Showing papers by "Toyota published in 2016"

High-power all-solid-state batteries using sulfide superionic conductors

Abstract: Compared with lithium-ion batteries with liquid electrolytes, all-solid-state batteries offer an attractive option owing to their potential in improving the safety and achieving both high power and high energy densities. Despite extensive research efforts, the development of all-solid-state batteries still falls short of expectation largely because of the lack of suitable candidate materials for the electrolyte required for practical applications. Here we report lithium superionic conductors with an exceptionally high conductivity (25 mS cm−1 for Li9.54Si1.74P1.44S11.7Cl0.3), as well as high stability ( ∼0 V versus Li metal for Li9.6P3S12). A fabricated all-solid-state cell based on this lithium conductor is found to have very small internal resistance, especially at 100 ∘C. The cell possesses high specific power that is superior to that of conventional cells with liquid electrolytes. Stable cycling with a high current density of 18 C (charging/discharging in just three minutes; where C is the C-rate) is also demonstrated. The development of all-solid-state batteries requires fast lithium conductors. Here, the authors report a lithium compound, Li9.54Si1.74P1.44S11.7Cl0.3, with an exceptionally high conductivity and demonstrate that all-solid-state batteries based on the compound have high power densities.

Towards a calcium-based rechargeable battery

Abstract: The development of a rechargeable battery technology using light electropositive metal anodes would result in a breakthrough in energy density. For multivalent charge carriers (M(n+)), the number of ions that must react to achieve a certain electrochemical capacity is diminished by two (n = 2) or three (n = 3) when compared with Li(+) (ref. ). Whereas proof of concept has been achieved for magnesium, the electrodeposition of calcium has so far been thought to be impossible and research has been restricted to non-rechargeable systems. Here we demonstrate the feasibility of calcium plating at moderate temperatures using conventional organic electrolytes, such as those used for the Li-ion technology. The reversibility of the process on cycling has been ascertained and thus the results presented here constitute the first step towards the development of a new rechargeable battery technology using calcium anodes.

Heterogeneous Molecular Systems for Photocatalytic CO2 Reduction with Water Oxidation

Abstract: Artificial photosynthesis-reduction of CO2 into chemicals and fuels with water oxidation in the presence of sunlight as the energy source-mimics natural photosynthesis in green plants, and is considered to have a significant part to play in future energy supply and protection of our environment. The high quantum efficiency and easy manipulation of heterogeneous molecular photosystems based on metal complexes enables them to act as promising platforms to achieve efficient conversion of solar energy. This Review describes recent developments in the heterogenization of such photocatalysts. The latest state-of-the-art approaches to overcome the drawbacks of low durability and inconvenient practical application in homogeneous molecular systems are presented. The coupling of photocatalytic CO2 reduction with water oxidation through molecular devices to mimic natural photosynthesis is also discussed.

Avoiding short circuits from zinc metal dendrites in anode by backside-plating configuration.

Abstract: Portable power sources and grid-scale storage both require batteries combining high energy density and low cost. Zinc metal battery systems are attractive due to the low cost of zinc and its high charge-storage capacity. However, under repeated plating and stripping, zinc metal anodes undergo a well-known problem, zinc dendrite formation, causing internal shorting. Here we show a backside-plating configuration that enables long-term cycling of zinc metal batteries without shorting. We demonstrate 800 stable cycles of nickel-zinc batteries with good power rate (20 mA cm(-2), 20 C rate for our anodes). Such a backside-plating method can be applied to not only zinc metal systems but also other metal-based electrodes suffering from internal short circuits.

Improving Powder Magnetic Core Properties via Application of Thin, Insulating Silica-Nanosheet Layers on Iron Powder Particles

Abstract: A thin, insulating layer with high electrical resistivity is vital to achieving high performance of powder magnetic cores. Using layer-by-layer deposition of silica nanosheets or colloidal silica over insulating layers composed of strontium phosphate and boron oxide, we succeeded in fabricating insulating layers with high electrical resistivity on iron powder particles, which were subsequently used to prepare toroidal cores. The compact density of these cores decreased after coating with colloidal silica due to the substantial increase in the volume, causing the magnetic flux density to deteriorate. Coating with silica nanosheets, on the other hand, resulted in a higher electrical resistivity and a good balance between high magnetic flux density and low iron loss due to the thinner silica layers. Transmission electron microscopy images showed that the thickness of the colloidal silica coating was about 700 nm, while that of the silica nanosheet coating was 30 nm. There was one drawback to using silica nanosheets, namely a deterioration in the core mechanical strength. Nevertheless, the silica nanosheet coating resulted in nanoscale-thick silica layers that are favorable for enhancing the electrical resistivity.

