Showing papers by "United States Geological Survey published in 1988"

Novel mode of microbial energy metabolism: organic carbon oxidation coupled to dissimilatory reduction of iron or manganese.

Abstract: A dissimilatory Fe(III)- and Mn(IV)-reducing microorganism was isolated from freshwater sediments of the Potomac River, Maryland. The isolate, designated GS-15, grew in defined anaerobic medium with acetate as the sole electron donor and Fe(III), Mn(IV), or nitrate as the sole electron acceptor. GS-15 oxidized acetate to carbon dioxide with the concomitant reduction of amorphic Fe(III) oxide to magnetite (Fe(3)O(4)). When Fe(III) citrate replaced amorphic Fe(III) oxide as the electron acceptor, GS-15 grew faster and reduced all of the added Fe(III) to Fe(II). GS-15 reduced a natural amorphic Fe(III) oxide but did not significantly reduce highly crystalline Fe(III) forms. Fe(III) was reduced optimally at pH 6.7 to 7 and at 30 to 35 degrees C. Ethanol, butyrate, and propionate could also serve as electron donors for Fe(III) reduction. A variety of other organic compounds and hydrogen could not. MnO(2) was completely reduced to Mn(II), which precipitated as rhodochrosite (MnCO(3)). Nitrate was reduced to ammonia. Oxygen could not serve as an electron acceptor, and it inhibited growth with the other electron acceptors. This is the first demonstration that microorganisms can completely oxidize organic compounds with Fe(III) or Mn(IV) as the sole electron acceptor and that oxidation of organic matter coupled to dissimilatory Fe(III) or Mn(IV) reduction can yield energy for microbial growth. GS-15 provides a model for how enzymatically catalyzed reactions can be quantitatively significant mechanisms for the reduction of iron and manganese in anaerobic environments.

Crustal contributions to arc magmatism in the Andes of Central Chile

Abstract: Fifteen andesite-dacite stratovolcanoes on the volcanic front of a single segment of the Andean arc show along-arc changes in isotopic and elemental ratios that demonstrate large crustal contributions to magma genesis. All 15 centers lie 90 km above the Benioff zone and 280±20 km from the trench axis. Rate and geometry of subduction and composition and age of subducted sediments and seafloor are nearly constant along the segment. Nonetheless, from S to N along the volcanic front (at 57.5% SiO2) K2O rises from 1.1 to 2.4 wt %, Ba from 300 to 600 ppm, and Ce from 25 to 50 ppm, whereas FeO*/MgO declines from >2.5 to 1.4. Ce/Yb and Hf/Lu triple northward, in part reflecting suppression of HREE enrichment by deep-crustal garnet. Rb, Cs, Th, and U contents all rise markedly from S to N, but Rb/Cs values double northward — opposite to prediction were the regional alkali enrichment controlled by sediment subduction. K/Rb drops steeply and scatters greatly within many (biotite-free) andesitic suites. Wide diversity in Zr/Hf, Zr/Rb, Ba/Ta, and Ba/La within and among neighboring suites (which lack zircon and alkali feldspar) largely reflects local variability of intracrustal (not slab or mantle) contributions. Pb-isotope data define a limited range that straddles the Stacey-Kramers line, is bracketed by values of local basement rocks, in part plots above the field of Nazca plate sediment, and shows no indication of a steep (mantle+sedimentary) Pb mixing trend. 87Sr/86Sr values rise northward from 0.7036 to 0.7057, and 143Nd/144Nd values drop from 0.5129 to 0.5125. A northward climb in basal elevation of volcanic-front edifices from 1350 m to 4500 m elevation coincides with a Bougueranomaly gradient from −95 to −295 mgal, interpreted to indicate thickening of the crust from 30–35 km to 50–60 km. Complementary to the thickening crust, the mantle wedge beneath the front thins northward from about 60 km to 30–40 km (as slab depth is constant). The thick northern crust contains an abundance of Paleozoic and Triassic rocks, whereas the proportion of younger arc-intrusive basement increases southward. Primitive basalts are unknown anywhere along the arc. Base-level isotopic and chemical values for each volcano are established by blending of subcrustal and deep-crustal magmas in zones of melting, assimilation, storage and homogenization (MASH) at the mantle-crust transition. Scavenging of mid-to upper-crustal silicic-alkalic melts and intracrustal AFC (prominent at the largest center) can subsequently modify ascending magmas, but the base-level geochemical signature at each center reflects the depth of its MASH zone and the age, composition, and proportional contribution of the lowermost crust.

