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Showing papers by "United States Department of Energy published in 1991"


Journal ArticleDOI
TL;DR: In this article, the surface coverage of the oxidized n-alkanethiol species is shown to be 9.3×10−10 mol/cm2 and 7.0 × 10−10 cm2 on Au and Ag, respectively.

993 citations


Journal ArticleDOI
TL;DR: In this article, the authors present techniques and results that are useful in the calculation of cross sections for processes with many final state partons which have applications in the study of multi-jet phenomena in high-energy Colliders.

710 citations


Journal ArticleDOI
TL;DR: It is shown that Josephson coupling can be neglected in the high-temperature superconductors only under very stringent conditions.
Abstract: The structure of vortices within an infinite stack of thin superconducting layers is considered and examined in detail in the limit of zero interlayer Josephson coupling The basic building block for the description of three-dimensional (3D) vortex lines is shown to be the 2D pancake vortex, which is a vortex located in only one of the layers; the other layers contain no vortices, but have an important effect in screening the magnetic field generated by currents in the first layer It is shown that 3D vortex lines can be built up by superposing the contributions of stacks of 2D pancake vortices Thermal excitation is shown to break up a single 3D vortex line at a temperature corresponding to the Kosterlitz-Thouless temperature of a single superconducting layer The effect of thermally induced decoupling of the 2D vortex solids in different layers, corresponding to melting only in the direction perpendicular to the layers, is also considered It is shown that Josephson coupling can be neglected in the high-temperature superconductors only under very stringent conditions Although these conditions evidently are not met in ${\mathrm{Bi}}_{2}$${\mathrm{Sr}}_{2}$${\mathrm{CaCu}}_{2}$${\mathrm{O}}_{8}$ and ${\mathrm{Tl}}_{2}$${\mathrm{Ba}}_{2}$${\mathrm{Ca}}_{1}$${\mathrm{Cu}}_{2}$${\mathrm{O}}_{8}$, they should be satisfied in superconducting-insulating multilayer systems, such as ${\mathrm{YBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$/${\mathrm{PrBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7\mathrm{\ensuremath{-}}\mathrm{\ensuremath{\delta}}}$

610 citations


Journal ArticleDOI
05 Apr 1991-Science
TL;DR: The application of genetic engineering methods affords opportunities for researchers to apply knowledge gained about plant lipid metabolism toward enhanced use of plant oils as abundant and renewable sources of reduced carbon.
Abstract: The mechanisms that regulate plant lipid metabolism determine the dietary and industrial value of storage oils found in economically important species and may control the ability of many plants to survive exposure to temperature extremes. Many of the problems researchers have in defining the pathways, enzymes, and genes involved in plant lipid metabolism appear to be amenable to analysis by genetic approaches. Mutants with alterations in membrane lipid composition have also been used to study the structural and adaptive roles of lipids. The application of genetic engineering methods affords opportunities for researchers to apply knowledge gained about plant lipid metabolism toward enhanced use of plant oils as abundant and renewable sources of reduced carbon.

474 citations


Journal ArticleDOI
TL;DR: In this article, a simple theoretical model is proposed for the reversible magnetization of type-II superconductors as a function of the applied field H for the entire field region between H and the principal axis.
Abstract: A simple theoretical model is proposed for the reversible magnetization of type-II superconductors as a function of the applied field H for the entire field region between ${\mathit{H}}_{\mathit{c}1}$ and ${\mathit{H}}_{\mathit{c}2}$. For H\ensuremath{\simeq}${\mathit{H}}_{\mathit{c}1}$, the theory reduces to a variational model, from which ${\mathit{H}}_{\mathit{c}1}$ can be accurately computed in the Ginzburg-Landau regime. In calculating the free energy, we include, in addition to the supercurrent kinetic energy and the magnetic-field energy, the kinetic-energy and the condensation-energy terms arising from suppression of the order parameter in the vortex core. The model is further extended to include anisotropy by introducing an effective-mass tensor for the case when H is parallel to one of the principal axes. The theory is compared to reversible-magnetization data on a ${\mathrm{YBa}}_{2}$${\mathrm{Cu}}_{3}$${\mathrm{O}}_{7}$ single crystal. The method permits an accurate determination of ${\mathit{H}}_{\mathit{c}2}$ versus temperature from measurements of the magnetization versus temperature at fixed magnetic field and explains why the measurements have different slopes in different fields, contrary to what might have been expected from the linear Abrikosov formula near ${\mathit{H}}_{\mathit{c}2}$. The deduced ${\mathit{dH}}_{\mathit{c}2}$/dT is (-1.65\ifmmode\pm\else\textpm\fi{}0.23) T/K for H parallel to the c axis near ${\mathit{T}}_{\mathit{c}}$, implying ${\ensuremath{\xi}}_{\mathit{a}\mathit{b}}$(0)=(17\ifmmode\pm\else\textpm\fi{}1) \AA{}.