Millimeter Wave Vehicular Communications: A Survey

Abstract: Future vehicles will require massive sensing capability. Leveraging only onboard sensors, though, is challenging in crowded environments where the sensing field-of-view is obstructed. One potential solution is to share sensor data among the vehicles and infrastructure. This has the benefits of providing vehicles with an enhanced field-of-view and also additional redundancy to provide more reliability in the sensor data. A main challenge in sharing sensor data is providing the high data rates required to exchange raw sensor data. The large spectral channels at millimeter wave mmWave frequencies provide a means of achieving much higher data rates. This monograph provides an overview of mmWave vehicular communication with an emphasis on results on channel measurements, the physical PHY layer, and the medium access control MAC layer. The main objective is to summarize key findings in each area, with special attention paid to identifying important topics of future research. In addition to surveying existing work, some new simulation results are also presented to give insights on the effect of directionality and blockage, which are the two distinguishing features of mmWave vehicular channels. A main conclusion of this monograph is that given the renewed interest in high rate vehicle connectivity, many challenges remain in the design of a mmWave vehicular network.

Molecularly Designed, Nitrogen-Functionalized Graphene Quantum Dots for Optoelectronic Devices.

Abstract: Nitrogen-functionalized graphene quantum dots (NGQDs) with tailorable optical properties are prepared by a versatile technique, which allows the highest occupied molecular orbital/lowest unoccupied molecular orbital energy levels and energy gaps to be continuously varied. The integration of NGQD layers into the structures significantly improves the performance of optoelectronic devices.

Facile Exfoliation and Noncovalent Superacid Functionalization of Boron Nitride Nanosheets and Their Use for Highly Thermally Conductive and Electrically Insulating Polymer Nanocomposites.

Abstract: There is an increasing demand for highly thermally conductive and electrically insulating polymer materials for next-generation electronic devices, power systems, and communication equipment. Boron nitride nanosheets (BNNSs) are insulating materials with extremely high thermal conductivity. However, BNNSs suffer from the lack of facile and low-cost methods for producing large volumes of BNNSs, and extremely low through-plane thermal conductivities of BNNS/polymer composites as compared to the in-plane thermal conductivities. Herein, highly soluble, noncovalently functionalized boron nitride nanosheets (NF-BNNSs) with chlorosulfonic acid (CSA) were prepared by extremely facile and low-cost direct exfoliation of hexagonal boron nitrides (h-BNs), and acted as excellent nanofillers for dramatically improving both in- and through-plane thermal conductivities of insulating polymers. CSA is a cheap and versatile superacid with a large production volume. CSA showed strong physical adsorption on h-BN surfaces, giv...

A New Automotive VLC System Using Optical Communication Image Sensor

Abstract: As a new technology for next-generation vehicle-to-everything (V2X) communication, visible-light communication (VLC) using light-emitting diode (LED) transmitters and camera receivers has been energetically studied. Toward the future in which vehicles are connected anytime and anywhere by optical signals, the cutting-edge camera receiver employing a special CMOS image sensor, i.e., the optical communication image sensor (OCI), has been prototyped, and an optical V2V communication system applying this OCI-based camera receiver has already demonstrated 10-Mb/s optical signal transmission between real vehicles during outside driving. In this paper, to reach a transmission performance of 54 Mb/s, which is standardized as the maximum data rate in IEEE 802.11p for V2X communication, a more advanced OCI-based automotive VLC system is described. By introducing optical orthogonal frequency-division multiplexing (optical-OFDM), the new system achieves a more than fivefold higher data rate. Additionally, the frequency response characteristics and circuit noise of the OCI are closely analyzed and taken into account in the signal design. Furthermore, the forward-current limitation of an actual LED is also considered for long operational reliability, i.e., the LED is not operated in overdrive. Bit-error-rate experiments verify a system performance of 45 Mb/s without bit errors and 55 Mb/s with $\text{BER}\ .

Tuning thermal conductivity in molybdenum disulfide by electrochemical intercalation.