The formation and failure of natural dams

Abstract: Of the numerous kinds of dams that form by natural processes, dams formed from landslides, glacial ice, and late-neoglacial moraines present the greatest threat to people and property. Landslide dams form in a wide range of physiographic settings. The most common types of mass movements that form landslide dams are rock and debris avalanches; rock and soil slumps and slides; and mud, debris, and earth flows. The most common initiation mechanisms for dam-forming landslides are excessive rainfall and snowmelt and earthquakes. Landslide dams can be classified into six categories based on their relation with the valley floor. Type I dams (11% of 184 landslide dams from around the world that we were able to classify) do not reach from one valley side to the other. Type II dams (44%) span the entire valley floor, in some cases depositing material high on opposite valley sides. Type III dams (41%) move considerable distances both upstream and downstream from the landslide failure. Type IV dams (<1%) are rare and involve the contemporaneous failure of material from both sides of a valley. Type V dams (<1%) also are rare and are created when a single landslide sends multiple tongues of debris into a valley and forms two or more landslide dams in the same reach of river. Type VI dams (3%) involve one or more failure surfaces that extend under the stream or valley and emerge on the opposite valley side. Many landslide dams fail shortly after formation. In our sample of 73 documented landslide-dam failures, 27% of the landslide dams failed less than 1 day after formation, and about 50% failed within 10 days. Over-topping is by far the most common cause of failure. The timing of failure and the magnitude of the resulting floods are controlled by dam size and geometry; material characteristics of the blockage; rate of inflow to the impoundment; size and depth of the impoundment; bedrock control of flow; and engineering controls such as artificial spill-ways, diversions, tunnels, and planned breaching by blasting or conventional excavation. Glacial-ice dams can produce at least nine kinds of ice-dammed lakes. The most dangerous are lakes formed in main valleys dammed by tributary glaciers. Failure can occur by erosion of a drainage tunnel under or through the ice dam or by a channel over the ice dam. Cold polar-ice dams generally drain supraglacially or marginally by downmelting of an outlet channel. Warmer, temperate-ice dams tend to fail by sudden englacial or subglacial breaching and drainage. Late-neoglacial moraine-dammed lakes are located in steep mountain areas affected by the advances and retreats of valley glaciers in the last several centuries. These late-neoglacial dams pose hazards because (1) they are sufficiently young that vegetation has not stabilized their slopes, (2) many dam faces are steeper than the angle of repose, (3) these dams and lakes are immediately downslope from steep crevassed glaciers and near-vertical rock slopes, and (4) downstream from these dams are steep canyons with easily erodible materials that can be incorporated in the flow and increase flood peaks. The most common reported failure mechanism is overtopping and breaching by a wave or series of waves in the lake generated by icefalls, rockfalls, or snow or rock avalanches. Melting of ice cores or frozen ground and piping and seepage are other possible failure mechanisms. Natural dams may cause upstream flooding as the lake rises and downstream flooding as a result of failure of the dam. Although data are few, for the same potential energy at the dam site, ownstream flood peaks from the failure of glacier-ice dams are smaller than those from landslide, moraine, and structed earth-fill and rock-fill dam failures. Moraine-dam failures appear to produce some of the largest downstream flood peaks for potential energy at the dam site greater than 1011-1012 joules. Differences in flood peaks natural-dam failures appear to be controlled by dam characteristics and failure mechanisms.

Semianalytical Computation of Path Lines for Finite‐Difference Models

Abstract: A semianalytical particle tracking method was developed for use with velocities generated from block centered finite-difference ground-water flow models. The method is based on the assumption that each directional velocity component varies linearly within a grid cell in its own coordinate directions. This assumption allows an analytical expression to be obtained describing the flow path within an individual grid cell. Given the initial position of a particle anywhere in a cell, the coordinates of any other point along its path line within the cell, and the time of travel between them, can be computed directly. For steady-state systems, the exit point for a particle entering a cell at any arbitrary location can be computed in a single step. By following the particle as it moves from cell to cell, this method can be used to trace the path of a particle through any multidimensional flow field generated from a block-centered finite-difference flow model.