224 citations


Journal ArticleDOI
TL;DR: In this paper, the structure of Ag/Si(111) was investigated using first-principles total energy calculations and it was shown that the lowest energy configuration consists of a top layer of Ag atoms arranged as ''honeycomb chained trimers'' lying above a distorted top layer Si( 111) substrate.
Abstract: The structure of (\ensuremath{\surd}3 \ifmmode\times\else\texttimes\fi{} \ensuremath{\surd}3 ) Ag/Si(111) is investigated using first-principles total-energy calculations. The lowest-energy configuration consists of a top layer of Ag atoms arranged as ``honeycomb chained trimers'' lying above a distorted ``missing top layer'' Si(111) substrate. We find that the honeycomb structure observed in scanning-tunneling-microscope images arises from the electronic charge density on an empty surface band near the Fermi level.

127 citations


Journal ArticleDOI
TL;DR: In this paper, the authors explicitly deform classical oscillators to multiparameter quantum oscillators which do not commute with each other, leading to the construction of a consistent quantum algebra GLq(N) with 1 2 (N−1)(N−2) dependent parameters.

110 citations


Journal ArticleDOI
TL;DR: In this article, the authors used time-resolved Fourier Transform Reflection Absorption-Infrared Spectroscopy (FT-IRAS) to characterize the nature of the surface during reaction and qualitatively determine steady-state coverages of CO and oxygen.

106 citations


Patent
08 Apr 1991
TL;DR: In this article, the authors describe methods and techniques for reversibly binding charged biological particles in a fluid medium to an electrode surface using reversibly electroactive materials such as polyvinylferrocene, silicon-linked ferrocene or quinone.
Abstract: Methods and techniques are described for reversibly binding charged biological particles in a fluid medium to an electrode surface. The methods are useful in a variety of applications. The biological materials may include microbes, proteins, and viruses. The electrode surface may consist of reversibly electroactive materials such as polyvinylferrocene, silicon-linked ferrocene or quinone.

102 citations


Patent
11 Apr 1991
TL;DR: Melamine-formaldehyde (MF) aerogels have low densities, high surface areas, continuous porsity, ultrafine cell/pore sizes, and optical clarity as discussed by the authors.
Abstract: Organic aerogels that are transparent and essentially colorless are prepa from the aqueous, sol-gel polymerization of melamine with formaldehyde. The melamine-formaldehyde (MF) aerogels have low densities, high surface areas, continuous porsity, ultrafine cell/pore sizes, and optical clarity.

101 citations


Journal ArticleDOI
TL;DR: In this article, the authors analyzed transect data from three locations to determine if multiple scales of pattern could be detected, as predicted by Hierarchy Theory, and found 3-5 scales of patterns on all three sites.
Abstract: Vegetation transect data from three locations were analyzed to determine if multiple scales of pattern could be detected. The sites included a semiarid grassland in New Mexico, a series of calcareous openings in a deciduous forest in Tennessee, and a shrub-steppe system in Washington. The data were explored with four statistical techniques. A scale of pattern was accepted if detected by more than one analytical method or located by a single method in multiple taxa. The analyses indicated 3–5 scales of pattern on all three sites, as predicted by Hierarchy Theory.

Journal ArticleDOI
TL;DR: It is shown that the apparently linear dependence of {ital M} vs ln{ital H} in the intermediate-field region, a behavior that has been observed experimentally, can be obtained from a previously proposed variational model.
Abstract: We point out that the London model for the reversible magnetization {ital M} of high-{kappa} type-II superconductors in the intermediate-field region is quantitatively incorrect, and we discuss the implications on our understanding of the mixed state of type-II superconductors. We also show that the apparently linear dependence of {ital M} vs ln{ital H} in the intermediate-field region, a behavior that has been observed experimentally, can be obtained from a previously proposed variational model.