Abstract: Thermal conductivity of two-dimensional (2D) materials is of interest for energy storage, nanoelectronics and optoelectronics. Here, we report that the thermal conductivity of molybdenum disulfide can be modified by electrochemical intercalation. We observe distinct behaviour for thin films with vertically aligned basal planes and natural bulk crystals with basal planes aligned parallel to the surface. The thermal conductivity is measured as a function of the degree of lithiation, using time-domain thermoreflectance. The change of thermal conductivity correlates with the lithiation-induced structural and compositional disorder. We further show that the ratio of the in-plane to through-plane thermal conductivity of bulk crystal is enhanced by the disorder. These results suggest that stacking disorder and mixture of phases is an effective mechanism to modify the anisotropic thermal conductivity of 2D materials.

Autonomous driving vehicle system

Abstract: A system includes an acquisition unit that acquires an operation amount or a duration count, and a switching unit that switches a driving state. The switching unit switches the driving state to the cooperative driving state when the operation amount is equal to or greater than an intervention threshold and less than a start threshold or the duration count is equal to or greater than a first threshold and less than a second threshold during the autonomous driving state, switches the driving state to the autonomous driving state when the operation amount is less than the intervention threshold or the duration count is less than the first threshold during the cooperative driving state, and switches the driving state to the manual driving state when the operation amount is equal to or greater than the start threshold or the duration count is equal to or greater than the second threshold.

A Stochastic Geometry Approach to the Modeling of DSRC for Vehicular Safety Communication

Abstract: Vehicle-to-vehicle safety communications based on the dedicated short-range communication technology have the potential to enable a set of applications that help avoid traffic accidents. The performance of these applications, largely affected by the reliability of communication links, stringently ties back to the MAC and PHY layer design, which has been standardized as IEEE 802.11p. The link reliabilities depend on the signal-to-interference-plus-noise ratio (SINR), which, in turn, depends on the locations and transmit power values of the transmitting nodes. Hence, an accurate network model needs to take into account the network geometry. For such geometric models, however, there is a lack of mathematical understanding of the characteristics and performance of IEEE 802.11p. Important questions such as the scalability performance of IEEE 802.11p have to be answered by simulations, which can be very time consuming and provide limited insights to future protocol design. In this paper, we investigate the performance of IEEE 802.11p by proposing a novel mathematical model based on queuing theory and stochastic geometry. In particular, we extend the Matern hard-core type-II process with a discrete and nonuniform distribution, which is used to derive the temporal states of backoff counters. By doing so, concurrent transmissions from nodes within the carrier sensing ranges of each other are taken into account, leading to a more accurate approximation to real network dynamics. A comparison with Network Simulator 2 (ns2) simulations shows that our model achieves a good approximation in networks with different densities.

Beam design for beam switching based millimeter wave vehicle-to-infrastructure communications

Abstract: Beam alignment is a source of overhead in mobile millimeter wave communication systems due to the need for frequent repointing. Beam switching architectures can reduce the amount of repointing required by leveraging position prediction. This paper presents an optimization of beam design in terms of rate. We consider a non-congested two-lane highway scenario where road side units are installed on lighting poles. Under this scenario, line-of-sight to the road side unit is very likely and vehicle speed does not vary much. We formulate and solve numerically using a gradient descent method for an optimal beam design to maximize the data rate for non-overlap beams. The result shows close performance to the equal coverage beam design. We study the effect of the overlap on the average rate and outage and compare the equal coverage with the equal beamwidth design. Numerical examples show that the equal coverage design can achieve up to 1.5x the rate of the equal beamwidth design confirming the importance of the choice of beam design.

A photoluminescent covalent triazine framework : CO2 adsorption, light-driven hydrogen evolution and sensing of nitroaromatics

Abstract: A highly photoluminescent (PL) porous covalent triazine-based framework (PCTF-8) is synthesized from tetra(4-cyanophenyl)ethylene by using trifluoromethanesulfonic acid as the catalyst at room temperature. Due to triazine units in the framework, the PCTF-8 exhibits excellent thermal stability (>400 °C). The Brunauer–Emmett–Teller (BET) specific surface area of PCTF-8 is 625 m2 g−1 which is lower than the one obtained from the synthesis under Lewis acid conditions (ZnCl2). At 1 bar and 273 K, the PCTF-8 adsorbs a significant amount of CO2 (56 cm3 g−1) and CH4 (17 cm3 g−1) which is highly comparable to nanoporous 1,3,5-triazine frameworks (NOP-1-6, 29–56 cm3 g−1). This nitrogen rich framework exhibits good ideal selectivity (61 : 1 (85% N2 : 15% CO2) at 273 K, 1 bar). Thus, it can be used as a promising candidate for potential applications in post-combustion CO2 capture and sequestration technologies. In addition, photoluminescence properties as well as the sensing behaviour towards nitroaromatics have been demonstrated. The fluorescence emission intensity of PCTF-8 is quenched by ca. 71% in the presence of 2,4,6-trinitrophenol (TNP). From time-resolved studies, a static quenching behaviour was found. This high photoluminescence property is used for hydrogen evolving organic photocatalysis from water in the presence of a sacrificial electron donor and a cocatalyst.