Normalization of oxygen and hydrogen isotope data

Abstract: To resolve confusion due to expression of isotopic data from different laboratories on non-corresponding scales, oxygen isotope analyses of all substances can be expressed relative to VSMOW or VPDB (Vienna Peedee belemnite) on scales normalized such that the δ18O of SLAP is −55.5% relative to VSMOW. H3+ contribution in hydrogen isotope ratio analysis can be easily determined using two gaseous reference samples that differ greatly in deuterium content.

Geochemical and climatic effects of increased marine organic carbon burial at the Cenomanian/Turonian boundary

Abstract: Perhaps the most significant event in the Cretaceous record of the carbon isotope composition of carbonate1,2, other than the 1–2.5 ‰ negative shift in the carbon isotope composition of calcareous plankton at the Cretaceous/Tertiary boundary3, is the rapid global positive excursion of ∼2 ‰ (13C enrichment) which took place between ∼91.5 Myr and 90.3 Myr (late Cenomanian to earliest Turonian (C/T boundary event))1,4,5. This excursion has been attributed to a change in the isotope composition of the marine total dissolved carbon (TDC) reservoir resulting from an increase in rate of burial of 13C-depleted organic carbon, which coincided with a major global rise in sea level5 during the so-called C/T oceanic anoxic event (OAE)6. Here we present new data, from nine localities, which demonstrate that a positive excursion in the carbon isotope composition of organic carbon at or near the C/T boundary7,8 is nearly synchronous with that for carbonate and is widespread throughout the Tethys and Atlantic basins (Fig. 1), as well as in more high-latitude epicontinental seas. The postulated increase in the rate of burial of organic carbon may have had a significant effect on CO2 and O2 concentrations in the oceans and atmosphere, and consequent effects on global climate and sedimentary facies.

Compositional evolution of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon

Abstract: The climactic eruption of Mount Mazama has long been recognized as a classic example of rapid eruption of a substantial fraction of a zoned magma body. Increased knowledge of eruptive history and new chemical analyses of ∼350 wholerock and glass samples of the climactic ejecta, preclimactic rhyodacite flows and their inclusions, postcaldera lavas, and lavas of nearby monogenetic vents are used here to infer processes of chemical evolution of this late Pleistocene — Holocene magmatic system. The 6845±50 BP climactic eruption vented ∼50 km3 of magma to form: (1) rhyodacite fall deposit; (2) welded rhyodacite ignimbrite; and (3) lithic breccia and zoned ignimbrite, these during collapse of Crater Lake caldera. Climactic ejecta were dominantly homogeneous rhyodacite (70.4±0.3% SiO2), followed by subordinate andesite and cumulate scoriae (48–61% SiO2). The gap in wholerock composition reflects mainly a step in crystal content because glass compositions are virtually continuous. Two types of scoriae are distinguished by different LREE, Rb, Th, and Zr, but principally by a twofold contrast in Sr content: High-Sr (HSr) and low-Sr (LSr) scoriae. HSr scoriae were erupted first. Trace element abundances indicate that HSr and LSr scoriae had different calcalkaline andesite parents; basalt was parental to some mafic cumulate scoriae. Parental magma compositions reconstructed from scoria wholerock and glass data are similar to those of inclusions in preclimactic rhyodacites and of aphyric lavas of nearby monogenetic vents.

Use of “Specific” Inhibitors in Biogeochemistry and Microbial Ecology

Abstract: The above statement, although meant to be tongue in cheek, contains an essential truism: all work with inhibitors is inherently suspect. This fact has been known by biochemists for some time. However, use of chemical inhibitors of enzymic systems and membranes continues to be a common approach taken toward unraveling the biochemistry and biophysics of plants, animals, and microorganisms. Various types of “broad-spectrum” biochemical inhibitors (e.g., poisons, respiratory inhibitors, and uncouplers) have been employed by ecologists for many years in order to demonstrate the active participation of microbes in chemical reactions occurring in natural samples (e.g., soils, sediments, and water). In recent years, considerable advances have been made in our understanding of the biochemistry of microorganisms of biogeochemical interest. Concurrent with these advances have been the discoveries of novel types of compounds that will block the metabolism of one particular group of microbes, but have little disruptive effect on other physiological types. Thus, the term “specific inhibitor” has been applied to these types of compounds when they are used to probe the functions of mixed populations of microorganisms. These substances provide powerful experimental tools for investigating the activity and function of certain types of microorganisms in natural samples.

