Tokyo University of Science

About: Tokyo University of Science is a education organization based out in Tokyo, Japan. It is known for research contribution in the topics: Thin film & Enantioselective synthesis. The organization has 15800 authors who have published 24147 publications receiving 438081 citations. The organization is also known as: Tōkyō Rika Daigaku & Science University of Tokyo.

Sodium and Manganese Stoichiometry of P2-Type Na2/3 MnO2.

Abstract: To realize a reversible solid-state MnIII/IV redox couple in layered oxides, co-operative Jahn–Teller distortion (CJTD) of six-coordinate MnIII (t2g3–eg1) is a key factor in terms of structural and physical properties. We develop a single-phase synthesis route for two polymorphs, namely distorted and undistorted P2-type Na2/3MnO2 having different Mn stoichiometry, and investigate how the structural and stoichiometric difference influences electrochemical reaction. The distorted Na2/3MnO2 delivers 216 mAh g−1 as a 3 V class positive electrode, reaching 590 Wh (kg oxide)−1 with excellent cycle stability in a non-aqueous Na cell and demonstrates better electrochemical behavior compared to undistorted Na2/3MnO2. Furthermore, reversible phase transitions correlated with CJTD are found upon (de)sodiation for distorted Na2/3MnO2, providing a new insight into utilization of the MnIII/IV redox couple for positive electrodes of Na-ion batteries.

Development of a Rare-Earth-Free SR Motor With High Torque Density for Hybrid Vehicles

Abstract: The increased price and the limited supply of rare-earth materials have been recognized as a problem by the international clean energy community. Rare-earth permanent magnets are widely used in electrical motors in hybrid and pure electrical vehicles, which are prized for improving fuel efficiency and reducing carbon dioxide (CO 2 ) emissions. Such motors must have characteristics of high efficiency, compactness, and high torque density, as well as a wide range of operating speeds. So far, these demands have not been achieved without the use of rare-earth permanent magnets. Here, we show that a switched reluctance motor that is competitive with rare-earth permanent-magnet motors can be designed. The developed motor contains no rare-earth permanent magnets, but rather, employs high-silicon steel with low iron loss to improve efficiency. Experiments showed that the developed motor has competitive or better efficiency, torque density, compactness, and range of operating speeds compared with a standard rare-earth permanent-magnet motor. Our results demonstrate how a rare-earth-free motor could be developed to be competitive with rare-earth permanent-magnet motors, for use as a more affordable and sustainable alternative, not only in electric and hybrid vehicles, but also in the wide variety of industrial applications.

Inflationary non-Gaussianities in the most general second-order scalar-tensor theories

Abstract: For very general scalar-field theories in which the equations of motion are at second order, we evaluate the three-point correlation function of primordial scalar perturbations generated during inflation. We show that the shape of non-Gaussianities is well approximated by the equilateral type. The equilateral nonlinear parameter ${f}_{\mathrm{NL}}^{\mathrm{equil}}$ is derived on the quasi-de Sitter background, where the slow-variation parameters are much smaller than unity. We apply our formula for ${f}_{\mathrm{NL}}^{\mathrm{equil}}$ to a number of single-field models of inflation---such as k-inflation, k-inflation with Galileon terms, potential-driven Galileon inflation, nonminimal coupling models (including field-derivative coupling models), and Gauss-Bonnet gravity.

Downregulation of cytoplasmic DNases is implicated in cytoplasmic DNA accumulation and SASP in senescent cells

Abstract: Accumulating evidence indicates that the senescence-associated secretory phenotype (SASP) contributes to many aspects of physiology and disease. Thus, controlling the SASP will have tremendous impacts on our health. However, our understanding of SASP regulation is far from complete. Here, we show that cytoplasmic accumulation of nuclear DNA plays key roles in the onset of SASP. Although both DNase2 and TREX1 rapidly remove the cytoplasmic DNA fragments emanating from the nucleus in pre-senescent cells, the expression of these DNases is downregulated in senescent cells, resulting in the cytoplasmic accumulation of nuclear DNA. This causes the aberrant activation of cGAS-STING cytoplasmic DNA sensors, provoking SASP through induction of interferon-β. Notably, the blockage of this pathway prevents SASP in senescent hepatic stellate cells, accompanied by a decline of obesity-associated hepatocellular carcinoma development in mice. These findings provide valuable new insights into the roles and mechanisms of SASP and possibilities for their control.

Octet-line node structure of superconducting order parameter in KFe2As2.

Abstract: In superconductors, electrons are bound into pairs, and the exact form of that pairing and the resulting energy gap can vary, depending on the details of the electron-electron interaction and the band structure of the material. The energy gaps of the recently discovered iron-based superconductors exhibit a variety of pairing functions. KFe2As2 has been suggested to have a d -wave gap, similar to cuprate superconductors. Okazaki et al. (p. [1314][1]) use laser-based angle-resolved photoemission spectroscopy (ARPES) to map out the superconducting gap on three Fermi surfaces (FS) of the compound. They find a different gap structure on each, with the middle FS gap vanishing at eight distinct positions (nodes). It appears that the gap respects the tetragonal symmetry of the crystal, indicating (although the details may vary) the all iron-based superconductors have an extended s -wave–symmetric pairing—a finding that will help understanding of unconventional superconductivity. [1]: /lookup/doi/10.1126/science.1222793