Simulation-Based Approaches for Verification of Embedded Control Systems: An Overview of Traditional and Advanced Modeling, Testing, and Verification Techniques

Abstract: Designers of industrial embedded control systems, such as automotive, aerospace, and medical-device control systems, use verification and testing activities to increase their confidence that performance requirements and safety standards are met. Since testing and verification tasks account for a significant portion of the development effort, increasing the efficiency of testing and verification will have a significant impact on the total development cost. Existing and emerging simulation-based approaches offer improved means of testing and, in some cases, verifying the correctness of control system designs.

Single-Photon Avalanche Diode with Enhanced NIR-Sensitivity for Automotive LIDAR Systems.

Abstract: A single-photon avalanche diode (SPAD) with enhanced near-infrared (NIR) sensitivity has been developed, based on 0.18 μm CMOS technology, for use in future automotive light detection and ranging (LIDAR) systems. The newly proposed SPAD operating in Geiger mode achieves a high NIR photon detection efficiency (PDE) without compromising the fill factor (FF) and a low breakdown voltage of approximately 20.5 V. These properties are obtained by employing two custom layers that are designed to provide a full-depletion layer with a high electric field profile. Experimental evaluation of the proposed SPAD reveals an FF of 33.1% and a PDE of 19.4% at 870 nm, which is the laser wavelength of our LIDAR system. The dark count rate (DCR) measurements shows that DCR levels of the proposed SPAD have a small effect on the ranging performance, even if the worst DCR (12.7 kcps) SPAD among the test samples is used. Furthermore, with an eye toward vehicle installations, the DCR is measured over a wide temperature range of 25–132 °C. The ranging experiment demonstrates that target distances are successfully measured in the distance range of 50–180 cm.

Factors affecting cycling life of LiNi0.8Co0.15Al0.05O2 for lithium-ion batteries

Abstract: Factors affecting the cycling life of cylindrical lithium-ion batteries of LiNi0.8Co0.15Al0.05O2 (NCA) with graphite were examined in terms of the rechargeable capacity and polarization of NCA derivatives of LizNi0.8Co0.15Al0.05O2−δ (0.8 ≤ z ≤ 1.05). NCA derivatives with rock-salt domains in the structure were prepared by a co-precipitation method and the structures of [Li1−yNiy]3(b)[Ni,Co,Al]3(a)O26(c) based on a space group of Rm were refined by a Rietveld method of the XRD patterns. The electrochemical reactivity of the NCA derivatives with rock-salt domains was examined in non-aqueous lithium cells, and it was found that the rechargeable capacities (Q) of the samples decrease linearly as the amount of rock-salt domain (y) increases. An empirical relation is obtained to be Q = 181.4 − 725.5y in which Q reaches zero at y = 0.25, which is derived from not only the capacity loss owing to inactive rock-salt domains but also the polarization increase. The galvanostatic intermittent titration technique (GITT) measurement told us that polarization of NCA derivatives increases when the amount of rock-salt domains is above 2%, i.e., y > 0.02, and such a relation is remarkable in the lithium insertion direction into the structure, which is ascribed to slow lithium ion mobility due to nickel ions in the lithium layers. The NCA derivatives with increased rock-salt domains of above 2% deteriorate rapidly in non-aqueous lithium cells upon charge and discharge cycles, which is ascribed to the cumulative increase in polarization during charge and discharge. An extended cycling test for cylindrical lithium-ion batteries of the NCA derivatives with a graphite negative electrode at elevated temperature was performed and the quantitative relation is discussed thereof.