Arsenic in Ground Water of the Western United States

Abstract: Natural occurrences of ground water with moderate (10 to 50 micrograms per liter) to high (greater than 50 micrograms per liter) concentrations of arsenic are common throughout much of the Western United States. High concentrations of arsenic are generally associated with one of four geochemical environments: (1) basin-fill deposits of alluvial-lacustrine origin, particularly in semiarid areas, (2) volcanic deposits, (3) geothermal systems, and (4) uranium and gold-mining areas. These findings are based on an extensive literature review, compilation of unpublished reports and data, and the review of data bases containing more than 7,000 analyses of ground-water samples for arsenic. In the first two environments, arsenic appears to be associated with sediments derived, in part, from volcanic rocks of intermediate to acidic composition. Dissolved arsenic concentrations in water from volcanic aquifers in the same regions, however, may be low (less than 10 micrograms per liter). Solid phases (minerals, amorphous solids, and sedimentary organic matter) that supply the dissolved arsenic have not been identified in most areas. Alluvial and lacustrine sedimentary deposits appear to be an important source of arsenic in volcanic areas (such as Lane County, Oregon) and in areas underlain by basin-fill deposits (such as Carson Desert in Nevada and the Tulare Lake basin in California). Mobilization of arsenic in sedimentary aquifers may be, in part, a result of changes in the geochemical environment due to agricultural irrigation. In the deeper subsurface, elevated arsenic concentrations are associated with compaction caused by groundwater withdrawals.

Resonance of a fluid-driven crack: Radiation properties and implications for the source of long-period events and harmonic tremor

Abstract: A dynamic source model is presented, in which a three-dimensional crack containing a viscous compressible fluid is excited into resonance by an impulsive pressure transient applied over a small area ΔS of the crack surface. The crack excitation depends critically on two dimensionless parameters called the crack stiffness, C = (b/μ)(L/d), and viscous damping loss, F = (12ηL)/(ρƒd2α), where b is the bulk modulus, η is the viscosity, ρƒ is the density of the fluid, μ is the rigidity, α is the compressional velocity of the solid, L is the crack length, and d is the crack thickness. The first parameter characterizes the ability of the crack to vibrate and shapes the spectral signature of the source, and the second quantifies the effect of fluid viscosity on the duration of resonance. Resonance is sustained by a very slow wave trapped in the fluid-filled crack. This guided wave, called the crack wave, is similar to the tube wave propagating in a fluid-filled borehole; it is inversely dispersive, showing a phase velocity that decreases with increasing wavelength, and its wave speed is always lower than the acoustic velocity of the fluid, decreasing rapidly as the crack stiffness increases. The source spectrum shows many sharp peaks characterizing the individual modes of vibration of the crack; the variation of spectral shape, both in the number and width of peaks, is surprisingly complex, reflecting the interference between the lateral and longitudinal modes of resonance, as well as nodes for these modes. The far-field spectrum is marked by narrow-band dominant and subdominant peaks that reflect the interaction of the various source modes. The frequency of the dominant spectral peak radiated by the source is independent of the radiation direction. The frequency, bandwidth, and spacing of the resonant peaks are strongly dependent on the crack stiffness, larger values of the stiffness factor shifting these peaks to lower frequencies and decreasing their bandwidth. The excitation of a particular mode depends on the position of the trigger and on the extent of the crack surface affected by the pressure transient. Fluid viscosity decreases the amplitudes of the main spectral peaks, smears out the finer structure of the spectrum, and greatly reduces the duration of the radiated signal. The energy loss by radiation is stronger for high frequencies, producing a seismic signature that is marked by a high-frequency content near the onset of the signal and dominated by a longer-period component of much longer duration in the signal coda. Such signature is in harmony with those displayed by long-period events observed on active volcanoes and in hydrofracture experiments. The very low velocity which is possible in a crack with high stiffness (C ≥ 100) also provides an attractive explanation for very long period tremor, such as type 2 tremor at Aso volcano, Japan, without the requirement of an unrealistically large magma container. The standing wave pattern set up on the crack surface by the sustained resonance in the fluid is observable in the near field of the crack, suggesting that the location and extent of the source may be estimated from the mapping of the pattern of nodes and antinodes seen in its vicinity. According to the model, the long-period event and harmonic tremor share the same source but differ in the boundary conditions for fluid flow and in the triggering mechanism setting up the resonance of the source, the former being viewed as the impulse response of the tremor generating system and the latter representing the excitation due to more complex forcing functions.