Journal ArticleDOI
TL;DR: In this paper, a mathematical description for a flowing mixture of solid particulates and a fluid is developed within the context of mixture theory, and the equations governing the flow of a two-component mixture of a Newtonian fluid and a granular solid are derived.

Journal ArticleDOI
TL;DR: In this paper, a broad distribution curve has been observed for low velocities, which becomes sharper as the velocity increases, and a comparison with the theoretical model shows that the average spacings are consistently larger than the predicted by the minimum undercooling criterion, whereas the smallest observed spacing corresponds to the theoretical extremum value.
Abstract: Directional solidification studies have been carried out in Pb-Au, Pb-Pd, Pd-Cd, and Pb-Sn systems to characterize the variation in eutectic spacing with velocity. In the Pb-Cd, Pb-Sn, and Pb-Pd systems, statistical distributions of spacings at each velocity were determined and a significant spread was observed. The smallest and the largest spacings, along with the average spacing, have been characterized. A broad distribution curve has been observed for low velocities which becomes sharper as the velocities increase. A comparison with the theoretical model shows that the average spacings are consistently larger than the spacings predicted by the minimum undercooling criterion, whereas the smallest observed spacing corresponds to the theoretical extremum value. Dynamical studies have been carried out to examine the spacing selection process at a given velocity by initially starting with a higher or a lower average spacing. The final spacing distribution at a given velocity was found to be the same irrespective of the initial starting condition which establishes that a definite distribution of spacings exists in eutectic systems without any hysteresis effect and that dynamical effects are not responsible for the existence of a band of stable spacing.

Patent
11 Oct 1991
TL;DR: In this paper, a monolithically integrated optoelectronic device is provided which integrates a vertical cavity surface emitting laser and either a photosensitive or an electrosensitive device either as input or output to the VCSE either in parallel or series connection.
Abstract: A monolithically integrated optoelectronic device is provided which integrates a vertical cavity surface emitting laser and either a photosensitive or an electrosensitive device either as input or output to the vertical cavity surface emitting laser either in parallel or series connection Both vertical and side-by-side arrangements are disclosed, and optical and electronic feedback means are provided Arrays of these devices can be configured to enable optical computing and neural network applications


Journal ArticleDOI
TL;DR: In this article, a nonlinear simultaneous equation for ground-water velocity and porosity is derived for a single-well drift-and-pumpback tracer system, based on the hydraulic conductivity of a well.
Abstract: Estimates of ground-water velocity, based either on Darcy's law or on the single-well drift and pumpback tracer method, require prior knowledge of effective porosity. That is, after field data have been collected, the equation for ground-water velocity, using either method, still contains the two unknowns, velocity and porosity. If the local hydraulic gradient is known and if a drift and pumpback tracer test is conducted at a well whose hydraulic conductivity has been determined, two independent functional relationships between velocity and porosity are established. By treating these functions as nonlinear simultaneous equations, a unique solution for the local velocity and porosity can be obtained.

Patent
24 May 1991
TL;DR: In this paper, a chemical sensor includes two or more pairs of interdigital electrodes having different periodicities having different frequencies associated with each pair are functions of the transducer periodicity as well as the velocity of the particular acoustic wave in the chosen substrate material.
Abstract: A chemical sensor (1) includes two or more pairs of interdigital electrodes (10) having different periodicities Each pair is comprised of a first electrode (10a) and a second electrode (10b) The electrodes are patterned on a surface of a piezoelectric substrate (12) Each pair of electrodes may launch and receive various acoustic waves (AW), including a surface acoustic wave (SAW), and may also launch and receive several acoustic plate modes (APMs) The frequencies associated with each are functions of the transducer periodicity as well as the velocity of the particular AW in the chosen substrate material An AW interaction region (13) exists between each pair of electrodes Circuitry (20, 40) is used to launch, receive, and monitor the propagation characteristics of the AWs and may be configured in an intermittent measurement fashion or in a continuous measurement fashion Perturbations to the AW velocity and attenuation are recorded at several frequencies and provide the sensor response

Journal ArticleDOI
TL;DR: In this paper, the co-adversorption of CO and O on a Ru(001) surface under UHV conditions was investigated using time-resolved Fourier Transform Reflection Absorption-Infrared Spectroscopy (FT-IRAS), Thermal Desorption Mass Spectrometry (TDMS), and Low-Energy Electron Diffraction (LEED).

