto-neutron stars. We compare two sets of EOSs, namely, those by Lattimer and Swesty (LS-EOS) and by Shen et al. (SH-EOS). We found that, for both EOSs, the core does not explode and the shock wave stalls similarly in the first 100 ms after bounce. A revival of the shock wave does not occur even after a long period in either case. However, the recession of the shock wave appears different beyond 200 ms after bounce, having different thermal evolution of the central core. A more compact proto-neutron star is found for LS-EOS than SH-EOS with a difference in the central density by a factor of ~2 and a difference of ~10 MeV in the peak temperature. The resulting spectra of supernova neutrinos are different to an extent that may be detectable by terrestrial neutrino detectors.

Mutations of ARX are associated with striking pleiotropy and consistent genotype–phenotype correlation

Abstract: We recently identified mutations of ARX in nine genotypic males with X-linked lissencephaly with abnormal genitalia (XLAG), and in several female relatives with isolated agenesis of the corpus callosum (ACC). We now report 13 novel and two recurrent mutations of ARX, and one nucleotide change of uncertain significance in 20 genotypic males from 16 families. Most had XLAG, but two had hydranencephaly and abnormal genitalia, and three males from one family had Proud syndrome or ACC with abnormal genitalia. We obtained detailed clinical information on all 29 affected males, including the nine previously reported subjects. Premature termination mutations consisting of large deletions, frameshifts, nonsense mutations, and splice site mutations in exons 1 to 4 caused XLAG or hydranencephaly with abnormal genitalia. Nonconservative missense mutations within the homeobox caused less severe XLAG, while conservative substitution in the homeodomain caused Proud syndrome. A nonconservative missense mutation near the C-terminal aristaless domain caused unusually severe XLAG with microcephaly and mild cerebellar hypoplasia. In addition, several less severe phenotypes without malformations have been reported, including mental retardation with cryptogenic infantile spasms (West syndrome), other seizure types, dystonia or autism, and nonsyndromic mental retardation. The ARX mutations associated with these phenotypes have included polyalanine expansions or duplications, missense mutations, and one deletion of exon 5. Together, the group of phenotypes associated with ARX mutations demonstrates remarkable pleiotropy, but also comprises a nearly continuous series of developmental disorders that begins with hydranencephaly, lissencephaly, and agenesis of the corpus callosum, and ends with a series of overlapping syndromes with apparently normal brain structure.

[Co(bpy)3)]3+/2+ and [Co(phen)3] 3+/2+ electron mediators for overall water splitting under sunlight irradiation using Z-scheme photocatalyst system

Abstract: [Co(bpy)3]3+/2+ and [Co(phen)3]3+/2+ redox couples were revealed to play as electron mediators for Z-scheme photocatalyst systems composed of Ru/SrTiO3:Rh and BiVO4 powders for overall water splitting under visible light irradiation. These electron mediators were effective for only the combination of SrTiO3:Rh with BiVO4. They did not work when nondoped SrTiO3 and TiO2 of H2-evolving photocatalysts and WO3 of O2-evolving photocatalysts were employed. These results indicated that the affinity between photocatalysts and the Co-complex electron mediators was important. The photocatalytic activity depended on pH. Neutral pH conditions gave the highest activity for overall water splitting. Overall water splitting by the present system steadily proceeded for a long time. The Z-scheme photocatalyst system was also confirmed to split water under sunlight irradiation at the rates depending on weather. Moreover, overall water splitting by the Z-scheme photocatalyst system with the Co-complex electron mediator using...