Climatological observations and predicted sublimation rates at Lake Hoare, Antarctica.

Abstract: In December 1985, an automated meteorological station was established at Lake Hoare in the dry valley region of Antarctica. Here, the first year-round observations available for any site in Taylor Valley are reported. The mean annual solar flux at Lake Hoare was 92 W/sq m during 1986, the mean air temperature -17.3 C, and the mean 3-m wind speed 3.3 m/s. The local climate is controlled by the wind regime during the 4-month sunless winter and by seasonal and diurnal variations in the incident solar flux during the remainder of the year.

Aftershock patterns and main shock faulting

Abstract: We have compared aftershock patterns following several moderate to large earthquakes with the corresponding distributions of coseismic slip obtained from previous analyses of the recorded strong ground motion and teleseismic waveforms. Well-located aftershock hypocenters are projected onto the main shock fault plane, and their positions are examined relative to the zones of coseismic displacement indicated by the estimated distributions of main shock slip. We also examine the aftershock focal mechanisms, when these data are available, in an attempt to identify possible patterns of secondary faulting within the aftershock zone. Our results are consistent with a hypothesis of aftershock occurrence that requires a secondary redistribution of stress following primary failure on the earthquake fault. Aftershocks following the earthquakes examined in this study occur mostly outside of or near the edges of the source areas indicated by the patterns of main shock slip. The spatial distribution of aftershocks reflects either a continuation of slip in the outer regions of the areas of maximum coseismic displacement or the activation of subsidiary faults within the volume surrounding the boundaries of main shock rupture.

Plate tectonics and island arcs

Abstract: The plate-tectonic concepts that developed rapidly in the late l960s made possible the understanding of island arcs. Before that time, mobilistic concepts evolved slowly, hindered, particularly in the United States, by an obstructionist geoscience establishment. The volcanic belts of island arcs form about 100 km above subducting plates. Convergent-plate boundaries evolve complexly with time and, at any one time, vary greatly along their lengths. Seismicity defines positions, but not trajectories, of descending slabs, which sink more steeply than they dip and are overridden by advancing upper plates. Subduction occurs beneath only one side at a time of an internally rigid plate, and the common regime in an overriding plate, behind a surficial accretionary wedge, is extensional, except where a collision is underway. Back-arc-basin lithosphere is built behind, or by, migrating island arcs, which lengthen and increase their curvatures. A collision can involve two active arcs, in which case, intervening lithosphere sinks beneath both of them, or an active margin and a passive one. Either type of collision generally is followed by the breaking through of new subduction, beneath the composite mass of light crust, from a new trench on the outside of the aggregate; conversely, a new subduction system commonly is a by-product of collision. A strip of back-arc-basin crust is in many cases left attached to the aggregate, in front of the new trench, and becomes the basement for a fore-arc basin, the leading edge of which is raised as melange is stuffed under it. Sedimentation in trenches is predominantly longitudinal and can be from distant sources. Accretionary wedges are dynamic, being thickened at both toes and bottoms by tectonic accretion and thinned by gravitational forward flow; melange is largely a product of tectonic imbrication and flowage driven by these conflicting processes, not of submarine sliding. High-pressure metamorphic rocks form beneath overriding plates, not within wedges in front of them. Arc magmas incorporate much material from the lithosphere through which they rise and vary correspondingly with the evolving composition of that lithosphere. Arc crust is inflated into geanticlines by intrusive rocks and thermal expansion. Submarine island-arc volcanic rocks are widely spilitized, with Na enrichment and Ca depletion, by hydrothermal reaction with sea water. The lower crust of mature island arcs consists of granulite-facies rocks of mafic, intermediate, and felsic-intermediate compositions. The Mohorovicic discontinuity may be primarily a constructional boundary, representing the shallow limit off crystallization of voluminous rocks of ultramafic composition or plagioclase-free mineralogy.