Augmenting Layer-Based Object Detection With Deep Convolutional Neural Networks

Abstract: By way of example, the technology disclosed by this document receives image data; extracts a depth image and a color image from the image data; creates a mask image by segmenting the depth image; determines a first likelihood score from the depth image and the mask image using a layered classifier; determines a second likelihood score from the color image and the mask image using a deep convolutional neural network; and determines a class of at least a portion of the image data based on the first likelihood score and the second likelihood score. Further, the technology can pre-filter the mask image using the layered classifier and then use the pre-filtered mask image and the color image to calculate a second likelihood score using the deep convolutional neural network to speed up processing.

Monolayer-to-bilayer transformation of silicenes and their structural analysis.

Abstract: Silicene, a two-dimensional honeycomb network of silicon atoms like graphene, holds great potential as a key material in the next generation of electronics; however, its use in more demanding applications is prevented because of its instability under ambient conditions. Here we report three types of bilayer silicenes that form after treating calcium-intercalated monolayer silicene (CaSi2) with a BF4− -based ionic liquid. The bilayer silicenes that are obtained are sandwiched between planar crystals of CaF2 and/or CaSi2, with one of the bilayer silicenes being a new allotrope of silicon, containing four-, five- and six-membered sp3 silicon rings. The number of unsaturated silicon bonds in the structure is reduced compared with monolayer silicene. Additionally, the bandgap opens to 1.08 eV and is indirect; this is in contrast to monolayer silicene which is a zero-gap semiconductor. Two dimensional forms of silicon offer different conductive properties to that of the bulk material, promising applications in new electronic technologies. Here, the authors report the fabrication of bilayer silicenes which, unlike their monolayer form, are indirect bandgap semiconductors.

Eco-friendly p-type Cu2SnS3 thermoelectric material: crystal structure and transport properties.

Abstract: As a new eco-friendly thermoelectric material, copper tin sulfide (Cu2SnS3) ceramics were experimentally studied by Zn-doping. Excellent electrical transport properties were obtained by virtue of 3-dimensionally conductive network for holes, which are less affected by the coexistence of cubic and tetragonal phases that formed upon Zn subsitition for Sn; a highest power factors ~0.84 mW m−1 K−2 at 723 K was achieved in the 20% doped sample. Moreover, an ultralow lattice thermal conductivity close to theoretical minimum was observed in these samples, which could be related to the disordering of atoms in the coexisting cubic and tetragonal phases and the interfaces. Thanks to the phonon-glass-electron-crystal features, a maximum ZT ~ 0.58 was obtained at 723 K, which stands among the tops for sulfide thermoelectrics at the same temperature.

Robust dynamic walking using online foot step optimization

Abstract: To enable robust dynamic walking on the Atlas robot, we extend our previous work by adding a receding-horizon component. The new controller consists of three hierarchies: a center of mass (CoM) trajectory planner that follows a sequence of desired foot steps, a receding-horizon controller that optimizes the next foot placement to minimize future CoM tracking errors, and an inverse dynamics based full body controller that generates instantaneous joint commands to track these motions while obeying physical constraints. An approximate value function is generated by the CoM planner, and is used to guide the foot placement and inverse dynamics optimizations. The proposed controller is implemented and tested on the Atlas robot. It is capable of walking with strong external perturbations such as recovering from large pushes and traversing unstructured terrain.

Structural and electronic features of binary Li(2)S-P(2)S(5) glasses.

Abstract: The atomic and electronic structures of binary Li2S-P2S5 glasses used as solid electrolytes are modeled by a combination of density functional theory (DFT) and reverse Monte Carlo (RMC) simulation using synchrotron X-ray diffraction, neutron diffraction, and Raman spectroscopy data. The ratio of PSx polyhedral anions based on the Raman spectroscopic results is reflected in the glassy structures of the 67Li2S-33P2S5, 70Li2S-30P2S5, and 75Li2S-25P2S5 glasses, and the plausible structures represent the lithium ion distributions around them. It is found that the edge sharing between PSx and LiSy polyhedra increases at a high Li2S content, and the free volume around PSx polyhedra decreases. It is conjectured that Li(+) ions around the face of PSx polyhedra are clearly affected by the polarization of anions. The electronic structure of the DFT/RMC model suggests that the electron transfer between the P ion and the bridging sulfur (BS) ion weakens the positive charge of the P ion in the P2S7 anions. The P2S7 anions of the weak electrostatic repulsion would causes it to more strongly attract Li(+) ions than the PS4 and P2S6 anions, and suppress the lithium ionic conduction. Thus, the control of the edge sharing between PSx and LiSy polyhedra without the electron transfer between the P ion and the BS ion is expected to facilitate lithium ionic conduction in the above solid electrolytes.