PatentDOI
TL;DR: In this article, a method for synthesizing no-carrier-added (NCA) aryl [18 F] fluoride substituted aromatic aldehyde compositions bearing an electron donating group is described.

Journal ArticleDOI
D. Decamp1, B. Deschizeaux1, C. Goy1, J. P. Lees1  +396 moreInstitutions (25)
TL;DR: In this article, the authors measured the charged particle multiplicity distribution of hadronic Z decays using the ALEPH detector at LEP and found that the distribution has a mean 〈n〉=20.85± 0.24 and a dispersion D=6.34±0.12.

Journal ArticleDOI
TL;DR: Ion-exclusion chromatography is a relatively old technique that has been attracting increased attention as mentioned in this paper, particularly useful for separating hydrophilic molecular species from one another and from large amounts of ionic materials.

Journal ArticleDOI
TL;DR: In this paper, the first quantum correction for 2 gluons→ n gluon in the presence of an instanton was calculated and the correction was found to be negative and proportional to αsϱ 2 with ϱ the instanton size.

Journal ArticleDOI
TL;DR: A method for the determination of boron in a variety of biological samples is described in this paper, where the sample material is fused with sodium carbonate and borons are separated from matrix components by using Amberlite IRA-743 borón selective ion exchange resin.

Patent
27 Nov 1991
TL;DR: In this paper, the geometrical restrictions on a laser beam homogenizer are relaxed by ug a coherence delay line to separate a coherent input beam into several components each having a path length difference equal to a multiple of the coherence length with respect to the other components.
Abstract: The geometrical restrictions on a laser beam homogenizer are relaxed by ug a coherence delay line to separate a coherent input beam into several components each having a path length difference equal to a multiple of the coherence length with respect to the other components. The components recombine incoherently at the output of the homogenizer, and the resultant beam has a more uniform spatial intensity suitable for microlithography and laser pantogography. Also disclosed is a variable aperture homogenizer, and a liquid filled homogenizer.

Patent
19 Aug 1991
TL;DR: In this paper, a multi-sensor system for detecting the presence of objects on the surface of the ground or buried just under the surface, such as anti-personnel or anti-tank mines or the like, is presented.
Abstract: A multi-sensor system (10) for detecting the presence of objects on the surface of the ground or buried just under the surface, such as anti-personnel or anti-tank mines or the like. A remote sensor platform (12) has a plurality of metal detector sensors (22) and a plurality of short pulse radar sensors (24). The remote sensor platform (12) is remotely controlled from a processing and control unit (14) and signals from the remote sensor platform (12) are sent to the processing and control unit (14) where they are individually evaluated in separate data analysis subprocess steps (34, 36) to obtain a probability "score" for each of the pluralities of sensors (22, 24). These probability scores are combined in a fusion subprocess step (38) by comparing score sets to a probability table (130) which is derived based upon the historical incidence of object present conditions given that score set. A decision making rule is applied to provide an output which is optionally provided to a marker subprocess (40) for controlling a marker device (76) to mark the location of found objects.

Journal ArticleDOI
TL;DR: In this article, the energy loss of a high-energy parton traversing the equilibrium quark-gluon plasma is discussed, and the collisions with the thermalized plasma partons and the plasma polarization effects are considered in detail.

Journal ArticleDOI
TL;DR: In this paper, the equations governing the flow of a two-component mixture of a Newtonian fluid and a granular solid are derived for steady pressure driven flow through a pipe of circular cross-section.

Journal ArticleDOI
TL;DR: In this paper, a cold field emission gun, a small-gap immersion probe-forming lens, and a clean dry-pumped vacuum are used for high-resolution scanning electron microscopy.

Journal ArticleDOI
TL;DR: In this paper, a direct injection nebulizer (DIN) was used to produce a finer aerosol with a narrower drop size distribution than that for a conventional glass concentric nebulizers when both were operated at the same liquid and NE gas flow rates.
Abstract: Photographs and laser-scattering measurements showed that a direct injection nebulizer (DIN) produced a finer aerosol with a narrower drop size distribution than that for a conventional glass concentric nebulizer when both were operated at the same liquid and nebulizer gas flow rates. The droplets from the DIN were slightly larger, however, than those leaving a Scott-type spray chamber with a glass concentric nebulizer. The droplets from the DIN had a Sauter mean diameter of ∼7 μm and a 90% mass diameter of 11–16 μm. The droplet size distribution became narrower and shifted to lower diameters as the aerosol gas flow rate increased.