Hydrologic precursors to earthquakes: A review

Abstract: This review summarizes reports of anomalous flow rates or pressures of groundwater, oil, or gas that have been interpreted as earthquake precursors. Both increases and decreases of pressure and flow rate have been observed, at distances up to several hundred kilometers from the earthquake epicenter, with precursor times ranging from less than one day to more than one year. Although information that might rule out nontectonic causes does not appear in many published accounts of hydrologic anomalies, several recent studies have critically evaluated the possible influences of barometric pressure, rainfall, and groundwater or oil exploitation. Anomalies preceding the 1976 Tangshan, China, and the 1978 Izu-Oshima-Kinkai, Japan, earthquakes are especially well-documented and worthy of further examination. Among hydrologic precursors, pressure head changes in confined subsurface reservoirs are those most amenable to quantitative interpretation in terms of crustal strain. The response of pressure head to earth tides determines coefficients of proportionality between pressure head and crustal strain. The same coefficients of proportionality should govern the fluid pressure response to any crustal strain field in which fluid flow in the reservoir is unimportant. Water level changes in response to independently recorded tectonic events, such as earthquakes and aseismic fault creep, provide evidence that a calibration based on response to earth tides may be applied to crustal strains of tectonic origin. Several models of earthquake generation predict accelerating stable slip on part of the future rupture plane. If precursory slip has moment less than or equal to that of the impending earthquake, then the coseismic volume strain is an upper bound for precursory volume strain. Although crustal strain can be only crudely estimated from most reported pressure head anomalies, the sizes of many anomalies within 150 kilometers of earthquake epicenters appear consistent with this upper bound. In contrast, water level anomalies at greater epicentral distances appear to be larger than this bound by several orders of magnitude. It is clear that water level monitoring can yield information about the earthquake generation process, but progress higes on better documentation of the data.

Growth and persistence of Hawaiian volcanic rift zones

Abstract: Hawaiian volcanic rift zones are modeled by representing the rifts and adjacent volcano flanks as long ridges with the geometry of flattened triangular prisms. The intrusion of dikes along the axis of a rift requires a mechanism to generate the appropriate dike-trapping stress field within the prism. Possible factors that affect the state of stress in the prism include multiple dike intrusion along the ridge axis, faulting, and gravitational sagging of the topography. In extreme models with very steep slopes and high Poisson's ratio, corresponding to the gelatin models of rift zones by Fiske and Jackson (1972), results of finite element calculations indicate that gravity-induced stresses are sufficient to trap a dike into propagating within the prism and parallel to the rift zone as proposed by Fiske and Jackson. However, the mechanism does not work for gently sloping flanks or a more acceptable Poisson's ratio of about 0.25. Additionally, trapping stresses in the gravity-loading and density stratification models will not persist after a few dike injection episodes. Therefore in mature Hawaiian rift zones with possibly thousands of dikes, additional processes must act to control the stresses that permit continued dike intrusion and rift persistence. It is proposed that accommodation to dike emplacement occurs by slip on deep faults, possibly of the type proposed for the 1975 Kalapana, Hawaii, earthquake. As suggested by others for this earthquake, the faults could coincide with the contact of the volcano with the seafloor within the weak seafloor sediments. Such faulting not only provides a means for the flanks to adjust continuously to intrusions but also generates the stress patterns needed to constrain future dikes to propagate along the rift axis. Other possible faulting mechanisms, such as shallow gravity slides and normal faulting of the flanks, do not appear to favor rift zone persistence. In this model the horizontal stress generated by a standing column of magma at the time of dike emplacement, the stresses in the ridges, and the fault strength are coupled. This results in a feedback between the maximum height that magma can rise along the rift, fault friction, and fault width. Through this feedback the slope of the volcano flank is controlled by the fault friction. When applied to Kilauea Volcano, the model yields an estimate for the coefficient of fault friction as high as 0.39 assuming normal hydrostatic pore fluid pressure. An implication of this model, supported by other studies, is that rift intrusion and lateral spreading could be major contributors to volcano growth.

The Mechanics and Three‐Dimensional Internal Structure of Active Magmatic Systems: Kilauea Volcano, Hawaii

Abstract: Interpretation of abundant seismic data suggests that Kilauea's primary conduit within the upper mantle is concentrically zoned to about 34-km depth. This zoned structure is inferred to contain a central core region of relatively higher permeability, surrounded by numerous dikes that are in intermittent hydraulic communication with each other and with the central core. During periods of relatively high magma transport, the entire cross section of the conduit is utilized. During periods of relatively low to moderate transport, however, only the central core is active. As the conduit penetrates the oceanic crust and enters the volcanic shield, it simultaneously supplies the deeper sections of the rift zones (6-to 10-km depth) and the roots of the summit reservoir with picritic magma. The rift zones at depth are inferred to be almost wholly molten and to possess a high degree of fluid continuity from Heiheiahulu in the East Rift Zone, 45 km westward through the roots of the summit magma reservoir, and well into the Southwest Rift Zone. Higher in the shield, the subcaldera magma reservoir and the shallow rift zones occupy the 2-to 4-km depth interval. Summit-differentiated olivine tholeiite (ρ ≈ 2.62 g cm−3) is periodically injected laterally along a horizon of neutral buoyancy within the rift zones, where the density of the magma is just balanced by the in situ density of the shield (Ryan, 1987a, b). Deep rift zone intrusions push seaward the deep tectonic blocks of the volcano's south flank. Shallow rift intrusions build a sheeted dike complex, inferred to be in isostatic equilibrium with the higher-density deep rift cores below. General finite element analyses are presented for the deformation and stress fields surrounding such dikes in the horizontal and vertical planes. The dike tip in two and three dimensions is surrounded by a tubular core of tensile (σ1, σ2) and shear stress (τmax). The displacement field is characterized by counterrotating cells on either side of the dike tip which, in vertical orientation, produce the characteristic subsidence above the dike complex, with uplift on either side, forming a ridge-trough-ridge structure. A finite element model of Kilauea's shield computes the displacement fields and principal stress (σ1) distributions resulting from intrusive activity on each or both of the rift zones. Within the summit region, tensile stress lobes produced by the three-dimensional upward extension of the intrusions superpose constructively to produce calderawide regimes of tensile stress, conducive to caldera development. Parametric studies of (1) intrusion in the East Rift Zone only, (2) intrusion in the Southwest Rift Zone only, and (3) intrusion in both rift zones demonstrate their unique kinematic contributions. For case 1, the caldera undergoes a counterclockwise rotation (torque up state) conducive to the development of rightstepping en echelon eruptive fissures, as exemplified by the August 14, 1971, eruption. For case 2, the caldera undergoes a clockwise rotation (torque down state) conducive to the development of left-stepping eruptive fissures, as occurred during the December 31, 1974, eruption. For case 3, the caldera substructure is driven due southward, producing the southward migration of the upper portions of the summit magma reservoir.

Iron photoreduction and oxidation in an acidic mountain stream.

Abstract: In a small mountain stream in Colorado that receives acidic mine drainage, photoreduction of ferric iron results in a well-defined increase in dissolved ferrous iron during the day. To quantify this process, an instream injection of a conservative tracer was used to measure discharge at the time that each sample was collected. Daytime production of ferrous iron by photoreduction was almost four times as great as nighttime oxidation of ferrous iron. The photoreduction process probably involves dissolved or colloidal ferric iron species and limited interaction with organic species because concentrations of organic carbon are low in this stream.

The geometric signature: Quantifying landslide-terrain types from digital elevation models

Abstract: Topography of various types and scales can be fingerprinted by computer analysis of altitude matrices (digital elevation models, or DEMs). The critical analytic tool is the geometric signature, a set of measures that describes topographic form well enough to distinguish among geomorphically disparate landscapes. Different surficial processes create topography with diagnostic forms that are recognizable in the field. The geometric signature abstracts those forms from contour maps or their DEMs and expresses them numerically. This multivariate characterization enables once-in-tractable problems to be addressed. The measures that constitute a geometric signature express different but complementary attributes of topographic form. Most parameters used here are statistical estimates of central tendency and dispersion for five major categories of terrain geometry; altitude, altitude variance spectrum, slope between slope reversals, and slope and its curvature at fixed slope lengths. As an experimental application of geometric signatures, two mapped terrain types associated with different processes of shallow landsliding in Marin County, California, were distinguished consistently by a 17-variable description of topography from 21×21 DEMs (30-m grid spacing). The small matrix is a statistical window that can be used to scan large DEMs by computer, thus potentially automating the mapping of contrasting terrain types. The two types in Marin County host either (1) slow slides: earth flows and slump-earth flows, or (2) rapid flows: debris avalanches and debris flows. The signature approach should adapt to terrain taxonomy and mapping in other areas, where conditions differ from those in Central California.

The Giant Submarine Alika Debris Slide, Mauna Loa, Hawaii

Abstract: probably represent multiple subsidence events before, during, and after the debris avalanches. Lower slopes of the slide contain distinctive lobate-terraced deposits that are interpreted as having been emplaced more slowly, prior to the debris avalanches. Estimated thicknesses of 50-200 m suggest volumes of 200--600 km 3 for the two lobes. The combined volume of the entire slide and slump terrane is probably 1500-2000 km 3. The slide deposits predate a 13-ka coral reef and probably postdate the block-faulted Ninole Basalt, roughly dated as a few hundred thousand years old. The Alika slide, or a similar deposit recognized on GLORIA images further north along the Hawaiian Ridge, probably triggered a giant wave that washed 325 m high on Lanai at about 100 ka. Slumping on Mauna Loa has been most intense adjacent to the large arcuate bend in its southwest rift zone, as the rift zone migrated westward away from the growing Kilauea volcano. Slumping events were probably triggered by seismic activity accompanying dike injection along the rift zone. Such massive slumps, landslides, and distal submarine turbidity flows appear to be widespread on the flanks of Hawaiian volcanoes.

Late Frasnian Mass Extinction: Conodont Event Stratigraphy, Global Changes, and Possible Causes

Abstract: Several abrupt changes in conodont biofacies are documented to occur synchronously at six primary control sections across the Frasnian-Famennian boundary in Euramerica. These changes occurred within a time-span of only about 100,000 years near the end of the latest Frasnian linguiformis Zone, which is formally named to replace the Uppermost gigas Zone. The conodont-biofacies changes are interpreted to reflect a eustatic rise followed by an abrupt eustatic fall immediately preceding the late Frasnian mass extinction. Two new conodont species are named and described. Ancyrognathus ubiquitus n.sp. is recorded only just below and above the level of late Frasnian extinction and hence is a global marker for that event. Palmatolepispraetriangularis n.sp. is the long-sought Frasnian ancestor of the formerly cryptogenic species, Pa. triangularis, indicator of the earliest Famennian Lower triangularis Zone. The actual extinction event occurred entirely within the Frasnian and is interpreted to have been of brief duration-from as long as 20,000 years to as short as several days. The eustatic rise-and-fall couplet associated with the late Frasnian mass extinction is similar to eustatic couplets associated with the demise of most Frasnian (F2h) reefs worldwide about 1 m.y. earlier and with a latest Famennian mass extinction about 9.5 m.y. later. All these events may be directly or indirectly attributable to extraterrestrial triggering mechanisms. An impact of a small bolide or a near miss of a larger bolide may have caused the earlier demise of Frasnian reefs. An impact of possibly the same larger bolide in the Southern Hemisphere would explain the late Frasnian mass extinction. Global regression during the Famennian probably resulted from Southern-Hemisphere glaciation triggered by the latest Frasnian impact. Glaciation probably was the indirect cause of the latest Famennian mass extinction.

Development of simple strike-slip fault zones, Mount Abbot quadrangle, Sierra Nevada, California

Abstract: Simple strike-slip fault zones mark the third stage of faulting in granitic plutons in the Mount Abbot quadrangle of the Sierra Nevada of California. Deformation began with the opening of nearly vertical subparallel joints. These joints were filled mostly with epidote and chlorite, are up to a few tens of meters long, and typically are less than 1 cm wide. Next, some of these joints slipped left-laterally and became small faults. Small faults accommodated up to ∼2 m of displacement and are characterized by mylonitic fabrics and ductilely deformed quartz. Oblique fractures commonly developed near the ends of small faults and in many cases linked faults end-to-end. Simple fault zones developed as abundant oblique fractures linked small faults side-to-side. These fractures opened and were filled with chlorite, epidote, and quartz. Such fractures are scarce outside the two faults that mark the boundaries of a zone. Simple fault zones typically are 0.5-3 m wide, hundreds of meters long, and laterally displace dikes up to ∼10 m. Displacement is concentrated along the boundary faults, which are characterized by cataclastic textures and brittlely deformed quartz. The fault zones consist of noncoplanar segments a few tens of meters long that join at steps or bends. The segmentation reflects the initial joint pattern and indicates that fault zones grew in length as noncoplanar faults linked end-to-end. Away from bends, the most prominent internal fractures have straight traces and strike 20°-60° counterclockwise from the boundaries, whereas near bends they have gentle S-shaped traces and are nearly perpendicular to the boundaries. We suggest that as some faults linked to form longer structures, a "shear stress shadow" was cast over adjacent smaller faults, causing slip on them essentially to cease. In this manner, displacement progressively became localized on the longer faults and fault zones. If the regional shear strain rate remained constant during this process, then the shear strain rate across the still active faults must have increased. This may have caused cataclastic textures to develop in the boundary faults.